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N-Heterocyclic nitrenium-catalyzed photoreductive radical-polar crossover for alkene dicarbofunctionalization Green Synth. Catal. Pub Date : 2024-03-18 Youfeng Han, Beibei Zhang, Zhixiang Wang, Xiangyu Chen
The photoredox radical-polar crossover paradigm is a valuable tool for 1,2-difunctionalization of alkenes. However, the use of unactivated alkyl halides as radical precursors remains far less developed. Here, we report a photoreductive -heterocyclic nitrenium-catalyzed radical-polar crossover for the 1,2-dicarbofunctionalization of alkenes by using unactivated alkyl and aryl iodides. These reactions
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Transaminase catalyzed asymmetric synthesis of active pharmaceutical ingredients Green Synth. Catal. Pub Date : 2024-03-16 Yiman Cui, Yadong Gao, Licheng Yang
Chiral amine molecules constitute vital components of pharmaceutical ingredients. Recent years have witnessed a growing focus on the efficient synthesis of chiral amines. Transaminases, as catalysts, have emerged as green, efficient, and highly selective solutions for substrates containing ketones or aldehydes, demonstrating exceptional performance in the synthesis of active drug molecules and natural
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Unraveling chemical glycosylation: DFT insights into factors imparting stereoselectivity Green Synth. Catal. Pub Date : 2024-03-15 Aoxin Guo, Yuan Xu, Zhenhua Jia, Teck-Peng Loh, Xue-Wei Liu
Stereoselective chemical glycosylation reactions are pivotal for preparing manifold biologically and medically important compounds, while mechanisms of chemical glycosylation reactions remain obscure and largely speculative. Herein, we performed DFT calculations to delve into the multifaceted mechanistic details of glycosylation reactions, including the equilibria among reactive glycosyl triflate intermediates
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Photo- and electro-induced perfluoroalkylation/cyclization of o-hydroxyaryl enaminones: Synthesis of perfluoroalkyl chromones Green Synth. Catal. Pub Date : 2024-03-13 Shengjie Song, Wenjian Wang, Jun Sun, Can Luo, Chunlei Wu, Jianjun Li
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Enantioselective synthesis of planar chiral ferrocenes via gold(I)-catalyzed hydroarylation of N-ferrocenyl propiolamides Green Synth. Catal. Pub Date : 2024-03-08 Qian Zhou, Lulin Qiao, An-An Zhang, Lu Li, Tuan-Jie Meng, Baomin Fan, Yuan-Yuan Gao, Lantao Liu
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Mild and green thioacylation with dithiocarboxylates via photoredox catalysis Green Synth. Catal. Pub Date : 2024-03-07 Wen-Chao Gao, Wei Li, Juan Zhang, Hong-Hong Chang, Rong Zhou
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Thioamide construction via sulfur interrupted Brook rearrangement Green Synth. Catal. Pub Date : 2024-02-28 Shunmin Zhang, Yanyan Liao, Xuefeng Jiang
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Palladium-catalyzed halosulfonylation of alkynes with ionic liquid as the green solvent and halide sources Green Synth. Catal. Pub Date : 2024-02-26 Yin-Long Lai, Li-Yun Wu, Xun Xiong, Yi-Wei Lan, Yin-Yun Lin, Rui-Min Zhong, Huanfeng Jiang, Jianxiao Li
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Rapid access to diverse indoles by addition/SNAr with Grignard reagents and 2-fluorophenyl acetonitriles Green Synth. Catal. Pub Date : 2024-02-24 Yuanyun Gu, Yaxin Feng, Baotong Huang, Yan-En Wang, Yaqi Yuan, Dan Xiong, Yonghong Hu, Xiufang Xu, Patrick J. Walsh, Jianyou Mao
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1,5-Pentanediol production from 3,4-dihydro-2H-pyran and acetic acid via successive reactions of esterification and hydrogenation Green Synth. Catal. Pub Date : 2024-02-24 Siyuan Zhao, Hong Du, Qi Fang, Yuying Li, Lei Wu, Xiumei Liu, Feng Wang
