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Ultrafast Au(III)-Mediated Arylation of Cysteine J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-24 Evan A. Doud, James A. R. Tilden, Joseph W. Treacy, Elaine Y. Chao, Hayden R. Montgomery, Grace E. Kunkel, Eileen J. Olivares, Nima Adhami, Tyler A. Kerr, Yu Chen, Arnold L. Rheingold, Joseph A. Loo, Christopher G. Frost, K. N. Houk, Heather D. Maynard, Alexander M. Spokoyny
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Excited State Dynamics in Unidirectional Photochemical Molecular Motors J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-24 Palas Roy, Andy S. Sardjan, Wesley R. Browne, Ben L. Feringa, Stephen R. Meech
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Three-Dimensional Crystalline Organic Framework Stabilized by Molecular Mortise-and-Tenon Jointing J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-24 Xinru Sheng, Zeju Wang, Guan Sheng, Chongzhi Zhu, Ding Xiao, Tianyu Shan, Xuedong Xiao, Ming Liu, Guangfeng Li, Yihan Zhu, Jonathan L. Sessler, Feihe Huang
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Molecular Motors’ Magic Methyl and Its Pivotal Influence on Rotation J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-24 Yohan Gisbert, Maximilian Fellert, Charlotte N. Stindt, Alexander Gerstner, Ben L. Feringa
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Doubly Spiro-Conjugated Chiral Carbocycles Exhibiting SOMO–HOMO Inversion in Persistent Radical Cations J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-24 Takumi Sakamaki, Yan Zhang, Shota Fukuma, Carlos M. Cruz, Abel Cárdenas Valdivia, Araceli G. Campaña, Juan Casado, Rui Shang, Eiichi Nakamura
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An Atomic and Molecular Insight into How PFOA Reduces α-Helicity, Compromises Substrate Binding, and Creates Binding Pockets in a Model Globular Protein J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-24 Anju Yadav, Lela Vuković, Mahesh Narayan
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Degradable π-Conjugated Polymers J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-24 Azalea Uva, Sofia Michailovich, Nathan Sung Yuan Hsu, Helen Tran
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Spotlights on Recent JACS Publications, Volume 146, Issue 18 J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-24 ACS Contributing Correspondents
This article has not yet been cited by other publications.
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Probing Ion–Receptor Interactions in Halide Complexes of Octamethyl Calix[4]Pyrrole J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-23 Lane M. Terry, Madison M. Foreman, Anne P. Rasmussen, Anne B. McCoy, J. Mathias Weber
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Tuning Photoredox Catalysis of Ruthenium with Palladium: Synthesis of Heterobimetallic Ru–Pd Complexes That Enable Efficient Photochemical Reduction of CO2 J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-23 Siteng Yang, Yuto Morita, Yuta Nakamura, Nobuharu Iwasawa, Jun Takaya
New Ru–Pd heterobimetallic complexes were synthesized and structurally characterized utilizing 6,6″-bis(phosphino)-2,2′:6′,2″-terpyridine as a scaffold for the metal–metal bond. The dicationic Ru–Pd complex was found to exhibit high catalytic activity as a photocatalyst for photochemical reduction of CO2 to CO under visible light irradiation. This study established a new design of transition metal
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Machine Learning for Experimental Reactivity of a Set of Metal Clusters toward C–H Activation J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-23 Xi-Guan Zhao, Qi Yang, Ying Xu, Qing-Yu Liu, Zi-Yu Li, Xiao-Xiao Liu, Yan-Xia Zhao, Sheng-Gui He
