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Depth profile analysis and high-resolution surface mapping of lithium isotopes in solids using laser-induced breakdown spectroscopy (LIBS) Spectrochim. Acta B. At. Spectrosc. (IF 3.3) Pub Date : 2024-04-10 Doriane Gallot-Duval, Céline Quéré, Eric De Vito, Jean-Baptiste Sirven
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A strategy to reduce spectral intensity uncertainty and predicted content uncertainty of low and medium alloy steel elements Spectrochim. Acta B. At. Spectrosc. (IF 3.3) Pub Date : 2024-04-04 Shilei Xiong, Tianlang Liao, Yada Chi, Ming Luo, Changfeng Yao, Zhenzhen Wang, Yoshihiro Deguchi, Minchao Cui
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A wide-band, high-resolution semi-von Hamos spectrometer for K-shell multi-ionization atoms X-ray measurements Spectrochim. Acta B. At. Spectrosc. (IF 3.3) Pub Date : 2024-04-03 W. Wang, C.J. Shao, D.Y. Yu, X.H. Cai
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Detection and diagnosis of bacterial pathogens in blood using laser-induced breakdown spectroscopy Spectrochim. Acta B. At. Spectrosc. (IF 3.3) Pub Date : 2024-04-02 E.J. Blanchette, E.A. Tracey, A. Baughan, G.E. Johnson, H. Malik, C.N. Alionte, I.G. Arthur, M.E.S. Pontoni, S.J. Rehse
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Accelerated real-time plasma diagnostics: Integrating argon collisional-radiative model with machine learning methods Spectrochim. Acta B. At. Spectrosc. (IF 3.3) Pub Date : 2024-03-31 P.S.N.S.R. Srikar, Indhu Suresh, R.K. Gangwar
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A rapid in-situ hardness detection method for steel rails based on LIBS and machine learning Spectrochim. Acta B. At. Spectrosc. (IF 3.3) Pub Date : 2024-03-30 Langyu Xia, Zefeng Yang, Wenfu Wei, Guangning Wu
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The in-situ excitation on internal electrode of DBD-OES system for cadmium sensitive detection Spectrochim. Acta B. At. Spectrosc. (IF 3.3) Pub Date : 2024-03-26 Yi Cai, Wei Li, Cheng Yao, Yong Zhao
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Characterization of lithium phosphorus oxide thin film libraries by laser-induced breakdown spectroscopy imaging: A step towards high-throughput quantitative analyses Spectrochim. Acta B. At. Spectrosc. (IF 3.3) Pub Date : 2024-03-25 William Berthou, Maxime Legallais, Bruno Bousquet, Vincent Motto-Ros, Frédéric Le Cras
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Analytical performance characteristics of Micro-structured surfaces for laser-induced breakdown spectroscopic analysis of liquids Spectrochim. Acta B. At. Spectrosc. (IF 3.3) Pub Date : 2024-03-24 Dilara Kaplan, İlayda Yaman, Şerife Yalçın
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Reply to “Comment on Comparison of direct and indirect measures of transport efficiency in single particle inductively coupled plasma mass spectrometry” by H. Goenaga-Infante Spectrochim. Acta B. At. Spectrosc. (IF 3.3) Pub Date : 2024-03-23 Karen E. Murphy, Antonio R. Montoro Bustos, Lee L. Yu, Monique E. Johnson, Michael R. Winchester
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Controlling capillary flow by using laser-fabricated acrylic substrates with rectangular grooves for the improvement of repeatability of laser induced breakdown spectroscopy liquid analysis Spectrochim. Acta B. At. Spectrosc. (IF 3.3) Pub Date : 2024-03-21 Hongbao Wang, Honglian Li, Ziying Chen, Yingrui Song, Shijie Fu, Lide Fang
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In situ chemical analysis of duplex stainless steel weld by laser induced breakdown spectroscopy Spectrochim. Acta B. At. Spectrosc. (IF 3.3) Pub Date : 2024-03-21 Lukas Quackatz, Igor Gornushkin, Axel Griesche, Thomas Kannengiesser, Kai Treutler, Volker Wesling
