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Enhanced photocatalytic CO2 reduction by controlled oxygen vacancy generation and co-constructed heterojunction strategy for Pd/CeO2 Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-04-16 Fanlin Kong, Xiaoyan Lu, Jing Xie, Zhenjiang Lu, Jindou Hu, Yali Cao
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Large enhancement of electrochemical biomass oxidation by optimizing the competitive adsorption of HMF and OH− on doped CoOx Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-04-17 Tianqi Nie, Guihao Liu, Ziheng Song, Tianyang Shen, Xiaoliang Sun, Tianrui Yu, Sha Bai, Lirong Zheng, Yu-Fei Song
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Achieving high-sensitivity dual-mode optical thermometry via phonon-assisted cross-relaxation in a double-perovskite structured up-conversion phosphor Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-04-15 Houhe Dong, Zonghao Lei, Shikun Su, Wenhua Yang, Xuyang Zhang, Wenying Teng, Guangyue Zu, Bing Teng, Degao Zhong
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Hysteretic magnetism–dielectricity switching in 2D Hofmann type spin-crossover compounds Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-04-11 Nian-Tao Yao, Meng-Jia Shang, Han-Han Lu, Qiang Liu, Wen Wen, Shi-Hui Zhang, Liang Zhao, Hiroki Oshio, Yin-Shan Meng, Tao Liu
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Near-infrared-photoinduced metamagnet based on a layered cyanido-bridged Co–W assembly with π–π interactions Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-04-09 Kazuki Nakamura, Koji Nakabayashi, Shota Kobayashi, Shin-ichi Ohkoshi
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Structural and electrochemical properties of Tan+1Cn MXene anode materials for metal-ion batteries Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-04-11 Jiayi Guo, Danni Hu, Chenqi Bai, Lina Xu, Hongping Xiao, Qian Shi, Xinhua Li, Xi'an Chen, Yingjin Ma, Guoyong Fang
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Insights into the modulation mechanisms of multiple active sites in a conjugated small molecule towards organic cathode capacity from first-principles Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-04-11 Zhaopeng Sun, Hao Tian, Meng Zhang, Yi Zhang, Zhiping Li, Weiwei Huang
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Metal– and covalent organic frameworks for photocatalytic CO2 reduction coupled with H2O oxidation Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-04-09 Xiao-Xiang Zhou, Yongshi Ye, Qia-Chun Lin, Wei-Ming Liao, Jun He
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Efficient photocatalytic hydrogen evolution of g-C3N4/Vs-SnS2/CdS through a sulfur vacancy-rich SnS2 induced charge storage effect Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-04-09 Fangyuan Xing, Junyan Li, Chengzhi Wang, Shaohua Jin, Haibo Jin, Jingbo Li
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Nanocarbon armor reinforced Ag particles to build a high-rate and long-lifespan aqueous Zn2+/Cl− dual-ion battery Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-04-09 Wenbo Guo, Tianyuan Zhang, Guangchang Shu, Leiyu Fan, Zhouxiang Wu, Lei Yan, Liyuan Zhang, Haoxiang Yu, Ting-Feng Yi, Jie Shu
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Efficient doped and non-doped light-emitting diodes based on a TADF-emitting Cu4Br4 cluster Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-04-08 Xin Lu, Shao-Jie Wu, Ya-Shu Wang, Shan-Yue Wei, Lingyi Meng, Xi-He Huang, Xu-Lin Chen, Can-Zhong Lu
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Energetic copper(II) quadridentate chelate: a novel green laser-sensitive primary explosive Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-04-08 Qi Zhang, Ruibing Lv, Ying Wang, Zhenghang Luo, Pengyang Pan, Tingwei Wang, Quancheng Liu
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Facile access to tetra-substituted FeIIFeII biomimetics for the oxidized state active site of [FeFe]-hydrogenases Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-04-03 Xin-Ping Gao, Shu-Fen Bai, Yan-Lan Wang, Shuang Lü, Qian-Li Li
In this study, we present a convenient method to obtain two types of novel tetra-substituted Fe/Se salts through a dehalogenation reaction, aiming to advance research on mimicking the FeIIFeII oxidation state of [FeFe]-H2ases. Initially, by treating [Fe2(μ-SeBn)2(CO)4(dppv)] (Bn = CH2C6H5, dppv = cis-1,2-bis(diphenylphosphino)ethylene) with one equivalent of dppv under UV and reflux conditions, the
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Electrochemical frontiers in the nitrogen cycle Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-04-04 Xuping Sun, Jieshan Qiu, Chenghua Sun
A graphical abstract is available for this content
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Disruption of lipid metabolism to induce ferroptosis using multifunctional fibrate-Pt(IV) prodrugs for cancer treatment Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-04-05 Peng Sun, Jia-Qian Wang, Qiang Xie, Xuan-Lin Ren, Xin Qiao, Jing-Yuan Xu
