当前位置:
X-MOL 学术
›
Phys. Status Solidi B
›
论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Structural and Photoluminescence Characteristics of a Novel Single‐Phase White‐Emitting Phosphor SrBi2Nb2O9:Dy3+
Physica Status Solidi (B) - Basic Solid State Physics ( IF 1.6 ) Pub Date : 2024-03-22 , DOI: 10.1002/pssb.202400049 Xiao Yang 1 , Ruirui Cui 2 , Jun Zhang 3 , Chaoyong Deng 2
Physica Status Solidi (B) - Basic Solid State Physics ( IF 1.6 ) Pub Date : 2024-03-22 , DOI: 10.1002/pssb.202400049 Xiao Yang 1 , Ruirui Cui 2 , Jun Zhang 3 , Chaoyong Deng 2
Affiliation
A group of white light‐emitting phosphors SrBi2 Nb2 O9 :x Dy3+ (SBN:x Dy3+ ) are prepared by high‐temperature solid reaction. The crystal phase, morphology, and photoluminescence (PL) characteristics of the prepared SBN:x Dy3+ are analyzed. The X‐ray diffraction results prove that the synthesized samples are pure phase, in which the shift of the main peak depicted that crystal interplanar distance decreases after Dy3+ replacing Bi3+ . The scanning electron microscope results show that the average crystal size of the sample is ≈1–10 μm. Energy dispersive X‐ray spectroscopy shows that the ratio of element composition of the SBN:x Dy3+ is similar to the theoretical calculation. The PL excitation illustrates the excitation peaks mainly exist at 389, 399, 426, and 450 nm due to the transitions of Dy3+ . For PL, the emission peaks of samples with different doping concentrations are centered at 479 and 573 nm. The ratio of yellow intensity to blue intensity indicates that Dy3+ is located at a high symmetry site, which has the possibility to produce suitable white light. The Commission Internationale de l’Eclairage coordinates of the SBN:x Dy3+ are located near the standard white light coordinate. All these results prove that SrBi2 Nb2 O9 :x Dy3+ can be a potential material in the white light application.
中文翻译:
新型单相白光荧光粉SrBi2Nb2O9:Dy3+的结构和光致发光特性
一组白光荧光粉SrBi2 铌2 氧9 :X 镝3+ (国家编号:X 镝3+ )是通过高温固相反应制备的。制备的SBN的晶相、形貌和光致发光(PL)特性:X 镝3+ 进行分析。 X射线衍射结果证明合成的样品为纯相,其中主峰的移动表明Dy后晶体晶面距离减小。3+ 取代Bi3+ 。扫描电镜结果表明样品的平均晶体尺寸约为1~10 μm。能量色散X射线光谱表明SBN的元素组成比:X 镝3+ 与理论计算类似。 PL 激发表明,由于 Dy 的跃迁,激发峰主要存在于 389、399、426 和 450 nm 处3+ 。对于PL,不同掺杂浓度的样品的发射峰集中在479和573 nm处。黄色强度与蓝色强度之比表明 Dy3+ 位于高对称性位置,有可能产生合适的白光。 SBN 的国际照明委员会坐标:X 镝3+ 位于标准白光坐标附近。所有这些结果都证明SrBi2 铌2 氧9 :X 镝3+ 可以成为白光应用中的潜在材料。
更新日期:2024-03-22
中文翻译:
新型单相白光荧光粉SrBi2Nb2O9:Dy3+的结构和光致发光特性
一组白光荧光粉SrBi