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Deciphering functional roles of protein succinylation and glutarylation using genetic code expansion Nat. Chem. (IF 21.8) Pub Date : 2024-03-26 Maria Weyh, Marie-Lena Jokisch, Tuan-Anh Nguyen, Maximilian Fottner, Kathrin Lang
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Blocking and rescuing tryptophan interactions Nat. Chem. (IF 21.8) Pub Date : 2024-03-25 Aidan K. Haney, T. Ashton Cropp
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Silicon-RosIndolizine fluorophores with shortwave infrared absorption and emission profiles enable in vivo fluorescence imaging Nat. Chem. (IF 21.8) Pub Date : 2024-03-25 William E. Meador, Eric Y. Lin, Irene Lim, Hannah C. Friedman, David Ndaleh, Abdul K. Shaik, Nathan I. Hammer, Boqian Yang, Justin R. Caram, Ellen M. Sletten, Jared H. Delcamp
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Catalyst self-assembly accelerates bimetallic light-driven electrocatalytic H2 evolution in water Nat. Chem. (IF 21.8) Pub Date : 2024-03-25 Isaac N. Cloward, Tianfei Liu, Jamie Rose, Tamara Jurado, Annabell G. Bonn, Matthew B. Chambers, Catherine L. Pitman, Marc A. ter Horst, Alexander J. M. Miller
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Dynamic three-dimensional structures of a metal–organic framework captured with femtosecond serial crystallography Nat. Chem. (IF 21.8) Pub Date : 2024-03-25 Jaedong Kang, Yunbeom Lee, Seonggon Lee, Hosung Ki, Jungmin Kim, Jain Gu, Yongjun Cha, Jun Heo, Kyung Won Lee, Seong Ok Kim, Jaehyun Park, Sang-Youn Park, Sangsoo Kim, Rory Ma, Intae Eom, Minseok Kim, Jeongho Kim, Jae Hyuk Lee, Hyotcherl Ihee
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Non-modular fatty acid synthases yield distinct N-terminal acylation in ribosomal peptides Nat. Chem. (IF 21.8) Pub Date : 2024-03-25 Hengqian Ren, Chunshuai Huang, Yuwei Pan, Shravan R. Dommaraju, Haiyang Cui, Maolin Li, Mayuresh G. Gadgil, Douglas A. Mitchell, Huimin Zhao
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Identifying phase-separating biomolecular condensates in cells Nat. Chem. (IF 21.8) Pub Date : 2024-03-22
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Enantioselective propargylic amination and related tandem sequences to α-tertiary ethynylamines and azacycles Nat. Chem. (IF 21.8) Pub Date : 2024-03-19 Zheng Zhang, Ying Sun, Yi Gong, Da-Liang Tang, Hui Luo, Zhi-Peng Zhao, Feng Zhou, Xin Wang, Jian Zhou
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Cage escape governs photoredox reaction rates and quantum yields Nat. Chem. (IF 21.8) Pub Date : 2024-03-18 Cui Wang, Han Li, Tobias H. Bürgin, Oliver S. Wenger
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High-throughput and proteome-wide discovery of endogenous biomolecular condensates Nat. Chem. (IF 21.8) Pub Date : 2024-03-18 Pengjie Li, Peng Chen, Fukang Qi, Jinyun Shi, Wenjie Zhu, Jiashuo Li, Peng Zhang, Han Xie, Lina Li, Mengcheng Lei, Xueqing Ren, Wenhui Wang, Liang Zhang, Xufu Xiang, Yiwei Zhang, Zhaolong Gao, Xiaojun Feng, Wei Du, Xin Liu, Limin Xia, Bi-Feng Liu, Yiwei Li
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RNA modulates hnRNPA1A amyloid formation mediated by biomolecular condensates Nat. Chem. (IF 21.8) Pub Date : 2024-03-12 Chiara Morelli, Lenka Faltova, Umberto Capasso Palmiero, Katarzyna Makasewicz, Marcell Papp, Raphaël P. B. Jacquat, Dorothea Pinotsi, Paolo Arosio
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Porphyrin-fused graphene nanoribbons Nat. Chem. (IF 21.8) Pub Date : 2024-03-08 Qiang Chen, Alessandro Lodi, Heng Zhang, Alex Gee, Hai I. Wang, Fanmiao Kong, Michael Clarke, Matthew Edmondson, Jack Hart, James N. O’Shea, Wojciech Stawski, Jonathan Baugh, Akimitsu Narita, Alex Saywell, Mischa Bonn, Klaus Müllen, Lapo Bogani, Harry L. Anderson
