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Electrocatalytic oxidation of petroleum, toluene and xylene on the Ni-porphyrin-modified graphite electrode
Journal of Porphyrins and Phthalocyanines ( IF 1.5 ) Pub Date : 2023-12-22 , DOI: 10.1142/s1088424623501304
Arezo Bahrami 1 , Majid Jafarian 1 , Ghodsiyeh Sadat Ferdowsi 1 , Saeed Rayati 1
Affiliation  

In this study, electrochemical oxidation of petroleum was performed for the first time. Since petroleum is a rich source of hydrocarbons, its oxidation and electron production resulting in the production of electricity which is green energy is much more efficient than burning it. Electrochemical oxidation of petroleum with Ni-porphyrin-modified graphite electrode in alkaline media and by cyclic voltammetry (CV), chronoamperometry (CA), and electrochemical impedance spectroscopy (EIS) techniques were investigated. Due to the existence of two aqueous and organic phases, adsorption played a vital role in the process. To further confirm the accuracy of petroleum electrooxidation, electrooxidation of its compounds such as xylene and toluene was performed with the Ni-porphyrin electrode and by the mentioned techniques, which confirmed the previous data.



中文翻译:

镍卟啉修饰石墨电极电催化氧化石油、甲苯和二甲苯

在这项研究中,首次对石油进行了电化学氧化。由于石油是碳氢化合物的丰富来源,它的氧化和电子产生导致产生电力,这是一种绿色能源,比燃烧它更有效。采用循环伏安法(CV)、计时安培法(CA)和电化学阻抗谱(EIS)技术,研究了碱性介质中镍卟啉修饰石墨电极对石油的电化学氧化。由于水相和有机相两相的存在,吸附在该过程中起着至关重要的作用。为了进一步证实石油电氧化的准确性,利用镍卟啉电极和上述技术对其化合物如二甲苯和甲苯进行了电氧化,证实了之前的数据。

更新日期:2023-12-22
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