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Synthesis and characterization of monodispersed uniform-size aromatic thiolate-protected cobalt nanoclusters for antibacterial and dye degradation studies
Journal of Crystal Growth ( IF 1.8 ) Pub Date : 2024-03-29 , DOI: 10.1016/j.jcrysgro.2024.127688
M. Ramadurai , R. Kirubhakaran , S. Chitra , Ali Saheb , M. Suresh , Vinayagam Mohanavel , Palanivel Velmurugan , Subbaiah Suresh Kumar , Arunachalam Chinnathambi , Sulaiman Ali Alharbi , Nagaraj Basavegowda

In this work, we successfully synthesized monodispersed uniform-sized nanoclusters of less than 7 nm using a dual solvent interaction effect based on nanoclusters formation and growth of thiol-protected (TP) stabilized cobalt nanoclusters (CoNCs) mechanism. The spherical morphology synthesized nanoclusters was confirmed by high-resolution transmission electron microscopy (HRTEM) microscopy. The X-Ray diffraction analysis (XRD) and Selected area electron diffraction (SAED) pattern of the nanoclusters were confirmed the physical properties and crystallographic nature. The obtained small particles play a significant role in antibacterial studies using one gram-positive (Staphylococcus aureus) and one gram-negative (Escherichia coli) bacteria, and sensing of methyl orange in the detection range is 9.2615 × 10 to 2.1760 × 10 M for methyl orange (MO) rapid degradation.

中文翻译:

用于抗菌和染料降解研究的单分散均匀尺寸芳香族硫醇盐保护的钴纳米团簇的合成和表征

在这项工作中,我们利用基于纳米团簇形成和硫醇保护(TP)稳定的钴纳米团簇(CoNC)机制的双溶剂相互作用效应,成功合成了小于7 nm的单分散均匀尺寸纳米团簇。通过高分辨率透射电子显微镜(HRTEM)显微镜证实了合成纳米团簇的球形形态。 X射线衍射分析(XRD)和选区电子衍射(SAED)图谱证实了纳米团簇的物理性质和晶体学性质。所获得的小颗粒在使用一种革兰氏阳性菌(金黄色葡萄球菌)和一种革兰氏阴性菌(大肠杆菌)的抗菌研究中发挥着重要作用,甲基橙的检测范围为 9.2615 × 10 至 2.1760 × 10 M甲基橙(MO)快速降解。
更新日期:2024-03-29
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