and Mn-incorporated apatite-type phosphate, Ca(PO)CuMn(O,OH), was successfully synthesized by heating the hydroxyapatite under N at 900 °C after Cu- and Mn-nitrate aqueous solution loading with = 0–0.2 and = 0–0.2 onto it. In Ca(PO)CuMn(O,OH), Cu occupies the apatite channel center site, and the Mn site shifts from the center. The deposition of Cu and Mn species was found to occur upon heating CuMn-Ca-HAp at 600–800 °C in air, accommodating the spinel-type complex metal oxide, (Cu, Mn)O formation from the apatite channel. In addition, the CuO deposition from the Ca(PO)Cu(O,OH) apatite was observed for samples heated at 600–800 °C, whereas MnO was observed for the Ca(PO)Mn(O,OH) sample heated at 800 °C. These results suggest that the presence of Cu in the apatite channel facilitates the deposition of Mn species.

中文翻译：

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将 Cu 和 Mn 离子掺入羟基磷灰石通道并沉积复合金属氧化物

和Mn掺入磷灰石型磷酸盐，Ca(PO)CuMn(O,OH)，通过在Cu-和Mn-硝酸盐水溶液负载= 0–0.2和=后，在N2下在900°C下加热羟基磷灰石成功合成0-0.2 就可以了。在Ca(PO)CuMn(O,OH)中，Cu占据磷灰石通道中心位置，而Mn位置从中心移动。研究发现，在空气中将 CuMn-Ca-HAp 加热至 600-800 °C 时，会发生 Cu 和 Mn 物质的沉积，从而适应从磷灰石通道形成的尖晶石型复合金属氧化物（Cu，Mn）O。此外，在 600–800 °C 加热的样品中观察到 Ca(PO)Cu(O,OH) 磷灰石中的 CuO 沉积，而在 100 °C 加热的 Ca(PO)Mn(O,OH) 样品中观察到 MnO 沉积。 800℃。这些结果表明磷灰石通道中铜的存在促进了锰物质的沉积。