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A new method for calibration-free analysis by Laser-Induced Breakdown Spectroscopy using a time-integrated spectrometer Spectrochim. Acta B. At. Spectrosc. (IF 3.3) Pub Date : 2024-03-19 Noura Lellouche, Bruno Cocciaro, Stefano Legnaioli, Giulia Lorenzetti, Vincenzo Palleschi, Francesco Poggialini, Simona Raneri, Sabrina Messaoud Aberkane
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A perturbed energy level of the holmium atom Spectrochim. Acta B. At. Spectrosc. (IF 3.3) Pub Date : 2024-03-19 L. Windholz, Gü. Başar, S. Kröger, Gö. Başar
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Microzone analysis of stalagmite chemical components in caves based on confocal controlled Raman and laser induced breakdown spectroscopy Spectrochim. Acta B. At. Spectrosc. (IF 3.3) Pub Date : 2024-03-18 Angze Li, Pingzhong Zhang, Chunjing He, Xiaojuan Chuai, Han Cui, Lirong Qiu, Weiqian Zhao
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Critical evaluation of energy dispersive X-ray fluorescence spectrometry for multielemental analysis of coffee samples: Sample preparation, quantification and chemometric approaches Spectrochim. Acta B. At. Spectrosc. (IF 3.3) Pub Date : 2024-03-15 M. Weinberger, I. Queralt, C. Streli, P. Wobrauschek, E. Besalú, J. Jablan, E. Marguí
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Benchmarking calculations of level energies, transition parameters and electron impact excitation cross sections of S-like Xe38+ Spectrochim. Acta B. At. Spectrosc. (IF 3.3) Pub Date : 2024-03-12 Shikha Rathi, Lalita Sharma
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The detection of elemental content changes in electrode coating using laser-induced breakdown spectroscopy Spectrochim. Acta B. At. Spectrosc. (IF 3.3) Pub Date : 2024-03-11 Lei Yang, Yinchuan Li, Congyuan Pan, Wenyi Bao, Lei Qin, Jingtao Dong, Mengjie Xu, Feng Ji, Yuzhong Zhang, Rongsheng Lu
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Evaporation-free tandem-column separation for Sr from geological samples with high Rb/Sr ratios Spectrochim. Acta B. At. Spectrosc. (IF 3.3) Pub Date : 2024-03-06 Deyi Peng, Xiuli Cai, Guoqing Li, Xinyi He, Ao Sun, Leran Wang, Di Yang, Tong Wang, Jinyong Xu
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Polarization-dependent optical Stark effect on Fraunhofer-type absorption in DP LIBS Spectrochim. Acta B. At. Spectrosc. (IF 3.3) Pub Date : 2024-02-27 L. Nagli, M. Gaft, Y. Raichlin
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Determination of inorganic and organic carbons in a Martian soil simulant under the Martian CO2 atmosphere using LIBS coupled with machine learning Spectrochim. Acta B. At. Spectrosc. (IF 3.3) Pub Date : 2024-02-27 Fengye Chen, Chen Sun, Shuaiyi Qu, Beiyi Zhang, Yunfei Rao, Tianyang Sun, Yu-Yan Sara Zhao, Jin Yu
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Compressed sensing for rapid tabletop X-ray absorption spectroscopy Spectrochim. Acta B. At. Spectrosc. (IF 3.3) Pub Date : 2024-02-24 Yousuf Hemani, Kilian Koch, Davide Bleiner
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Characterization of a co-planar dielectric barrier discharge design as a plasma source for trace element detection by atomic spectrometry Spectrochim. Acta B. At. Spectrosc. (IF 3.3) Pub Date : 2024-02-21 Sebastian Burhenn, Judith Golda, Jan Kratzer, Sebastian Brandt, Julian Held
Dielectric barrier discharges (DBD) are used in analytical chemistry for the dissociation of molecules, which can then be detected with methods like atomic absorption spectroscopy or emission spectroscopy. However, a drawback of this approach is that the analyte can be deposited on the reactor walls, lowering the density available for element detection. In this work, we propose a novel design of a