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Reconfiguring hydrogel assemblies using a photocontrolled metallopolymer adhesive for multiple customized functions Nat. Chem. (IF 21.8) Pub Date : 2024-03-08 Jiahui Liu, Yun-Shuai Huang, Yazhi Liu, Dachuan Zhang, Kaloian Koynov, Hans-Jürgen Butt, Si Wu
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Exploring the frontiers of condensed-phase chemistry with a general reactive machine learning potential Nat. Chem. (IF 21.8) Pub Date : 2024-03-07 Shuhao Zhang, Małgorzata Z. Makoś, Ryan B. Jadrich, Elfi Kraka, Kipton Barros, Benjamin T. Nebgen, Sergei Tretiak, Olexandr Isayev, Nicholas Lubbers, Richard A. Messerly, Justin S. Smith
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The importance of community as a pre-tenure faculty member Nat. Chem. (IF 21.8) Pub Date : 2024-03-06 Shira Joudan
Becoming an assistant professor brings with it several challenges, one of which is developing new relationships that can be professionally and personally beneficial. Shira Joudan reflects on getting to know people at a new institution, having different types of relationships, and how they help with happiness and success.
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A blueprint for catalysis Nat. Chem. (IF 21.8) Pub Date : 2024-03-06 Ciro Romano, Jack I. Mansell, David J. Procter
Ciro Romano, Jack I. Mansell, and David J. Procter have explored the versatility and selectivity of samarium diiodide, and its use as a radical relay catalyst.
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The anti-aromatic dianion and aromatic tetraanion of [18]annulene Nat. Chem. (IF 21.8) Pub Date : 2024-03-06 Wojciech Stawski, Yikun Zhu, Igor Rončević, Zheng Wei, Marina A. Petrukhina, Harry L. Anderson
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Nanopore DNA sequencing technologies and their applications towards single-molecule proteomics Nat. Chem. (IF 21.8) Pub Date : 2024-03-06 Adam Dorey, Stefan Howorka
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Tunable molecular editing of indoles with fluoroalkyl carbenes Nat. Chem. (IF 21.8) Pub Date : 2024-03-05 Shaopeng Liu, Yong Yang, Qingmin Song, Zhaohong Liu, Ying Lu, Zhanjing Wang, Paramasivam Sivaguru, Xihe Bi
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ATP hydrolysis captured in atomic detail Nat. Chem. (IF 21.8) Pub Date : 2024-03-01 Nadia Elghobashi-Meinhardt
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Visualization of CO2 electrolysis using optical coherence tomography Nat. Chem. (IF 21.8) Pub Date : 2024-03-01 Xin Lu, Chris Zhou, Roxanna S. Delima, Eric W. Lees, Abhishek Soni, David J. Dvorak, Shaoxuan Ren, Tengxiao Ji, Addie Bahi, Frank Ko, Curtis P. Berlinguette
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The impact of UV light on synthetic photochemistry and photocatalysis Nat. Chem. (IF 21.8) Pub Date : 2024-03-01 Giulio Goti, Kavyasree Manal, Jayaraman Sivaguru, Luca Dell’Amico
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Molecularly defined electrodes host a concert of protons and electrons Nat. Chem. (IF 21.8) Pub Date : 2024-02-29 Siyuan L. Xie, Eva M. Nichols
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Genetically encoded bioorthogonal tryptophan decaging in living cells Nat. Chem. (IF 21.8) Pub Date : 2024-02-28 Yuchao Zhu, Wenlong Ding, Yulin Chen, Ye Shan, Chao Liu, Xinyuan Fan, Shixian Lin, Peng R. Chen
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Photoinduced dual bond rotation of a nitrogen-containing system realized by chalcogen substitution Nat. Chem. (IF 21.8) Pub Date : 2024-02-28 Shotaro Nagami, Rintaro Kaguchi, Taichi Akahane, Yu Harabuchi, Tohru Taniguchi, Kenji Monde, Satoshi Maeda, Satoshi Ichikawa, Akira Katsuyama
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Tandem catalysis enables chlorine-containing waste as chlorination reagents Nat. Chem. (IF 21.8) Pub Date : 2024-02-23 Mingyang Liu, Xinbang Wu, Paul J. Dyson
