Abstract

It has been shown that the response of the functional property of the deposit on the action of dimensional factors of electrolysis conditions equally determines the dimensional property of the electrolyte. It has been established that the most universal assessment methods of dimensional effects can be formed based on the correlation of dimensionless quantities for a number of specified and directional values of the size factor with a number of corresponding values of the functional parameter of the sediment. It is shown that studying the dimensional properties of electrolytes and deposits, depending on the type of dimensional factors and their scale scales, will expand the capabilities of the electrolytes used, increase the controllability of the formation of the functional parameter of the deposit, obtain new information about the process of deposition of nanostructured deposits, and reveal the factors which previously did not attract attention. A determination method and cell for quantifying the dimensional properties of the precipitate and electrolyte are presented.

中文翻译：

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电镀中的尺寸效应：测定方法及其评价单元

摘要

已经表明，沉积物的功能特性对电解条件的尺寸因素的作用的响应同样决定了电解质的尺寸特性。已经确定的是，基于尺寸因子的多个指定和方向值的无量纲量与沉积物功能参数的多个相应值的相关性，可以形成最通用的尺寸效应评估方法。研究表明，根据尺寸因素的类型及其尺度，研究电解质和沉积物的尺寸特性，将扩大所用电解质的功能，增加沉积物功能参数形成的可控性，获得新的有关纳米结构沉积物沉积过程的信息，并揭示以前没有引起注意的因素。提出了一种用于量化沉淀物和电解质的尺寸特性的测定方法和电池。