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Superhydrophilic and Oil-Resistant SiO2/PU Fiber Membrane for Oil-In-Water Emulsion Separation under Gravity
Fibers and Polymers ( IF 2.5 ) Pub Date : 2024-04-03 , DOI: 10.1007/s12221-024-00526-3
Li Gao , Haihong Gu , Chunxia Wang , Huanling Wu , Chao Ye

A polyurethane membrane with interlayer channels was developed through electrospinning to separate oily sewage. To enhance its hydrophilicity, hydrophilic silica particles were grafted onto the fiber surface, creating a rough surface. This was done by treating the membrane with oxygen plasma to generate active sites, which were then coupled with 3-aminopropyltriethoxysilane, followed by adding the membrane to a hydrolytic solution of tetraethyl orthosilicate. The resultant membrane had a low water contact angle of 23.3° and excellent underwater oleophobicity, with a high-underwater oil contact angle (varied from 155.9 to 159.7°) and underwater oil sliding angle (ranged from 4.0 to 4.6°) for different types of oils. In addition, the prepared membrane had a good moisture-evaporation rate (4.2 g/h) and water-absorption capacity (273%). It is also oil-resistant and self-cleaning in water, and could efficiently separating oil-in-water emulsion under gravity, with an initial separation flux of 2864 L/m2/h. During cyclic separation of emulsion, the membrane had the oil-retention rate of more than 99.0%, and the final separation flux of the membrane was maintained at 25 L/m2/h.



中文翻译:

超亲水、耐油 SiO2/PU 纤维膜用于水包油乳液重力分离

通过静电纺丝技术开发了一种具有层间通道的聚氨酯膜,用于分离含油污水。为了增强其亲水性,将亲水性二氧化硅颗粒接枝到纤维表面,形成粗糙的表面。这是通过用氧等离子体处理膜以产生活性位点,然后将其与 3-氨基丙基三乙氧基硅烷偶联,然后将膜添加到原硅酸四乙酯的水解溶液中来完成的。所得膜具有23.3°的低水接触角和优异的水下疏油性,对于不同类型的水下油接触角(范围为155.9°至159.7°)和水下油滑角(范围为4.0°至4.6°)油。此外,制备的膜具有良好的水分蒸发速率(4.2 g/h)和吸水能力(273%)。该产品还具有耐油、水中自清洁的特点,可在重力作用下高效分离水包油乳液,初始分离通量为2864 L/m 2 /h。乳液循环分离过程中,膜的保油率大于99.0%,膜的最终分离通量保持在25L/m 2 /h。

更新日期:2024-04-03
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