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Water Hydrogen-Bond Mediated Layer by Layer Alignment of Lipid Rafts as a Precursor of Intermembrane Processes J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-23 Suho Lee, Ji Hyun Bak, Yuno Lee, Dae-Woong Jeong, Jaehee Lee, KeunMin Ken Lee, Hasaeam Cho, Hyun Hwi Lee, Changbong Hyeon, Myung Chul Choi
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Reconstructable Carbon Monolayer-MoS2 Intercalated Heterostructure Enabled by Atomic Layers-Confined Topotactic Transformation for Ultrafast Lithium Storage J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-23 Kexuan Liao, Lu Chen, Ruijin Meng, Yutong Feng, Shuo Meng, Hang Lu, Jie Ma, Chengxin Peng, Chi Zhang, Jinhu Yang
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Biosynthesis of Enfumafungin-type Antibiotic Reveals an Unusual Enzymatic Fusion Pattern and Unprecedented C–C Bond Cleavage J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-23 Zhi-Qin Cao, Gao-Qian Wang, Rui Luo, Yao-Hui Gao, Jian-Ming Lv, Sheng-Ying Qin, Guo-Dong Chen, Takayoshi Awakawa, Xue-Feng Bao, Qing-Hua Mei, Xin-Sheng Yao, Dan Hu, Ikuro Abe, Hao Gao
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Nonaggregated Anions Enable the Undercooled Aqueous Electrolyte for Low-Temperature Applications J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-23 Qiu Zhang, Yong Lu, Xiaomeng Liu, Weiwei Xie, Jun Chen
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Photoredox Nucleophilic (Radio)fluorination of Alkoxyamines J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-23 Sebastiano Ortalli, Joseph Ford, Andrés A. Trabanco, Matthew Tredwell, Véronique Gouverneur
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Catalytic, Spectroscopic, and Theoretical Studies of Fe4S4-Based Coordination Polymers as Heterogenous Coupled Proton–Electron Transfer Mediators for Electrocatalysis J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-23 Ningxin Jiang, Andrea Darù, Špela Kunstelj, Jenny G. Vitillo, Maia E. Czaikowski, Alexander S. Filatov, Anna Wuttig, Laura Gagliardi, John S. Anderson
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Rational Design of NIR-II G-Quadruplex Fluorescent Probes for Accurate In Vivo Tumor Metastasis Imaging J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-22 Ren-Xuan Wang, Yifeng Ou, Yushi Chen, Tian-Bing Ren, Lin Yuan, Xiao-Bing Zhang
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Enzyme-Inspired Ligand Engineering of Gold Nanoclusters for Electrocatalytic Microenvironment Manipulation J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-22 Zhihe Liu, Junmei Chen, Bo Li, De-en Jiang, Lei Wang, Qiaofeng Yao, Jianping Xie
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Customizable Organic Charge-Transfer Cocrystals for the Dual-Mode Optoelectronics in the NIR (II) Window J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-22 Yue Yu, Xing-Yu Xia, Chao-Fei Xu, Zhao-Ji Lv, Xue-Dong Wang, Liang-Sheng Liao
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Overdestabilization vs Overstabilization in the Theoretical Analysis of f-Orbital Covalency J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-22 Kirill D. Shumilov, Andrew J. Jenkins, Henry S. La Pierre, Bess Vlaisavljevich, Xiaosong Li
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Can the Rate of a Catalytic Turnover Be Altered by Ligands in the Absence of Direct Binding Interactions? J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-22 Jacklyn N. Hall, Stephen P. Vicchio, A. Jeremy Kropf, Massimiliano Delferro, Praveen Bollini
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Free Radicals Generated in Perfluorocarbon–Water (Liquid–Liquid) Interfacial Contact Electrification and Their Application in Cancer Therapy J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-22 Haimei Li, Zichen Wang, Xu Chu, Yi Zhao, Guangqin He, Yulin Hu, Yi Liu, Zhong Lin Wang, Peng Jiang
