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The Influence of the Anode Structure on the Electrical Properties of a Solid Oxide Fuel Cell
Materials Science ( IF 0.9 ) Pub Date : 2024-04-23 , DOI: 10.1007/s11003-024-00796-5
Ye. M. Brodnikovskyi , V. Ya. Podhurska , N. O. Lysunenko , D. M. Brodnikovskyi , I. O. Polishko , O. V. Bezdorozhev , A. A. Kyrysha , O. D. Vasylyev

The volt-ampere and impedance characteristics of solid oxide fuel cells (SOFC) at 800°C depending on the structure of the anode, electrolyte, and cathode were studied. The combination of the 10Sc1CeSZ–NiO anode with the 10Sc1CeSZ electrolyte, the GDC barrier cathode layer, and the LSCF–GDC cathode leads to an increase in the electrical properties of this SOFC in 1.4 and 2.8 times compared to the SOFC of the 3.5YSZ–NiO/8YSZ/LSM–8YSZ system to the SOFC of the 10Sc1CeSZ–NiO/8YSZ/LSM–8YSZ system, respectively. At the same time, the incompatibility of the 10Sc1CeSZ–NiO anode and the 8YSZ electrolyte was revealed, which is associated with cerium migration during sintering of the half-cell.



中文翻译:

阳极结构对固体氧化物燃料电池电性能的影响

研究了固体氧化物燃料电池 (SOFC) 在 800°C 下取决于阳极、电解质和阴极结构的伏安和阻抗特性。 10Sc1CeSZ-NiO 阳极与 10Sc1CeSZ 电解质、GDC 势垒阴极层和 LSCF-GDC 阴极的组合使该 SOFC 的电性能比 3.5YSZ- 的 SOFC 提高了 1.4 倍和 2.8 倍。 NiO/8YSZ/LSM–8YSZ 系统分别到 10Sc1CeSZ–NiO/8YSZ/LSM–8YSZ 系统的 SOFC。同时,10Sc1CeSZ-NiO阳极和8YSZ电解质的不相容性也被揭示,这与半电池烧结过程中的铈迁移有关。

更新日期:2024-04-24
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