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Study of spectral lines behaviour with a double pulse 1064–1064 nm laser-induced breakdown spectroscopy system at the direct analysis of algae on the filter Spectrochim. Acta B. At. Spectrosc. (IF 3.3) Pub Date : 2024-02-18 Jana Horská, Aleš Hrdlička, Jitka Hegrová, Martina Bucková, David Prochazka, Pavel Pořízka, Viktor Kanický, Jozef Kaiser
The nickel and zinc contamination of algae on a cellulose filter was studied with double pulse 1064–1064 nm laser-induced breakdown spectroscopy (LIBS). Samples of the green alga were contaminated with zinc and nickel. The surface concentrations on the filter calculated from the reference Inductively Coupled Plasma Mass Spectrometry analysis were 25 and 64 ng cm for nickel and zinc respectively. The
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Precise chlorine determination in geological materials using LIBS coupled with stable learning for Mars explorations Spectrochim. Acta B. At. Spectrosc. (IF 3.3) Pub Date : 2024-02-17 Yunfei Rao, Chen Sun, Xiaowen Yu, Fengye Chen, Li Wang, Beiyi Zhang, Tianyang Sun, Cong Liu, Jinbo Qiu, Yu-Yan Sara Zhao, Jin Yu
Chlorine plays an important role in Mars explorations by offering insights into the planet's ancient geological processes, such as hydrothermal and volcanic activities. In-situ detections of chlorine on Mars have been reported by using various instruments onboard landers or rovers, and in particular laser-induced breakdown spectroscopy (LIBS). The detection with LIBS is limited by the faintness of
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Quantifying salivary iodine biomarker using total reflection X-ray fluorescence (TXRF): A method for assessing and monitoring iodine status simulated by Monte Carlo Spectrochim. Acta B. At. Spectrosc. (IF 3.3) Pub Date : 2024-02-17 P. Zambianchi, J.K. Zambianchi
Iodine stands as a vital trace element essential crucial for synthesizing thyroid hormones, which are essential for regulating metabolism and tissue growth. The “gold standard” for assessing iodine status in a population quantifies the iodine content in urine samples and is based on Inductively Coupled Plasma - Mass Spectrometry (ICP-MS). Such method, or methods involving the readings of the Sandell-Kolthoff
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Sub-ppb detection limit of Cr, Pb, and Cu in water by surface-enhanced LIBS with femtosecond laser Spectrochim. Acta B. At. Spectrosc. (IF 3.3) Pub Date : 2024-02-15 Yutong Chen, Jiarui Si, Xiangtong Wan, Ying Wang, Anmin Chen, Mingxing Jin
Water pollution caused by heavy metal contamination significantly threatens human health. Detecting trace levels of heavy metals in water is of utmost importance. Surface-enhanced laser-induced breakdown spectroscopy (SE-LIBS) has become a reliable detection method. In this study, we improved the analytical sensitivity of trace heavy metals in water by introducing femtosecond lasers into the SE-LIBS
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A novel atmospheric pressure glow discharge system for sensitive determination of As, Sb, and Se by optical emission spectrometry following their hydride generation Spectrochim. Acta B. At. Spectrosc. (IF 3.3) Pub Date : 2024-02-15 Krzysztof Gręda, Jan Kratzer, Nikol Vlčková, Paweł Pohl
Hydride generation (HG) was combined with an atmospheric pressure glow discharge (APGD), sustained in a completely novel system, to sensitively determine As, Sb, and Se by optical emission spectrometry (OES). The carrier gas with the analyte hydrides produced by chemical HG together with co-generated H was introduced into the APGD system, where atomization and excitation processes took place. It was
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When one equals two: Chemometrics turns Mössbauer spectrometer into X-ray fluorescence one Spectrochim. Acta B. At. Spectrosc. (IF 3.3) Pub Date : 2024-02-13 Valentin Semenov, Mikhail Grigoriev, Dmitry Kirsanov, Vitaly Panchuk
