Results are given for a kinetic study of the synthesis of a new fullerene derivative containing a diterpene fragment obtained using HPLC and subsequent mathematical modelling. Kinetic and activation parameters were found for the cyclopropanation of fullerene using the Bingel procedure and a reaction mechanism was proposed. The optimal synthesis conditions were found to entail a slight excess of a chlorine‑containing cyclopropanation agent and carrying out the reaction at room temperature.

中文翻译：

---

含二萜片段的富勒烯衍生物的合成动力学研究

给出了使用 HPLC 和随后的数学模型获得的含有二萜片段的新型富勒烯衍生物的合成动力学研究结果。使用 Bingel 程序找到了富勒烯环丙烷化的动力学和活化参数，并提出了反应机理。发现最佳合成条件需要稍微过量的含氯环丙烷化剂并在室温下进行反应。