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The Mechanism of Rh(I)-Catalyzed Coupling of Benzotriazoles and Allenes Revisited: Substrate Inhibition, Proton Shuttling, and the Role of Cationic vs Neutral Species J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-22 Nora Jannsen, Fabian Reiß, Hans-Joachim Drexler, Katharina Konieczny, Torsten Beweries, Detlef Heller
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Selective Cleavage of α-Olefins to Produce Acetylene and Hydrogen J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-22 Meijia Xu, Zheng-Yang Hu, Xiaoyang Liang, Yifan Zhu, Honghe Ding, Jun Hu, Jinfeng Xu, Zhen Zhu, Zi-ang Wu, Xinwei Zhao, Weijun Guo, Kaiqi Nie, Yifan Ye, Junfa Zhu, Zhi-Pan Liu, Xiong Zhou, Kai Wu
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Growth Process of Fe–O Nanoclusters with Different Sizes Biosynthesized by Protein Nanocages J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-20 Wenming Wang, Hongfang Xi, Dan Fu, Danyang Ma, Wenjun Gong, Yaqin Zhao, Xiaomei Li, Lijie Wu, Yu Guo, Guanghua Zhao, Hongfei Wang
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Consequences of Vibrational Strong Coupling on Supramolecular Polymerization of Porphyrins J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-20 Kripa Joseph, Bas de Waal, Stef A. H. Jansen, Joost J. B. van der Tol, Ghislaine Vantomme, E. W. Meijer
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Chiral Bisphosphine-Catalyzed Asymmetric Staudinger/aza-Wittig Reaction: An Enantioselective Desymmetrizing Approach to Crinine-Type Amaryllidaceae Alkaloids J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-20 Hongzhi Yang, Jingyang Zhang, Sen Zhang, Zhengwen Xue, Shengkun Hu, Yi Chen, Yefeng Tang
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Breaking a Molecular Scaling Relationship Using an Iron–Iron Fused Porphyrin Electrocatalyst for Oxygen Reduction J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-19 Daiki Nishiori, Jan Paul Menzel, Nicholas Armada, Edgar A. Reyes Cruz, Brent L. Nannenga, Victor S. Batista, Gary F. Moore
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Promises and Perils of Big Data: Philosophical Constraints on Chemical Ontologies J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-19 Rebekah Duke, Ryan McCoy, Chad Risko, Julia R. S. Bursten
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Formation of Chromophores from cis-Pinonaldehyde Aged in Highly Acidic Conditions J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-19 Cynthia Wong, Jessica E. Pazienza, Scott D. Rychnovsky, Sergey A. Nizkorodov
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Supramolecular Assembly in Live Cells Mapped by Real-Time Phasor-Fluorescence Lifetime Imaging J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-19 Yong Ren, Zhixuan Zhou, Konrad Maxeiner, Anke Kaltbeitzel, Iain Harley, Jiaqi Xing, Yingke Wu, Manfred Wagner, Katharina Landfester, Ingo Lieberwirth, Tanja Weil, David Y. W. Ng
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Suppressing Metal Leaching and Sintering in Hydroformylation Reaction by Modulating the Coordination of Rh Single Atoms with Reactants J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-19 Zhounan Yu, Shengxin Zhang, Leilei Zhang, Xiaoyan Liu, Zhenghao Jia, Lin Li, Na Ta, An Wang, Wei Liu, Aiqin Wang, Tao Zhang
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Multiphosphorylation-Dependent Recognition of Anti-pS2 Antibodies against RNA Polymerase II C-Terminal Domain Revealed by Chemical Synthesis J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-19 Emanuele Piemontese, Alina Herfort, Yulia Perevedentseva, Heiko M. Möller, Oliver Seitz
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Artificial Photosynthases: Single-Chain Nanoparticles with Manifold Visible-Light Photocatalytic Activity for Challenging “in Water” Organic Reactions J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-19 Davide Arena, Ester Verde-Sesto, Iván Rivilla, José A. Pomposo
