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Physical properties and thermal stability of the GeTe2-x(SeSb)x (x = 0, 0.2, 0.4, 0.6) chalcogenide glasses
Pramana ( IF 2.8 ) Pub Date : 2024-04-15 , DOI: 10.1007/s12043-024-02748-9
Devesh Pati Tripathi , Surbhi Agarwal , D K Dwivedi , Pooja Lohia , Rajesh Kumar Yadav , M Khalid Hossain

Physical parameters are necessary to determine the suitability of the chalcogenide materials for specific applications. The present study reports the physical characteristics of the multicomponent GeTe2-x(SeSb)x (x = 0, 0.2, 0.4, 0.6) chalcogenide glasses synthesised by the melt-quench technique. The differential scanning calorimetric (DSC) technique has been used at separate heating rates β = 5, 10, 15, 20 °C\(/\)min. XRD and SEM–EDX studies have been carried out for structural and morphological analyses. The average coordination number and constraints of the compound have been calculated which indicates that the composition forms a glassy system. Lone pair electrons present in the composition have been evaluated. R parameter has a value greater than 1, indicating that the composition has sufficient chalcogen, chalcogen–chalcogen and heteropolar bonds. The overall bond energy of the compound has been calculated using the chemical bonding approach to understand the fine-structure properties of the compound. Cohesive energy has been observed to increase with composition. Thermal stability, glass transition temperature and glass forming ability of the compound have been calculated using different relations like Saad and Poulin relation, Dieztal relation, Hurby parameter (Hr) and reduced glass transition temperature (Trg) and studied theoretically to examine the thermal stability of the composition that shows that the prepared samples are suitable for data storage.



中文翻译:

GeTe2-x(SeSb)x (x = 0, 0.2, 0.4, 0.6) 硫系玻璃的物理性能和热稳定性

物理参数对于确定硫族化物材料对特定应用的适用性是必要的。本研究报告了 通过熔融淬火技术合成的多组分GeTe 2- x (SeSb) x ( x = 0, 0.2, 0.4, 0.6) 硫属化物玻璃的物理特性。差示扫描量热 (DSC) 技术已在单独的加热速率β  = 5、10、15、20 °C \(/\)分钟下使用。已进行 XRD 和 SEM-EDX 研究以进行结构和形态分析。计算了化合物的平均配位数和约束,这表明该组合物形成玻璃态系统。已经评估了组合物中存在的孤对电子。R参数的值大于1,表明该组合物具有足够的硫属元素、硫属元素-硫属元素和异极键。使用化学键合方法计算了化合物的总键能,以了解化合物的精细结构特性。已观察到内聚能随着成分的增加而增加。利用Saad和Poulin关系、Dieztal关系、Hurby参数( H r )和约化玻璃化转变温度( T rg )等不同关系式计算了化合物的热稳定性、玻璃化转变温度和玻璃形成能力,并进行了理论研究以检验热稳定性组合物的稳定性表明所制备的样品适合数据存储。

更新日期:2024-04-15
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