A series of transition metal‐pnictogenide compounds were prepared starting from [(Dipp2NacNac)MCl] (M = Cr, Mn, Fe, Zn) (Dipp2NacNac = HC{C(Me)N(Dipp)}2) and [M´E(SiMe3)2] (M´= Li, K; E = P, As, Sb) as well as [Li(Et2O)nPH2] and [Li(tmeda)AsH2]. In the course of these investigations we were able to characterize all permutations for compounds of the composition [(Dipp2NacNac)ZnE(SiMe3)2] (E = P, As, Sb) and [(Dipp2NacNac)ZnEH2] (E = P, As). Moreover, the synthesis of selected compounds of type [(Dipp2NacNac)ME(SiMe3)2] for M = Cr, Mn, Fe and E = P‐Sb are described. As part of our efforts, we established a number of bonding motifs that are underexplored in the literature to date. All isolated compounds, were examined by NMR spectroscopy, IR spectroscopy, Elemental analysis and X‐Ray structure analysis. DFT calculations on the chromium compounds were performed to investigate the binding situation between chromium and the group 15 element in more detail.

中文翻译：

---

新型过渡金属磷族化合物的合成与表征

以 [(Dipp2NacNac)MCl] (M = Cr, Mn, Fe, Zn) (Dipp2NacNac = HC{C(Me)N(Dipp)}2) 和 [M´E (SiMe3)2] (M´= Li、K；E = P、As、Sb) 以及 [Li(Et2O)nPH2] 和 [Li(tmeda)AsH2]。在这些研究过程中，我们能够表征 [(Dipp2NacNac)ZnE(SiMe3)2] (E = P, As, Sb) 和 [(Dipp2NacNac)ZnEH2] (E = P, As ）。此外，还描述了 M = Cr、Mn、Fe 和 E = P-Sb 的 [(Dipp2NacNac)ME(SiMe3)2] 类型选定化合物的合成。作为我们努力的一部分，我们建立了许多迄今为止在文献中尚未得到充分探索的粘合主题。所有分离的化合物均通过核磁共振光谱、红外光谱、元素分析和 X 射线结构分析进行了检查。对铬化合物进行 DFT 计算，以更详细地研究铬与第 15 族元素之间的结合情况。