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Synthesis of bridged bicyclic thiazine-2-thione and thiazole-2-thiones through DBU-promoted regioselective annulation of quinone monoacetals under mild conditions Green Synth. Catal. Pub Date : 2024-02-23 Hong Qin, Man Yang, Yuguang Li, Xiaobing Yang, Yujing Hu, Chengkou Liu, Wei He, Zheng Fang, Kai Guo
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Chemo- and site-selective aerobic oxidation of methylbenzenes to aromatic aldehydes enabled by an Fe(III) photocatalyst Green Synth. Catal. Pub Date : 2024-02-13 Rui-Hong Li, Li-Tian Zhang, Kai-Cheng Yu, Shuai Liu, Xiang-Guo Hu, Mu-Hua Huang
We have developed a chemo- and site-selective aerobic oxidation of methylbenzenes to aromatic aldehydes. It offers several advantages, including the use of an environmentally friendly catalyst (5 mol% of inexpensive ferric chloride hexahydrate), the utilization of air as a green oxidant, mild conditions, scalability (up to 5 g scale), and operational simplicity. Furthermore, the reaction demonstrates
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Metal-free and visible-light-mediated method enables the synthesis of olefins from ketones Green Synth. Catal. Pub Date : 2024-02-10 Yu Zhang, Xinyu Han, Rongkai Wu, Jinxin Wang, Qiannan Li, Jingchuan Lin, Dingding Xia, Xin Hong, Shoubhik Das, Wei-Dong Zhang
Direct synthesis of olefins continues to attract stellar attention due to the high importance of olefins. In this context, due to the wide availability of ketones, the synthesis of olefins directly from ketones provides a straightforward route. Considering this, olefins synthesis from ketones the formation of donor/donor type carbenes has been developed which leads to the efficient synthesis of versatile
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1,7-Hydride transfer-involved dearomatization of quinolines to access C3-spiro hydroquinolines Green Synth. Catal. Pub Date : 2024-02-06 Da-Ying Shao, Bin Qiu, Zi-Kang Wang, Zhen-Yuan Liu, Jian Xiao, Xiao-De An
1,7-Hydride transfer-involved dearomatization of quinolines toward C3-spiro hydroquinoline derivatives has been developed. This method offers a protocol to achieve the dearomatization of electron-deficient arenes via the redox-neutral hydride transfer process. A series of C3-spiro hydroquinolines can be provided in moderate to excellent yields (up to 98%) with good diastereoselectivities. Significant
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Efficient toluene degradation using Bacillus subtilis biofilm-supported Mn–Ce/zeolite catalysts Green Synth. Catal. Pub Date : 2024-02-05 Muhammad Zubair Mohsin, Ali Mohsin, Waqas Qamar Zaman, Xiaojuan Zhu, Xihua Zhao, Zain Abbas, Muhammad Hammad Hussain, Ali Shan, Muhammad Asif Nawaz, Rabia Omer, Yingping Zhuang, Meijin Guo, Jiaofang Huang
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A water-soluble supermolecular cage for artificial light-harvesting nanoreactors Green Synth. Catal. Pub Date : 2024-02-01 Xin Han, Luyao Ding, Xin-Qi Hao, Yujing Guo, Linlin Shi
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Photoinduced radical cascade brominative addition/spirocyclization of N-arylpropiolamides and CBr4 with O2 as oxidant Green Synth. Catal. Pub Date : 2024-01-15 Zheng-Wei Wu, Han-Han Kong, Yong Wei, Wen-Chao Zhou, Long Wang, Liang-Qiu Lu, Qing-Qing Yang
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Electrochemical N-olefination for the regio- and stereo-selective synthesis of vinyl azoles Green Synth. Catal. Pub Date : 2024-01-12 Kejun Lin, Jianyong Lan, Lin Hao, Tingshun Zhu
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Directed evolution of stereoselective enzymes meets click reactions: asymmetric synthesis of chiral triazoles using a Cu(I)-compatible halohydrin dehalogenase Green Synth. Catal. Pub Date : 2024-01-12 Shaixiao Tian, Xinying Ge, Qipeng Yan, Min Li, Qun Huang, Xinhua Zhang, Ming Ma, Bo Chen, Jian-bo Wang