Here we explore the feasibility of using classical Mössbauer spectroscopy setup in scattering geometry to assess the elemental composition of samples using characteristic X-ray fluorescence. Even though, the scintillation detector of Mössbauer spectrometer yields rather low spectral resolution spectra, this can be effectively compensated using chemometric data processing. This hypothesis was first
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Double-pulse LIBS in water with up to 600 bar hydrostatic pressure and up to 150 mJ energy of each pulse Spectrochim. Acta B. At. Spectrosc. (IF 3.3) Pub Date : 2024-02-10 M. Henkel, M. Siemens, R. Methling, B. Emde, J. Hermsdorf, D. Gonzalez
Double-pulse LIBS is a promising technique for underwater material exploration. Since this has barely been investigated for deep-sea applications, measurements in pressured water with up to 600 bar were done, to show the usability. For this, a double-pulse system with up to 150 mJ each laser pulse was used to find a setup which allows to identify separated spectral line emission from plasma even at
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Comment on “Comparison of direct and indirect measures of transport efficiency in single particle inductively coupled plasma mass spectrometry” by K. E. Murphy, A. R. Montoro Bustos, L. L. Yu, M. E. Johnson, M. R. Winchester Spectrochim. Acta B. At. Spectrosc. (IF 3.3) Pub Date : 2024-02-07 Heidi Goenaga Infante
This paper provides critical and constructive comments on the paper “Comparison of direct and indirect measures of transport efficiency in single particle inductively coupled plasma mass spectrometry” by K. E. Murphy, A. R. Montoro Bustos, L. L. Yu, M. E. Johnson, M. R. Winchester, which has been recently published in Spectrochimica Acta Part B. It details the author's reservations about the discussions
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A micro-gas column assisted in situ laser-induced breakdown spectroscopy system: Development and field testing Spectrochim. Acta B. At. Spectrosc. (IF 3.3) Pub Date : 2024-02-07 Mingda Sui, Yuanyuan Xue, Zeying Zhang, Yunpeng Qin, Kezeng Pan, Yiping Wang, Shilei Zhong, Jinjia Guo
Laser-induced breakdown spectroscopy (LIBS) has attracted extensive attention as a new technique for in situ marine applications. In this paper, a high-sensitivity underwater micro-gas column assisted in situ LIBS system (MGC-LIBSea) was designed and implemented. The system creates a stable millimeter-scale gas column in water and a pulsed laser is focused on the gas–liquid interface of the micro-gas
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LIBS depth-profile analysis of W/Cu functionally graded material Spectrochim. Acta B. At. Spectrosc. (IF 3.3) Pub Date : 2024-02-01 M. Ivkovic, J. Savovic, B.D. Stankov, M. Kuzmanovic, I. Traparic
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Statistical analysis of analytical results near detection limits with illustrations using elemental determinations in medical and biological samples by total reflection X-ray fluorescence Spectrochim. Acta B. At. Spectrosc. (IF 3.3) Pub Date : 2024-01-28 Aldona Kubala-Kukuś, Dariusz Banaś, Marek Pajek, Janusz Braziewicz, Stanisław Góźdź, Joanna Chwiej, Stanisław Głuszek, Paweł Jagodziński, Eva Marguí, Monika Pierzak-Stępień, Agata Pniak, Zuzanna Setkowicz, Ilona Stabrawa, Regina Stachura, Karol Szary, Grzegorz Wesołowski, Anna Wojsa, Jolanta Wudarczyk-Moćko
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Signal distribution impact on limit of detection in laser-induced breakdown spectroscopy Spectrochim. Acta B. At. Spectrosc. (IF 3.3) Pub Date : 2024-01-28 V.N. Lednev, P.A. Sdvizhenskii, D.S. Liu, I.V. Gorudko, S.M. Pershin, A.F. Bunkin
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Ultratrace determination and speciation of hexavalent chromium by EDXRF and TXRF using dispersive micro-solid phase extraction and tetraethylenepentamine graphene oxide Spectrochim. Acta B. At. Spectrosc. (IF 3.3) Pub Date : 2024-01-26 Marcin Musielak, Maciej Serda, Anna Gagor, Ewa Talik, Rafal Sitko