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Asymmetric oligomerization state and sequence patterning can tune multiphase condensate miscibility Nat. Chem. (IF 21.8) Pub Date : 2024-02-21 Ushnish Rana, Ke Xu, Amal Narayanan, Mackenzie T. Walls, Athanassios Z. Panagiotopoulos, José L. Avalos, Clifford P. Brangwynne
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Carbon isotope exchange for pharmaceutical radiolabelling through metal-catalysed functional group metathesis Nat. Chem. (IF 21.8) Pub Date : 2024-02-20
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Thorium(iv)–antimony complexes exhibiting single, double, and triple polar covalent metal–metal bonds Nat. Chem. (IF 21.8) Pub Date : 2024-02-20 Jingzhen Du, Kevin Dollberg, John A. Seed, Ashley J. Wooles, Carsten von Hänisch, Stephen T. Liddle
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Highly entangled polyradical nanographene with coexisting strong correlation and topological frustration Nat. Chem. (IF 21.8) Pub Date : 2024-02-19 Shaotang Song, Andrés Pinar Solé, Adam Matěj, Guangwu Li, Oleksandr Stetsovych, Diego Soler, Huimin Yang, Mykola Telychko, Jing Li, Manish Kumar, Qifan Chen, Shayan Edalatmanesh, Jiri Brabec, Libor Veis, Jishan Wu, Pavel Jelinek, Jiong Lu
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A metal-catalysed functional group metathesis approach to the carbon isotope labelling of carboxylic acids Nat. Chem. (IF 21.8) Pub Date : 2024-02-19 R. Garrison Kinney, José Zgheib, Pierre-Louis Lagueux-Tremblay, Cuihan Zhou, Haifeng Yang, Jingwei Li, Donald R. Gauthier, Bruce A. Arndtsen
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A catalytic process enables efficient and programmable access to precisely altered indole alkaloid scaffolds Nat. Chem. (IF 21.8) Pub Date : 2024-02-19 Youming Huang, Xinghan Li, Binh Khanh Mai, Emily J. Tonogai, Amanda J. Smith, Paul J. Hergenrother, Peng Liu, Amir H. Hoveyda
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Tunable valence tautomerism in lanthanide–organic alloys Nat. Chem. (IF 21.8) Pub Date : 2024-02-19 Maja A. Dunstan, Anna S. Manvell, Nathan J. Yutronkie, Frédéric Aribot, Jesper Bendix, Andrei Rogalev, Kasper S. Pedersen
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Clever cryptand cage coordinates contaminants Nat. Chem. (IF 21.8) Pub Date : 2024-02-16 Rosemary J. Goodwin, Nicholas G. White
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Asymmetric construction of sulfur(VI)–fluorine cores Nat. Chem. (IF 21.8) Pub Date : 2024-02-14 Patrick R. Melvin
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Diazobutanone-assisted isobaric labelling of phospholipids and sulfated glycolipids enables multiplexed quantitative lipidomics using tandem mass spectrometry Nat. Chem. (IF 21.8) Pub Date : 2024-02-16 Ting-Jia Gu, Peng-Kai Liu, Yen-Wen Wang, Matthew T. Flowers, Shuling Xu, Yuan Liu, Dawn B. Davis, Lingjun Li
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A divergent intermediate strategy yields biologically diverse pseudo-natural products Nat. Chem. (IF 21.8) Pub Date : 2024-02-16 Sukdev Bag, Jie Liu, Sohan Patil, Jana Bonowski, Sandra Koska, Beate Schölermann, Ruirui Zhang, Lin Wang, Axel Pahl, Sonja Sievers, Lukas Brieger, Carsten Strohmann, Slava Ziegler, Michael Grigalunas, Herbert Waldmann
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Enantioselective sulfur(VI) fluoride exchange reaction of iminosulfur oxydifluorides Nat. Chem. (IF 21.8) Pub Date : 2024-02-14 Zhiyuan Peng, Shoujun Sun, Meng-Meng Zheng, Yangyang Li, Xixi Li, Suhua Li, Xiao-Song Xue, Jiajia Dong, Bing Gao
