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Regioselective Syntheses of 1,4- and 1,6-Dicarbonyl Compounds via Photoredox-Based Oxidative Heterocoupling of Enolsilanes with Oxygen as an Oxidant
Organic Letters ( IF 5.2 ) Pub Date : 2024-04-18 , DOI: 10.1021/acs.orglett.4c00768
Xinyu Tan 1 , Zhilin Song 1 , Xinting Liang 1 , Zhenbao Wang 1 , Hongyi Yuan 1 , Zhongchao Zhang 1 , Zhen Yang 1, 2, 3
Affiliation  

A photoredox-based oxidative heterocoupling of enolsilanes to the corresponding 1,4- and 1,6-dicarbonyl compounds was developed by using Mes-Acr+BF4 as the photocatalyst, and oxygen was used as the oxidant. This newly developed chemistry adheres to the principles of atom economy, step economy, and redox economy, making it a concise and efficient method.

中文翻译:

通过烯醇硅烷与氧作为氧化剂的基于光氧化还原的氧化杂偶联来区域选择性合成 1,4- 和 1,6-二羰基化合物

使用Mes-Acr + BF 4 作为光催化剂,并使用氧气作为氧化剂,开发了烯醇硅烷与相应1,4-和1,6-二羰基化合物的基于光氧化还原的氧化杂偶联。这种新开发的化学方法遵循原子经济性、步骤经济性和氧化还原经济性的原则,使其成为一种简洁高效的方法。
更新日期:2024-04-19
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