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Controlled generation of ortho-quinone methides and (4+3) cyclization with 2-indolylalcohols by dual photoredox/Brønsted acid relay catalysis Green Synth. Catal. Pub Date : 2024-01-09 Dong Liang, Panpan Gao, Zhihan Zhang, Wenjing Xiao, Jiarong Chen
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Visible-light-induced reusable decatungstate-photocatalyzed radical cascade alkylation/cyclization of isocyanides with simple alkanes, ethers and ketones Green Synth. Catal. Pub Date : 2024-01-06 Ke-Li Wang, Hong-Tao Ji, Qiong-Hui Peng, Jun Jiang, Li-Juan Ou, Wei-Min He
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Water-controlled skeletal editing or peripheral modification of ortho-chalcone-substituted organophosphines Green Synth. Catal. Pub Date : 2024-01-05 Xin-Yue Niu, Chao-Yang Li, Cong-Cong Zhang, Zhan-Wei Bu, Yan Xie, Wen-Jing Zhang, Qi-Lin Wang
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Facile synthesis of asymmetric tetrablock copolymer by dual thermal and photochemical initiator Green Synth. Catal. Pub Date : 2023-12-18 Chenhuai Deng, Yuanhao Lin, Yunye Huang, Linxi Hou, Longqiang Xiao
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Brønsted acid promoted synthesis of polysubstituted pyrroles from enamines/imines and diazopyruvates: a metal-free cascade approach Green Synth. Catal. Pub Date : 2023-12-13 Farrukh Sajjad, Ming-Hua Xu
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Synthesis of dydrogesterone by aromatization-dearomatization strategy Green Synth. Catal. Pub Date : 2023-12-15 Heng Bai, Wei Gu, Di Zhao, Guangqing Xu, Wenjun Tang
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Recent Advances in (4 + 3) Cycloaddition of Allenes Green Synth. Catal. Pub Date : 2023-12-02 Yanyan Que, Wenli Lei, Yin Fang, Shuzhong He, Yang Chen
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Palladium-catalyzed intramolecular C-H arylation of ferrocenyl-sulfides, sulfoxide and its application in metal ion recognition Green Synth. Catal. Pub Date : 2023-12-01 Feifei Cao, Congyu Gao, Jingxin Zi, Jianfeng Hu, Yong Yang, Wen-Xiong Zhang, Hao Zhang
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Ferric nitrate-catalyzed aerobic oxidative ring-opening of substituted furans for the stereoselective synthesis of (Z)-1,4-enediones Green Synth. Catal. Pub Date : 2023-11-30 Tao Ye, Na Lin, Jia-Huan Shen, Lichun Kong, Yang-Zi Liu, Quannan Wang, Wei-Ping Deng
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A H2O2 generation-detection-regulation integrated platform for boosting the efficiency of peroxygenase-catalysed C–H oxidative hydroxylation Green Synth. Catal. Pub Date : 2023-11-30 Xiaowang Zhang, Zhuotao Tan, Mengjiao Xu, Wei Zhuang, Hanjie Ying, Zhenyu Chu, Chenjie Zhu
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Electrochemical enabled desaturated β-C(sp3)-H sulfonylation and phosphonylation of cyclic amines Green Synth. Catal. Pub Date : 2023-11-28 Tao Liu, Jie Lin, Fangjun Xia, Zhenhui Xu, Xuying Xia, Wei Qian, Weihui Zhong, Dingguo Song, Fei Ling
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Photo-Mediated para-Selective C(sp2)−H Difluoroalkylations Green Synth. Catal. Pub Date : 2023-11-17 Yi Luo, Lin Dong
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Asymmetric synthesis of chiral heterobenzylic amines via visible-light-induced enantioselective C(sp3)-H alkylation Green Synth. Catal. Pub Date : 2023-11-17 Yumei Huo, Beibei Chen, Xiaoyu Ren, Chao Wang, Rupeng Qi, Zhaoqing Xu