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Integrating multiple regulatory strategies: phase, morphology and interface engineering to construct a hierarchical Ni2P–MoS2/rGO heterostructure catalyst for efficient oxygen reduction reaction Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-04-04 Xinyi Wang, Jing Jin, Zeyuan Gao, Li Hou, Xiwen Tao, Jing Wang, Yueqi Zhao, Faming Gao
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Defect-rich Pd@PdOs nanobelts for electrocatalytic oxidation of ethylene glycol Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-04-03 Xianlong Wang, Xuewen Wei, Ruifan Zhang, Min Yan, Ranran Wei, Xiaoying Zhang, Zhaoyou Zhu, Yinglong Wang, Xinling Zhao, Shuli Yin
Reasonable design and development of catalysts with specific components and morphologies can effectively improve the catalytic performance of nanomaterials. Here, we propose a controllable strategy to prepare atomically thin defect-rich Pd@PdOs nanobelts (Pd@PdOs NBs) with a thickness of 1.8 nm for ethylene glycol oxidation reaction (EGOR). Due to the abundant structural defects and extended active
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Synthesis and characterization of a CsPbCl3 perovskite doped with Nd3+: structural, optical, and energy transfer properties Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-04-02 Mariusz Stefanski, Bartosz Bondzior, Adam Basinski, Maciej Ptak, Bibo Lou, Chong-Geng Ma
The purpose of this paper is to synthesize a micrometric inorganic perovskite CsPbCl3:Nd3+ and investigate the impact of doping with rare-earth ions on structural and optical properties, as well as energy transfer pathways between the host and dopant. Herein, we report the solid-state reaction synthesis of a concentration series of CsPbCl3:x%Nd3+ annealed under a nitrogen atmosphere. Additional doping
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Contributors to the Inorganic Chemistry Frontiers Emerging Investigator Series 2022–2023 Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-04-02
In the summer of 2022, Inorganic Chemistry Frontiers was pleased to launch an ongoing Emerging Investigators themed issue to highlight the best research being conducted by scientists in the early stages of their independent careers. Each contributor was recommended as carrying out work with the potential to influence future directions in inorganic chemistry. Congratulations to all the researchers featured
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The smallest endohedral borafullerene: structural isomerization, electronic properties, aromaticity and reactivity of U@C27B Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-04-02 Xinde Li, Lei Lou, Peng Jin
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A composite electrolyte based on aluminum oxide filler/polyester polymer via in situ thermal polymerization for long-cycle sodium metal batteries Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-03-28 Qiujun Wang, Xin He, Di Zhang, Zhaojin Li, Huilan Sun, Qujiang Sun, Bo Wang, Li-Zhen Fan
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Discovery of excellent ultraviolet nonlinear optical materials in chlorates and bromates with highly stereochemically active lone pairs Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-03-27 Chun-Li Hu, Qian-Qian Chen, Fang Kong, Jiang-Gao Mao
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Large-scale fabrication of ZIF-derived electrocatalysts for industrial oxygen evolution Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-03-27 Liangjun Chen, Zhuowen Huangfu, Xuelin Yang, Hang Lei, Zilong Wang, Wenjie Mai
The laboratory-scale catalyst synthesis is far from reaching the expectations of industrial-scale water electrolysis, and the bottleneck is the large-scale preparation of electrocatalysts. Herein, a cheap, efficient, and durable electrocatalyst (Mo–Co–O-ZIF) with two-dimensional nanosheet arrays in situ grown on pre-oxidized nickel foam is successfully synthesized through a time and energy-saving strategy
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Durable dielectric switching and photo-responsivity in a Dion–Jacobson hybrid perovskite semiconductor Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-03-25 Peng Wang, Xinling Li, Huang Ye, Qianwen Guan, Yifei Wang, Yaru Geng, Chengshu Zhang, Hang Li, Junhua Luo
Two-dimensional hybrid perovskite (2DHPs) semiconductors have shown great potential in multifunctional applications, especially dielectric switches and photoelectric detection owing to their diverse structural feasibility and excellent semiconducting features. However, most of the reported 2DHPs belong to the Ruddlesden–Popper (R–P) type, which unavoidably suffers from weak van der Waals interactions