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Manganese(III) Nitrate Complexes as Bench-Stable Powerful Oxidants J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-19 Ananya Saju, Matthew R. Crawley, Samantha N. MacMillan, David C. Lacy
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A single hydrogen bond that tunes flavin redox reactivity and activates it for modification Chem. Sci. (IF 8.4) Pub Date : 2024-04-24 Debarati Das, Anne-Frances Miller
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Visualizing partial solvation at the air–water interface Chem. Sci. (IF 8.4) Pub Date : 2024-04-24 Kenneth D. Judd, Sean W. Parsons, Dmitry B. Eremin, Valery V. Fokin, Jahan M. Dawlaty
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Biosynthesis of the Bacterial Antibiotic 3,7-Dihydroxytropolone through Enzymatic Salvaging of Catabolic Shunt Products Chem. Sci. (IF 8.4) Pub Date : 2024-04-24 Lars Höing, Sven T. Sowa, Marina Toplak, Jakob Klaus Reinhardt, Roman P Jakob, Timm Maier, Markus A. Lill, Robin Teufel
The non-benzenoid aromatic tropone ring is a structural motif of numerous microbial and plant natural products with potent bioactivities. In bacteria, tropone biosynthesis involves early steps of the widespread CoA-dependent phenylacetic acid (paa) catabolon, from which a shunt product is sequestered and surprisingly further utilized as universal precursor for structurally and functionally diverse
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De-epimerizing DyKAT of β-Lactones Generated by Isothiourea-Catalysed Enantioselective [2+2] Cycloaddition Chem. Sci. (IF 8.4) Pub Date : 2024-04-24 Aífe Conboy, Alister S. Goodfellow, Kevin Kasten, Joanne Dunne, David Bradford Cordes, Michael Buehl, Andrew D Smith
Moderate diastereoselectivity (typically 70:30 dr) is observed in the isothiourea-catalysed [2+2]-cycloaddition of C(1)-ammonium enolates with pyrazol-4,5-diones to generate spirocyclic β lactones, but subsequent ring-opening with morpholine generatesβ hydroxyamide products with enhanced stereoselectivity (up to >95:5 dr). Stereoconvergence is observed in the ring-opening of diastereoisomeric β lactones
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Materials Discovery with Extreme Properties via Reinforcement Learning-Guided Combinatorial Chemistry Chem. Sci. (IF 8.4) Pub Date : 2024-04-24 Hyunseung Kim, Haeyeon Choi, Dongju Kang, Won Bo Lee, Jonggeol Na
The goal of most materials discovery is to discover materials that are superior to those currently known. Fundamentally, this is close to extrapolation, which is a weak point for most machine learning models that learn the probability distribution of data. Herein, we develop reinforcement learning-guided combinatorial chemistry, which is a rule-based molecular designer driven by trained policy for
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Nickel/Photoredox-Catalyzed Three-Component Silylacylation of Acrylates via Chlorine Photoelimination Chem. Sci. (IF 8.4) Pub Date : 2024-04-24 Yejin Koo, Sungwoo Hong
The extensive utility of organosilicon compounds across a wide range of disciplines has sparked significant interest in their efficient synthesis. Although catalytic 1,2-silyldifunctionalization of alkenes provides a promising method for the assembly of intricate organosilicon frameworks with atom and step economy, its advancement is hindered by the requirement of an external hydrogen atom transfer
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Contracted porphyrins and calixpyrroles: synthetic challenges and ring-contraction effects Chem. Sci. (IF 8.4) Pub Date : 2024-04-24 Keita Watanabe, Narendra Nath Pati, Yasuhide Inokuma
Ring-contracted porphyrin analogues, such as subporphyrins and calix[3]pyrroles, have recently attracted considerable attention not only as challenging synthetic targets but also as functional macrocyclic compounds. Although canonical porphyrins and calix[4]pyrrole are selectively generated via acid-catalyzed condensation reactions of pyrrole monomers, their tripyrrolic analogues are always missing
