A photocatalysis process-enabled thioacylation of amines has been developed with eco-friendly feedstock potassium dithiocarboxylates as green thioacyl sources and water as the reaction solvent. The key to the success of this transformation is the light-induced generation of active dithioacyl disulfides as thioacyl donors. This green methodology has been successfully employed for the late-stage thioacylation of various amino compounds including drugs, hormones, amino acids and peptides under mild conditions.

中文翻译：

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通过光氧化还原催化与二硫代羧酸盐进行温和且绿色的硫代酰化

以环保原料二硫代羧酸钾为绿色硫代酰源，以水为反应溶剂，开发了一种光催化工艺的胺硫代酰化反应。这种转化成功的关键是光诱导产生活性二硫酰基二硫化物作为硫酰基供体。这种绿色方法已成功应用于温和条件下各种氨基化合物（包括药物、激素、氨基酸和肽）的后期硫酰化。