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Effects of weak intramolecular interactions and distortions from trigonal prismatic coordination on the magnetic properties of zero-field Co(II) single-ion magnets Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-03-26 Ben Zhang, Yang Zhou, Hao-Yi Huang, Xiao-Le Zhang, Yi Xiang, Yanbo Shi, Chennan Zhang, Aihua Yuan, Xingwei Cai, Lei Chen, Yi-Quan Zhang, Zhao-Bo Hu
The mononuclear cobalt(II) complexes [Co(LN8)](BPh4)2·C4H10O (1-BPh4) and [Co(LN8)](NO3)2·CH3CN (2-NO3) (LN8 = 1,4,7,10-tetrakis(2-pyridinemethyl)-1,4,7,10-tetraaza-cyclododecane) have been synthesized and fully characterized. They differ well beyond a formal replacement of the counter anions, with their Co(II) centers in significantly different coordination geometries. In 1-BPh4, the Co(II) ion is
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An unusual reaction in nitromethane solution: use of the Cp*Rh moiety to form Prussian blue analogues Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-03-26 Huirong Ma, Liangchen Liu, Yuluan Liao, Huatian Shi, Po Sun, Weibin Yu
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Rational design for broad near-infrared emission from a two-sited Rb2LiAlF6:Cr3+ phosphor with high efficiency and thermal stability for spectroscopic applications Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-03-26 Song Qing, Jing Wan, Tao Yang, Qiang Zhou, Yayun Zhou, Zhengliang Wang, Dawei Wen, Mingmei Wu
The exploration of high-performance near-infrared phosphors has attracted widespread attention. In this work, a brand new Rb2LiAlF6:Cr3+ (denoted as RLAF:Cr) phosphor has been constructed by the substitution of Al3+ ions with Cr3+ ions. Evidence shows that two sets of near-infrared emission bands, which originated from two types of Cr3+ sites, were observed upon blue light excitation. These emission
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Controlling the structural and adsorption features of polyoxovanadate-based metal–organic clusters by adjustable template effect Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-03-26 Yan-Hu Wang, Ke-Wei Tong, Chao-Qin Chen, Jing Du, Guo-Ping Yang, Peng Yang
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Competition mechanism of self-trapped excitons and Te4+ ions emission in the Te4+ doped vacancy-ordered double perovskite Rb2HfCl6 and its excellent properties Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-03-25 Ruxin Liu, Kaishun Zou, Guanglu Zhang, Min Feng, Mingxuan Li, Juncheng Liu
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Modulating Mn self-reduction and multimodal luminescence in CaSb2O6 through La3+ doping for quadruple-mode dynamic anti-counterfeiting and optical temperature sensing applications Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-03-25 Fenzhong Long, Lu Xie, Jiawei Fu, Kaian Shan, Huihui Fei, Xinmin Zhang
Luminescent materials play a key role in the field of optical anti-counterfeiting. However, the development of multimode, multi-color dynamic phosphors, making optical anti-counterfeiting more advanced and practical, remains a great challenge. Herein, multimode luminescence (PL, PersL, TL, PSL, and PSPL), dynamic multi-color emission phosphors based on a single CaSb2O6 (CSO) host doped with manganese
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Synergistic role of hydrogen bonding and band degeneracy leads to enhanced X-ray detection in HPIP-(NH4)0.7Cs0.3Br3·H2O perovskites Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-03-25 Pengxiang Dong, Chensheng Lin, Xin Zhao, Yicong Lv, Ning Ye, Min Luo
Metal-free perovskites (MFPs) have emerged as a promising material for the development of eco-friendly, non-toxic, and wearable X-ray detectors. However, the advancement of MFPs has been hindered by several significant challenges, most notably their lower absorption coefficient and susceptibility to oxidation and degradation in iodine-based detectors. To address these issues, this study proposes a
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NH3 plasma-etching-derived porous N-doped carbon nanotubes with FeP nanoparticles and intrinsic carbon defects for boosting oxygen reduction in rechargeable Zn–air batteries Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-03-25 Bing Chen, Minjie Zhou, Na Zhang, Xianglin Deng, HaiHua Yang
Modulating intrinsic activity and coupling with transition metal phosphides are encouraging strategies to enhance the electrochemical performance of carbon-based materials. In this study, N-doped carbon nanotubes were derived from polyaniline nanotubes by the guided growth of the soft template micelles comprising Fe3+ ions and methyl orange. Phytic acid was employed to detain Fe3+ ions from washing
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Pb3.5GeS4Br3: the first phase-matching thiogermanate halide infrared nonlinear optical material Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-03-22 Jiazheng Zhou, Hongshan Wang, Junjie Liu, Xin Su, Yu Chu, Jiale Qu, Xiangzhan Jiang
