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Investigation of an eco-friendly sodium alginate-sodium silicate inhibitor blend for carbon steel in a dynamic salt water environment
Corrosion Science ( IF 8.3 ) Pub Date : 2024-03-16 , DOI: 10.1016/j.corsci.2024.111991
E. De Ketelaere , D. Moed , M. Vanoppen , T. Depover , K. Verbeken

An innovative and sustainable sodium alginate-sodium silicate (SASS) inhibitor blend is investigated for carbon steel in a dynamic 3 wt% NaCl environment. Potentiodynamic scans and electrochemical impedance spectroscopy are performed to estimate inhibition efficiency (IE) and inhibition mechanism. Synergistic, highly efficient (up to 99%) blends are obtained due to formation of a structured film and integration of SA throughout the film thickness. Furthermore, the electrochemical behaviour of multiple SA:SS blend ratios is analysed, pointing to the necessity of sufficient SA and SS to form the most protective blend. Based on these findings, a mechanism for the film formation is also proposed.

中文翻译:

在动态盐水环境中研究用于碳钢的环保型海藻酸钠-硅酸钠抑制剂混合物

研究了一种创新且可持续的海藻酸钠-硅酸钠 (SASS) 抑制剂混合物,用于动态 3 wt% NaCl 环境中的碳钢。进行动电位扫描和电化学阻抗谱来估计抑制效率(IE)和抑制机制。由于结构化薄膜的形成以及整个薄膜厚度中 SA 的集成,获得了协同、高效(高达 99%)的共混物。此外,还分析了多种 SA:SS 混合比例的电化学行为,指出需要足够的 SA 和 SS 来形成最具保护性的混合物。基于这些发现,还提出了成膜机制。
更新日期:2024-03-16
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