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Solvent-controlled stereodivergent synthesis of E- and Z-enamines via metal-free formal C(sp2)-H amination of α-substituted styrenes Green Synth. Catal. Pub Date : 2023-11-14 Dangui Wang, Jinbei Yao, Wentao Zhang, Shuyue Zhang, Huaibin Yu, Laihu Peng, Weijun Yao, Zhifeng Dai, Guojiao Wu, Fangrui Zhong
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Development of a more efficient catalyst for the redox-neutral organocatalytic mitsunobu reaction by DFT-guided catalyst design Green Synth. Catal. Pub Date : 2023-11-13 Dingguo Song, Changjun Zhang, Yuqi Cheng, Linlin Chen, Jie Lin, Changdi Zheng, Ting Liu, Yuxin Ding, Fei Ling, Weihui Zhong
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Divergent synthesis of new naphtho-fused 2-aminoindolines and naphthoxindoles based on straightforward construction of phenanthrene Green Synth. Catal. Pub Date : 2023-11-10 Bin Qiu, Ya-Fei Shi, Xiao-De An, Shu-Kui Guo, Yao-Bin Shen, Jian Xiao
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Electrochemical cascade pyrazole annulation and C-H halogenation for the synthesis of 4-halopyrazoles Green Synth. Catal. Pub Date : 2023-10-24 Haijin Guo, Yunyun Liu, Jie-Ping Wan
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Transition-metal and base-free ether synthesis via alcohol-participated yne-allylic substitution Green Synth. Catal. Pub Date : 2023-10-21 Chao Xu, Yingkun Luo, Shengtong Niu, Fan Gong, Shouang Lan, Benlong Luo, Jinggong Liu, Shuang Yang, Xinqiang Fang
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Visible-light-induced radical-cascade alkylation/cyclization of N-methacryloyl-2-phenylbenzimidazole: Access to benzoimidazo[2,1-a]isoquinolin-6(5H)-ones Green Synth. Catal. Pub Date : 2023-10-18 Yanhong Wang, Xinlei Zhou, Tao Zhang, Xinxin Ren, Wei Xu, Bin Wang, Weiwei Jin, Yu Xia, Chenjiang Liu, Yonghong Zhang
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Photoinduced decatungstate-catalyzed direct coupling of cycloalkanes and cyclic aldimines Green Synth. Catal. Pub Date : 2023-10-18 Jingjing Wang, Feng Li, Kai Liu, Chong Li, Sheng Cao, Yuxiang Wu, Yongjun Yuan, Fei Teng, Teng Wang, Yao Zhou
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One-pot access to indazole fused-phenanthridinones via Rh(III)-catalyzed [4+2] annulation Green Synth. Catal. Pub Date : 2023-09-29 Shumin Li, Jinke Chang, Jian Shen, Xiuling Cui
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Pictet-spengler/transamination cascade reaction of indoles for modular synthesis of marinoquinoline analogues Green Synth. Catal. Pub Date : 2023-09-20 Jinjin Chen, Pingyu Jiang, Xinping Liu, Huawen Huang, Guojiang Mao, Guo-Jun Deng
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N-doped graphene fiber anchored Pd nanoparticles as a fixed-bed catalyst for continuous-flow reduction of N-containing unsaturated compounds Green Synth. Catal. Pub Date : 2023-09-09 Shuaihu Du, Zhuoyuan Bi, Jiangbo Xi
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Rhodium/Ming-Phos-catalyzed asymmetric annulation reaction of silacyclobutanes with terminal alkynes Green Synth. Catal. Pub Date : 2023-09-07 Yue Sun, Kaida Zhou, Chun Ma, Zhiming Li, Junliang Zhang
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Highly enantio-stereoselective Ni-catalyzed reductive cyclization to cyclopentanes with chiral quaternary centres of trisubstituted allylic siloxanes Green Synth. Catal. Pub Date : 2023-09-01 Wanjun Chen, Xinlong Yan, Lin Fan, Xu Guo, Jian Yang, Yiming Chen, Shaofang Zhou, Guodu Liu
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Visible-light induced photocatalyst-free difluoromethylation of quinoxalinones with difluorosulfones Green Synth. Catal. Pub Date : 2023-08-30 Linlin Shi, Tiantian Li, Wenjing Zhang, Weinan Hu, Xinju Zhu, Yixin Lu, Guang-Jian Mei
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Spirooxindoles: Recent report of green synthesis approach Green Synth. Catal. Pub Date : 2023-08-15 Agus Rimus Liandi, Antonius Herry Cahyana, Diva Naufal Alfariza, Rahma Nuraini, Renita Wulan Sari, Tio Putra Wendari