Two new thiohalides Pb3GeS4Br2 and Pb3.5GeS4Br3 have been synthesized by introducing Pb2+ into the thiogermanate system. The compounds crystallize in centrosymmetric P21/c (Pb3GeS4Br2) and non-centrosymmetric P63 (Pb3.5GeS4Br3) space groups, respectively. To the best of our knowledge, Pb3GeS4Br2 and Pb3.5GeS4Br3 are the first Pb-containing thiogermanate halides, and the latter is the first phase-matching
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Recent progress on the photocatalytic hydrogen evolution reaction over a metal sulfide cocatalyst-mediated carbon nitride system Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-03-22 Xunhuai Huang, Junpeng Song, Guanyu Wu, Zhihuan Miao, Yanhua Song, Zhao Mo
Under the dual background of energy and environment, the use of precious metal-free carbon nitride (g-C3N4) for photocatalytic H2 evolution has attracted the attention of scientific researchers. Nonetheless, bulk g-C3N4 suffers from serious drawbacks, such as severe photo-generated carrier recombination and scarcity of active sites. Among numerous modification strategies, cocatalyst loading can extract
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Sodium ion pre-intercalation regulates the electron density and structural stability of vanadium oxide nanowires for Ca–ion batteries Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-03-21 Huajie Feng, Yize Wang, Wenda Qiu, Zixi Liu, Yaping Tao, Xihong Lu
Benefiting from the abundant resource, low cost, and high operating potential, calcium–ion batteries (CIBs) have attracted great attention as emerging energy storage devices over lithium-based systems. Nevertheless, the progression of CIBs remains at an early stage and faces significant challenges in finding suitable cathode materials and electrolytes. In this work, we pioneer a novel sodium ion-pre-intercalated
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Recent progress in aluminum anodes for high-performance rechargeable aqueous Al-ion batteries Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-03-21 Le Li, Shaofeng Jia, Yue Shi, Conghui Wang, Hengwei Qiu, Yongqiang Ji, Minghui Cao, Dan Zhang
The growing market for electric vehicles and upcoming grid-scale storage systems is spurring the development of renewable energy storage technologies. Rechargeable aqueous aluminum-ion batteries (AIBs) are considered ideal for large-scale energy storage because of their cost-competitiveness, simplicity of manufacturing, eco-friendliness, high intrinsic safety, and high theoretical energy density. In
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Gold nanoparticles cross cell-subcellular barriers for biological regulation Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-03-21 Xiang Zheng, Guangchao Qing, Yaru Jia, Fangzhou Li, Lanju Xu, Xing-Jie Liang, Jinchao Zhang
Biological barriers are crucial to homeostasis, but they still remain a major cause of the insufficient therapeutic outcomes of drugs. Numerous nanocarriers have been developed currently to escort drugs cross the blood barrier and blood–tissue barriers. However, the cellular or subcellular barriers confronted by nanomedicines still need to be breached. Therefore, elucidating the mechanism by which
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Tailoring two magic number Au13 nanoclusters with N-containing diphosphine ligands: a classical icosahedral core vs. an unprecedented UFO- shaped core Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-03-21 Jing Liu, Jia-Chuan Liu, Hai-Ling Wang, Pei-Yu Liao, Jian-Hua Jia, Ming-Liang Tong
Two magic number Au13 nanoclusters, [Au13(PNP)5Cl2]Cl3 and [Au13(Hdppa)6]Cl5, with the same nuclearity number but completely distinct configurations, were elaborately constructed using N-containing diphosphine ligands (PNP or Hdppa). Significantly, the metal core of [Au13(PNP)5Cl2]3+ is a classical Au13 icosahedron, while the [Au13(Hdppa)6]5+ core presents a “UFO”-shaped polyhedron, which is illuminated
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Rapid Joule heating synthesis of Ni doped into porous honeycomb C3N4 with greatly improved photocatalytic H2 production Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-03-21 Zehui Zhao, Guangmin Ren, Zisheng Zhang, Xiangchao Meng, Zizhen Li
Photocatalytic water splitting is one of the sustainable and environmentally-friendly methods for producing hydrogen. Bulk C3N4 shows promise in the photocatalytic production of H2, but its activity is greatly limited by low number of reactive sites. Herein, Ni-doped porous honeycomb C3N4 (Ni/HCN-VN) was prepared for photocatalytic hydrogen production using a morphology modulation method followed by
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Harnessing nanoscale spatial effects in inner-modified zeolitic imidazolate framework-8 for enhanced Knoevenagel condensation reaction Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-03-20 Semi Kim, Seojeong Woo, Cheongwon Bae, Yuri Jeon, Yeeun Seong, Song Li, Juyeong Kim