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Detection of gold alloy elements by target-enhanced orthogonal triple-pulse laser-induced breakdown spectroscopy with improved sensitivity and minimal sample ablation Spectrochim. Acta B. At. Spectrosc. (IF 3.3) Pub Date : 2024-01-20 Yufeng Li, Yuqi Chen, Yinhua Jiang, Zenghui Wang, Xueqin Huang
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Fully relativistic distorted wave calculations of electron impact excitation of gallium atom: Cross sections relevant for plasma kinetic modeling Spectrochim. Acta B. At. Spectrosc. (IF 3.3) Pub Date : 2024-01-20 Indhu Suresh, Priti, R. Srivastava, R.K. Gangwar
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Detection of indigenous organic matter in rocks from the interpretation of carbon molecular forms in the laser-induced plasma Spectrochim. Acta B. At. Spectrosc. (IF 3.3) Pub Date : 2024-01-19 Laura García-Gómez, Tomás Delgado, Francisco J. Fortes, Luisa M. Cabalín, Javier Laserna
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Fast and simple method for simultaneous determination of palladium and rhodium in spent automotive catalysts by high-resolution continuum source electrothermal atomic absorption spectroscopy Spectrochim. Acta B. At. Spectrosc. (IF 3.3) Pub Date : 2024-01-13 Elżbieta Zambrzycka-Szelewa, Beata Godlewska-Żyłkiewicz
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Solution cathode glow discharge coupled to atmospheric pressure chemical ionization for elemental detection of S and P in organic compounds Spectrochim. Acta B. At. Spectrosc. (IF 3.3) Pub Date : 2024-01-09 Frenio A. Redeker, Kelsey O'Malley, William P. McMahon, Kaveh Jorabchi
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Effects of feature engineering on the robustness of laser-induced breakdown spectroscopy for industrial steel classification Spectrochim. Acta B. At. Spectrosc. (IF 3.3) Pub Date : 2024-01-08 Gookseon Jeon, Hohyun Keum, Hyunkeun Lee, Kyunghwan Oh, Janghee Choi
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Rapid authentication of geographical origins of Baishao (Radix Paeoniae Alba) slices with laser-induced breakdown spectroscopy based on conventional machine learning and deep learning Spectrochim. Acta B. At. Spectrosc. (IF 3.3) Pub Date : 2024-01-02 Fei Zhou, Weiyue Xie, Ming Lin, Longfei Ye, Chu Zhang, Zhangfeng Zhao, Fei Liu, Jiyu Peng, Wenwen Kong
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Optical emission spectroscopy of fiber laser sustained Xe plasma Spectrochim. Acta B. At. Spectrosc. (IF 3.3) Pub Date : 2023-12-28 Yanfei Hu, Xinbing Wang, Duluo Zuo
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Diffusion flame, heated quartz tube or dielectric barrier discharge? Comparing the resistance of hydride atomizers towards interferences with detection by atomic absorption spectrometry Spectrochim. Acta B. At. Spectrosc. (IF 3.3) Pub Date : 2024-01-02 Nikol Vlčková, Barbora Baranová, Milan Svoboda, Jan Kratzer
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Statistical scaling of elemental image by X-ray fluorescence spectrometry of magnesium alloy Spectrochim. Acta B. At. Spectrosc. (IF 3.3) Pub Date : 2023-12-31 Wataru Matsuda, Atsushi Morikawa, Atsushi Ohbuchi, Takao Moriyama, Toshihiro Nakamura
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In situ compositional analysis of ZnO films deposited using sputtering Spectrochim. Acta B. At. Spectrosc. (IF 3.3) Pub Date : 2023-12-22 Susumu Imashuku
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Investigation on plasma morphology fluctuation in laser-induced breakdown spectroscopy analysis of particle flow due to stochastic particle ablation Spectrochim. Acta B. At. Spectrosc. (IF 3.3) Pub Date : 2023-12-19 Ziyu Yu, Weizhe Ma, Weize Chen, Huaiqing Qin, Qingxiang Ma, Zhimin Lu, Shunchun Yao
