This review updates the field of enantioselective iron-catalysed transformations of all types since the beginning of 2020. It shows that asymmetric iron catalysis, that suits the growing demand for greener processes, offers a real opportunity to replace toxic and expensive metals in the near future. The review includes enantioselective iron-catalysed domino reactions; reductions of ketones and imines; cycloadditions; additions to alkenes; coupling reactions; Michael-type reactions; α-functionalisations of carbonyl compounds; sulfoxidations; alkylations of indoles; rearrangement reactions; intramolecular aminations; and miscellaneous reactions.

中文翻译：

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对映选择性铁催化转化。更新

这篇综述更新了自 2020 年初以来所有类型的对映选择性铁催化转化领域。它表明，不对称铁催化满足了对绿色工艺不断增长的需求，为在不久的将来取代有毒和昂贵的金属提供了真正的机会。该综述包括对映选择性铁催化多米诺骨牌反应；减少酮和亚胺；环加成；烯烃的加成物；偶联反应；迈克尔型反应；羰基化合物的α-官能化；磺化氧化；吲哚的烷基化；重排反应；分子内胺化；以及各种反应。