Metal–organic frameworks (MOFs) have played a pivotal role in catalysis, driven by their remarkable surface areas and structural versatility. The structural manipulation of zeolitic imidazolate frameworks (ZIFs) has shed light on the impact of size, facet orientation, and functional groups in enhancing their catalytic performance. However, these strategies possess inherent limitations, necessitating
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Hafnia-based oxide enhanced Ga2O3-based photodetectors via band engineering with ultralarge responsivity Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-03-19 Han Wu, Jiaying Shen, Lincong Shu, Jie Dai, Shulin Sha, Zeng Liu, Weihua Tang, Yuehui Wang, Zhenping Wu, Kun Lin, Qiang Li, Jun Miao, Xianran Xing
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N-heterocyclic carbene-stabilized Cu9 clusters with combined thermally activated delayed fluorescence and phosphorescence Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-03-19 Lin-Mei Zhang, Mo Xie, Hui-Zhi Wei, Shang-Fu Yuan, Dong-Sheng Li, Tao Wu
Metal clusters with both phosphorescence and thermally activated delayed fluorescence (TADF) at room temperature, allowing for efficient light emission and a short lifetime, are of particular interest. However, such clusters remain rare due to the challenge of achieving comparable and effective transitions T1 → S1 → S0 and T1 → S0 simultaneously. Herein, we report two copper clusters, [Cu9{(py)2im
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Perovskite photoinitiated RAFT-mediated polymerization-induced self-assembly for organic–inorganic hybrid nanomaterials Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-03-18 Bingfeng Shi, Wanchao Hu, Shiyi Li, Zhinan Xia, Changli Lü
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sp2–sp cross-carbanion coupling at a rare-earth center leading to the formation of carbon–carbon double bonds Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-03-18 Zhengqi Chai, Ze-Jie Lv, Wei Liu, Jinxiao Yang, Junnian Wei, Wen-Xiong Zhang
In contrast to transition metals, rare-earth metal-promoted sp2–sp carbon–carbon coupling through reductive elimination cannot be realized due to the inaccessibility of two-electron metal-based redox couples. Herein, we report that sp2–sp cross-carbanion coupling has been realized in the reaction of rare-earth azametallacyclopentadienes 2 with alkyl and aryl terminal alkynes. The reaction of 2, which
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Adhesion, stability, structural and electronic properties of perovskite/BaWO4 heterostructures: first-principles and experimental characterizations Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-03-18 Yao Guo, Shiding Zhang, Zhaoyu Zhang, Yuanbin Xue, Jianxin Li, Haixiang Song, Yuhua Wang, Qing Shen
The poor stability of lead halide perovskites poses a critical challenge for realizing potential applications. Constructing latticed-matched perovskite/BaWO4 heterostructures is highly advantageous for achieving enhanced stability. However, there is limited knowledge about the interfacial properties. Herein, we conducted combined first-principles and experimental investigations of the perovskite/BaWO4
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Electrochemical conversion of 5-hydroxymethylfurfural over CuNi bimetallic catalysts: the synergistic effect of interfacial active sites Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-03-18 Yiwei Zhao, Chao Zhang, Shuangxi Xing, Zuhang Jin, Tingting Xiao
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Ultrathin 2D–2D NiFe LDH/MOF heterojunction nanosheets: an efficient oxygen evolution reaction catalyst for water oxidation Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-03-18 Haoran Yin, Shibiao Su, Di Yao, Lixia Wang, Xinqiang Liu, Tayirjan Taylor Isimjan, Xiulin Yang, Dandan Cai
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Crystal structure, Bi3+ yellow luminescence, and high quantum efficiency of Ba3SbAl3Ge2O14:Bi3+ phosphor for white light-emitting diodes Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-03-18 Huihui Fei, Baolong Jing, Jin Han, Kaian Shan, Dongming Cheng, Xueqing Xu, Xinmin Zhang, Jing Wang
Bi3+-activated luminescent materials have attracted increasing attention owing to their strong excitation in the near-ultraviolet (NUV) range instead of the visible range. Such a unique feature allows them to avoid reabsorption among phosphors, resulting in their growing popularity in research and applications. However, the majority of Bi3+-doped phosphors suffer from low quantum efficiency, imposing
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Correction: In situ construction of a continuous ionic conductive coating for a high-performance Li3VO4 anode Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-03-15 Lulu Wang, Cheng Zeng, Jianing Liang, Chun Zhai, Hao Liu, Tianyou Zhai, Huiqiao Li
Correction for ‘In situ construction of a continuous ionic conductive coating for a high-performance Li3VO4 anode’ by Lulu Wang et al., Inorg. Chem. Front., 2024, 11, 1177–1185, https://doi.org/10.1039/D3QI02235H.