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Comparison of direct and indirect measures of transport efficiency in single particle inductively coupled plasma mass spectrometry Spectrochim. Acta B. At. Spectrosc. (IF 3.3) Pub Date : 2023-12-16 Karen E. Murphy, Antonio R. Montoro Bustos, Lee L. Yu, Monique E. Johnson, Michael R. Winchester
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Sharing calibration information among laser-induced breakdown spectroscopy instruments using spectral line binning and calibration transfer Spectrochim. Acta B. At. Spectrosc. (IF 3.3) Pub Date : 2023-12-15 K.H. Lepore, M.D. Dyar, C.R. Ytsma
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Unveiling the temporal evolution of boron oxide exciplex species in laser-induced plasma: A detailed analysis of ro-vibrational spectra Spectrochim. Acta B. At. Spectrosc. (IF 3.3) Pub Date : 2023-12-07 Anandhu Mohan, Anannya Banerjee, Arnab Sarkar
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Optimization of pXRF instrumentation conditions and multivariate modeling in soil fertility attributes determination Spectrochim. Acta B. At. Spectrosc. (IF 3.3) Pub Date : 2023-11-28 José Vinícius Ribeiro, Felipe Rodrigues dos Santos, José Francirlei de Oliveira, Graziela M.C. Barbosa, Fábio Luiz Melquiades
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The spectroscopic investigation of broad C I and C II lines emitted from pulsed atmospheric pressure gas discharge source in argon and argon‑hydrogen mixture Spectrochim. Acta B. At. Spectrosc. (IF 3.3) Pub Date : 2023-11-26 J. Jovović, G.Lj. Majstorović
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Asymmetric profiles of Ca I lines belonging to the transitions n1F°3 → 31D2 observed in long laser spark Spectrochim. Acta B. At. Spectrosc. (IF 3.3) Pub Date : 2023-11-29 Andrey M. Popov, Ivan N. Krylov, Timur A. Labutin
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Highly efficient natural deep eutectic solvent-based liquid-liquid microextraction and inductively coupled plasma mass spectrometry for selective determination of inorganic selenium species in nut samples Spectrochim. Acta B. At. Spectrosc. (IF 3.3) Pub Date : 2023-11-23 María B. Botella, María N. Oviedo, Pablo Pacheco, Rodolfo G. Wuilloud
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Laser-induced breakdown spectroscopy of biological tissues: Plasma diagnostics and a comparison of quantification approaches Spectrochim. Acta B. At. Spectrosc. (IF 3.3) Pub Date : 2023-11-25 Nikolai I. Sushkov, Timur A. Labutin
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A simple and rapid copper-assisted microprecipitation method for the on-site separation of inorganic arsenic species in water samples followed by hydride generation atomic fluorescence spectrometry determination Spectrochim. Acta B. At. Spectrosc. (IF 3.3) Pub Date : 2023-11-23 Venkata Balarama Krishna Mullapudi
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Characterization of iron oxides: Valence states and naturally occurring polymorphs using chemical shift of X–ray FeLβ1 line by WD–XRF Spectrochim. Acta B. At. Spectrosc. (IF 3.3) Pub Date : 2023-11-10 Piyali Deb Barman, Ashok Kumar Maurya, Subhendu Ghosh, Ankit Roy, Mukul Madaan
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Dynamics of lithium plasma in laser-induced breakdown spectroscopy Spectrochim. Acta B. At. Spectrosc. (IF 3.3) Pub Date : 2023-11-04 E.D. Marenkov, I.P. Tsygvintsev, D.A. Kim, A.S. Grushin, N.E. Efimov, D.N. Sinelnikov, Yu.M. Gasparyan
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Laser–induced breakdown spectroscopy combined with surface coating to enhance emission line intensity of metallic elements in metal sheet Spectrochim. Acta B. At. Spectrosc. (IF 3.3) Pub Date : 2023-10-30 Zhichao Zhang, Wenbao Jia, Qing Shan, Jiandong Zhang, Daqian Hei, Aiyun Sun, Mingyu Liao, Yongsheng Ling