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Synthesis of tetraarylmethanes: 1897–2022 Green Synth. Catal. Pub Date : 2023-08-04 Lai Chen, Jingqian Huo, Jinlin Zhang, Judith N. Currano, Haixing Guan, Patrick J. Walsh, Jianyou Mao
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Transition metal-free Csp3-Csp3 bond-forming reactions of N-tosylaziridines and gem-diborylalkanes Green Synth. Catal. Pub Date : 2023-07-26 Pu-Zhang Zi, Quan-Hong Zhao, Zhan-Cai Ma, Xiao-Lin Ren, Xing-Bang Liu, Yi-Wei Qiao, Lin-Wen Wei, Song Liu, Yuan Huang
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Erratum regarding previously published articles Green Synth. Catal. Pub Date : 2023-07-24
Abstract not available
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Synthesis of highly functional quinazolins via metal-free, visible-light-enabled radical cascade arylation/cyclization of fluorinated imidoyl isothiocyanates Green Synth. Catal. Pub Date : 2023-07-23 Yan Liang, Weigen Du, Xiaoqiong Zeng, Tiebo Xiao, Yubo Jiang
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Iridium-Catalyzed asymmetric reduction of α,β-Unsaturated nitriles with water Green Synth. Catal. Pub Date : 2023-07-22 Qinli Lu, Xianming Wang, Wanliu Wen, Ruifeng Fan, Binfeng Zhu, Bingjie Zhou, Jingchao Chen, Baomin Fan
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Synthesis of phenyliodine(III) bis(3-bromopropionate) for an organocatalyzed Markovnikov-type bromo-aminoxidation of vinylarenes Green Synth. Catal. Pub Date : 2023-06-08 Nagaraju Sakkani, Dhiraj K. Jha, Nouraan Sadiq, Parisa Sharif, John C.G. Zhao
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Photocatalytic generation of 1,4-disubstituted 1,2,3-triazoles under metal, oxidant and azide-free conditions Green Synth. Catal. Pub Date : 2023-05-24 Changhong Liu, Dilshat Abdukerem, Wenli Zhu, Kun Xia, Zechuan Mao, Ablimit Abdukader
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Photoredox/Ti dual-catalyzed dehydroxylative ring-opening Giese reaction of cyclobutanone oximes Green Synth. Catal. Pub Date : 2023-05-12 Huaigui Li, Yan Li, Weidong Yuan, Anling Qu, Kang Chen, Yingguang Zhu
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A sustainable synthesis of 3,3-disubstituted oxindoles via CuBr-catalysed capture of carboxylic oxonium ylides with isatylidene malononitrile Green Synth. Catal. Pub Date : 2023-05-07 Mengchu Zhang, Yukai Li, Yuwei Wang, Jirong Shu, Tianyuan Zhang, Dan Zhang, Song Cai, Taoda Shi, Wenhao Hu
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Corrigendum to “Palladium-catalyzed sulfonylative coupling of benzyl(allyl) carbonates with arylsulfonyl hydrazides” [Green Synth. Catal. 3 (2022) 110–115] Green Synth. Catal. Pub Date : 2023-04-26 Bozhen Gong, Haibo Zhu, Yishuai Liu, Qian Li, Liu Yang, Guorong Wu, Qiangwen Fan, Zongbo Xie, Zhanggao Le
Abstract not available
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Rh(II) catalyzed efficient sigmatropic rearrangement reaction of pyridotriazoles and sulfides Green Synth. Catal. Pub Date : 2023-04-23 Yuting Chen, Guanghui Lv, Zhiyang Li, Meiling Ye, Tianle Huang, Li Hai, Yong Wu
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Polymer-supported chiral palladium-based complexes as efficient heterogeneous catalysts for asymmetric reductive Heck reaction Green Synth. Catal. Pub Date : 2023-04-11 Hui Zhang, Bing Xu, Liejin Zhou, Zhan-Ming Zhang, Junliang Zhang
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Metal- and light-free approach to polyheterocycles via a quinone-Cs2CO3 couple promoted regioselective cascade radical cyclization Green Synth. Catal. Pub Date : 2023-04-03 Qijing Zhang, Pan Yue, Hao Lei, Cong-Ying Zhou, Chengming Wang