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Use of Aliphatic Carboxylic Acid Derivatives for NHC/Photoredox-Catalyzed meta-Selective Acylation of Electron-Rich Arenes
Synthesis ( IF 2.6 ) Pub Date : 2024-03-25 , DOI: 10.1055/a-2281-2975
Yamato Goto 1 , Sho Murakami 2 , Yuto Sumida 3 , Hirohisa Ohmiya 2
Affiliation  

We describe the use of acyl imidazoles derived from aliphatic carboxylic acids for the N-heterocyclic carbene/organic photoredox co-catalyzed meta-selective functionalization of electron-rich arenes. Compared to our previous work, a change of the wavelength of the applied LED light from 440 nm to 390 nm promotes this reaction efficiently.



中文翻译:

使用脂肪族羧酸衍生物进行 NHC/光氧化还原催化富电子芳烃的元选择性酰化

我们描述了使用衍生自脂肪族羧酸的酰基咪唑用于N-杂环卡宾/有机光氧化还原共催化富电子芳烃的间位选择性官能化与我们之前的工作相比,所应用的 LED 光的波长从 440 nm 变为 390 nm 有效地促进了这种反应。

更新日期:2024-03-26
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