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An hourglass-shaped nickel-based polyoxometalate crystalline material as a highly efficient bifunctional electrocatalyst for the oxygen evolution reaction and detection of H2O2 Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-03-13 Yajie Li, Na Zhu, Zhixuan Su, Xiaoli Hu, Zhiyu Dou, Zhongmin Su
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Bulk single crystal growth and optoelectronic properties of the quasi-two-dimensional perovskites (CH3NH3)3Bi2X9 (X− = Br− and I−) Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-03-13 Zhiyuan Li, Xiangjun Wang, Peng Zhao, Jingquan Liu, Xiangxin Tian
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Structural isomerism-tuned magnetisation relaxation dynamics in lanthanide coordination complexes Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-03-07 Steen H. Hansen, Christian D. Buch, Stergios Piligkos
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Isostructural chiral metal–organic frameworks with metal-regulated performances for electrochemical enantiomeric recognition of tyrosine and tryptophan Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-03-12 Ran An, Qiu-Yan Hu, Liu-Yang Song, Xu Zhang, Rui-Xuan Li, En-Qing Gao, Qi Yue
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Selective syntheses of homoleptic Ir(III) complexes bearing di-CF3-functionalized benzoimidazol-2-ylidenes for generation of blue phosphorescence Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-03-12 Jie Yan, Yi Pan, I-Che Peng, Wen-Yi Hung, Bingjie Hu, Guowei Ni, Shek-Man Yiu, Yun Chi, Kai Chung Lau
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Enhancing the separation of C2H4/C2H6 in customized MOR zeolites Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-03-11 Hongwei Chen, Binyu Wang, Bin Zhang, Yongheng Ren, Jiuhong Chen, Jiabao Gui, Xiufeng Shi, Wenfu Yan, Jinping Li, Libo Li
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Structural phase transition drives outright photoluminescence quenching and dielectric duple bistable switching Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-03-11 Zhi-Jie Wang, Ming-Jing Shen, Zhi-Peng Rao, Pei-Zhi Huang, Meng-Meng Lun, Bo-Wen Deng, Jun-Yi Li, Chang-Feng Wang, Hai-Feng Lu, Da-Wei Fu, Yi Zhang
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Achieving a near-unity photoluminescence quantum yield and high stability of CsPbI3 nanoplatelets by hydroiodic acid-assisted ligand treatment Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-03-10 Zongnan Li, Yusheng Song, Sheng Cao, Ke Xing, Zhentao Du, Bingsuo Zou, Jialong Zhao
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Boosting structural variety and catalytic activity of porphyrinic metal–organic frameworks by harnessing bifunctional ligands Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-03-10 Wei Wu, Xiu-Liang Lv, Tao He, Guang-Rui Si, Hongliang Huang, Lin-Hua Xie, Yabo Xie, Jian-Rong Li
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Three in one: a cadmium bismuth vanadate NLO crystal exhibiting a large second-harmonic generation response and enhanced birefringence Inorg. Chem. Front. (IF 7.0) Pub Date : 2024-03-09 Shuya Liu, Conggang Li, Jinmiao Jiao, Yuheng She, Tinghui Zhang, Dianxing Ju, Ning Ye, Zhanggui Hu, Yicheng Wu