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Biocatalytic strategy for the construction of sp3-rich polycyclic compounds from directed evolution and computational modelling Nat. Chem. (IF 21.8) Pub Date : 2024-02-13 David A. Vargas, Xinkun Ren, Arkajyoti Sengupta, Ledong Zhu, Satyajit Roy, Marc Garcia-Borràs, K. N. Houk, Rudi Fasan
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Site-selective episulfonium formation on protein surfaces Nat. Chem. (IF 21.8) Pub Date : 2024-02-14
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Operando film-electrochemical EPR spectroscopy tracks radical intermediates in surface-immobilized catalysts Nat. Chem. (IF 21.8) Pub Date : 2024-02-14 Maryam Seif-Eddine, Samuel J. Cobb, Yunfei Dang, Kaltum Abdiaziz, Mark A. Bajada, Erwin Reisner, Maxie M. Roessler
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Mapping the mechanisms of oxidative addition in cross-coupling reactions catalysed by phosphine-ligated Ni(0) Nat. Chem. (IF 21.8) Pub Date : 2024-02-14 Christina N. Pierson, John F. Hartwig
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A charge-neutral organic cage selectively binds strongly hydrated sulfate anions in water Nat. Chem. (IF 21.8) Pub Date : 2024-02-13 Liuyang Jing, Evelyne Deplazes, Jack K. Clegg, Xin Wu
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Protein-templated ligand discovery via the selection of DNA-encoded dynamic libraries Nat. Chem. (IF 21.8) Pub Date : 2024-02-07 Yu Zhou, Wenyin Shen, Ying Gao, Jianzhao Peng, Qingrong Li, Xueying Wei, Shihao Liu, Fong Sang Lam, Joan Mayol-Llinàs, Guixian Zhao, Gang Li, Yizhou Li, Hongzhe Sun, Yan Cao, Xiaoyu Li
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Oxidative two-state photoreactivity of a manganese(IV) complex using near-infrared light Nat. Chem. (IF 21.8) Pub Date : 2024-02-08 Nathan R. East, Robert Naumann, Christoph Förster, Charusheela Ramanan, Gregor Diezemann, Katja Heinze
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Characterizing ATP processing by the AAA+ protein p97 at the atomic level Nat. Chem. (IF 21.8) Pub Date : 2024-02-07 Mikhail Shein, Manuel Hitzenberger, Tat Cheung Cheng, Smruti R. Rout, Kira D. Leitl, Yusuke Sato, Martin Zacharias, Eri Sakata, Anne K. Schütz
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A protein-templated selection approach for the identification of full ligands from DNA-encoded libraries Nat. Chem. (IF 21.8) Pub Date : 2024-02-08
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Chelation enables selectivity control in enantioconvergent Suzuki–Miyaura cross-couplings on acyclic allylic systems Nat. Chem. (IF 21.8) Pub Date : 2024-02-08 Violeta Stojalnikova, Stephen J. Webster, Ke Liu, Stephen P. Fletcher
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Bistability between π-diradical open-shell and closed-shell states in indeno[1,2-a]fluorene Nat. Chem. (IF 21.8) Pub Date : 2024-02-08 Shantanu Mishra, Manuel Vilas-Varela, Leonard-Alexander Lieske, Ricardo Ortiz, Shadi Fatayer, Igor Rončević, Florian Albrecht, Thomas Frederiksen, Diego Peña, Leo Gross
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Small-pore hydridic frameworks store densely packed hydrogen Nat. Chem. (IF 21.8) Pub Date : 2024-02-06 Hyunchul Oh, Nikolay Tumanov, Voraksmy Ban, Xiao Li, Bo Richter, Matthew R. Hudson, Craig M. Brown, Gail N. Iles, Dirk Wallacher, Scott W. Jorgensen, Luke Daemen, Rafael Balderas-Xicohténcatl, Yongqiang Cheng, Anibal J. Ramirez-Cuesta, Michael Heere, Sergio Posada-Pérez, Geoffroy Hautier, Michael Hirscher, Torben R. Jensen, Yaroslav Filinchuk
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Redefining peptide therapeutics with semaglutide Nat. Chem. (IF 21.8) Pub Date : 2024-02-06 Thomas Kruse, Søren Østergaard
Thomas Kruse and Søren Østergaard reflect on the development of the GLP-1 analogue, semaglutide, which is reshaping peptide therapeutics in type 2 diabetes, weight management, and beyond.
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Near-atomic-resolution structure of J-aggregated helical light-harvesting nanotubes Nat. Chem. (IF 21.8) Pub Date : 2024-02-05 Arundhati P. Deshmukh, Weili Zheng, Chern Chuang, Austin D. Bailey, Jillian A. Williams, Ellen M. Sletten, Edward H. Egelman, Justin R. Caram
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Determinants that enable disordered protein assembly into discrete condensed phases Nat. Chem. (IF 21.8) Pub Date : 2024-02-05 Rachel M. Welles, Kandarp A. Sojitra, Mikael V. Garabedian, Boao Xia, Wentao Wang, Muyang Guan, Roshan M. Regy, Elizabeth R. Gallagher, Daniel A. Hammer, Jeetain Mittal, Matthew C. Good
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Ultrafast electronic relaxation pathways of the molecular photoswitch quadricyclane Nat. Chem. (IF 21.8) Pub Date : 2024-02-02 Kurtis D. Borne, Joseph C. Cooper, Michael N. R. Ashfold, Julien Bachmann, Surjendu Bhattacharyya, Rebecca Boll, Matteo Bonanomi, Michael Bosch, Carlo Callegari, Martin Centurion, Marcello Coreno, Basile F. E. Curchod, Miltcho B. Danailov, Alexander Demidovich, Michele Di Fraia, Benjamin Erk, Davide Faccialà, Raimund Feifel, Ruaridh J. G. Forbes, Christopher S. Hansen, David M. P. Holland, Rebecca
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The synthesis and characterization of an iron(VII) nitrido complex Nat. Chem. (IF 21.8) Pub Date : 2024-01-30 Martin Keilwerth, Weiqing Mao, Moritz Malischewski, Sergio A. V. Jannuzzi, Kevin Breitwieser, Frank W. Heinemann, Andreas Scheurer, Serena DeBeer, Dominik Munz, Eckhard Bill, Karsten Meyer
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Ten-electron count rule for the binding of adsorbates on single-atom alloy catalysts Nat. Chem. (IF 21.8) Pub Date : 2024-01-23 Julia Schumann, Michail Stamatakis, Angelos Michaelides, Romain Réocreux
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Spilling the tea Nat. Chem. (IF 21.8) Pub Date : 2024-01-25 Matthew R. Hartings
Steeped: The Chemistry of Tea Michelle FranclRoyal Society of Chemistry: 2024. 240 pp. £20
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Synthesis of polysubstituted azepanes by dearomative ring expansion of nitroarenes Nat. Chem. (IF 21.8) Pub Date : 2024-01-25 Rory Mykura, Raquel Sánchez-Bento, Esteban Matador, Vincent K. Duong, Ana Varela, Lucrezia Angelini, Rodrigo J. Carbajo, Josep Llaveria, Alessandro Ruffoni, Daniele Leonori