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Observation of super-Nernstian proton-coupled electron transfer and elucidation of nature of charge carriers in a multiredox conjugated polymer Chem. Sci. (IF 8.4) Pub Date : 2024-04-22 Duyen K. Tran, Sarah M. West, Elizabeth M. K. Speck, Samson A. Jenekhe
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Self-assembled tetrazine cryptophane for ion pair recognition and guest release by cage disassembly Chem. Commun. (IF 4.9) Pub Date : 2024-04-24 Louise Miton, Elise Antonetti, Marie Poujade, Jean-Pierre Dutasta, Paola Nava, Alexandre Martinez, Yoann Cotelle
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Quecretin@UiO-66 NPs and Chloroquine in Combined Tumor Therapy by Dual Autophagy-Ubiquitination System Blockade Chem. Commun. (IF 4.9) Pub Date : 2024-04-24 Yinzhu Chen, FeiYi Yan, Yue Yang, Lipeng Zhang, Xuepeng Teng, Shuai-Yu Wang, Tianlong Liu
In the study, a noveltherapy system composed of UiO-66 nanoparticles containing quercetin combined with chloroquine to achieve dual autophagy-ubiquitination blockade. Quercetin is known as a proteasome inhibitor, and through UiO-66 NPs drug loading, the solubility of quercetin under physiological conditions was improved to increase its effective concentration at the tumor site. The cell experiment
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Novel dual near-infrared fluorescent probe for bioimaging and visualization of viscosity in acute alcoholic liver injury Chem. Commun. (IF 4.9) Pub Date : 2024-04-24 Ruonan Wang, Xucong Zhou, Bingxue Li, Ru Ding, Jingqian Han, Ying Wang, Aixia Meng, Jin Zhou
A dual NIR fluorescent probe Cy-ND is developed for viscosity sensing with λex/em = 766/806nm, making Cy-ND apt for biological analysis, whose response is validated through DFT and TDDFT computations. Cy-ND successfully detected viscosity changes amidst acute alcohol-induced liver injury and liver ischemia-reperfusion injury.
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Mechanoresponsive luminescence triggered by phase transition of a supercooled copper(I) complex Chem. Commun. (IF 4.9) Pub Date : 2024-04-24 Jérémy Delafoulhouze, Marie Cordier, Jean-Yves Mevellec, Florian Massuyeau, Olivier Hernandez, Camille Latouche, Sandrine Perruchas
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Gold carbonyl cations and beyond: Homoleptic gold(I) complexes with P4 and P4S3 and the half-sandwich cation [Au(C6H6)(CO)]+ Chem. Commun. (IF 4.9) Pub Date : 2024-04-24 Manuel Schmitt, Sarah Nestle, Valentin Radtke, Ingo Krossing
Oxidation of Au0 with the synergistic Ag+/0.5 I2 system in the commercial organic solvent 1,2,3,4-tetrafluorobenzene led to the per¬fluoro¬alkoxyaluminate salt of the [Au(CO)2]+ cation known from superacid chemistry. This [Au(CO)2]+ salt proved to be an excellent ‘naked’ Au+-synthon yielding complex salts with [Au(η2-P4)2]+, [Au(η1-P4S3)2]+ and half-sandwich [Au(η2-C6H6)(CO)]+ cation.
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Exploring Present and Future Directions in Nano-Enhanced Optoelectronic Neuromodulation Acc. Chem. Res. (IF 18.3) Pub Date : 2024-04-23 Chuanwang Yang, Zhe Cheng, Pengju Li, Bozhi Tian
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Multifacets of Fullerene–Metal Clusters: From Fundamental to Application Acc. Chem. Res. (IF 18.3) Pub Date : 2024-04-23 Jianzhi Xu, Ya-Ke Li, Ewald Janssens, Gao-Lei Hou
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Induced Aggregation, Solvent Regulation, and Supracluster Assembly of Aluminum Oxo Clusters Acc. Chem. Res. (IF 18.3) Pub Date : 2024-04-23 Wei-Hui Fang, Yu-Long Xie, San-Tai Wang, Ya-Jie Liu, Jian Zhang
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Catalyst: Curtailing the scalable supply of fentanyl by using chemical AI Chem (IF 23.5) Pub Date : 2024-04-23 Barbara Mikulak-Klucznik, Tomasz Klucznik, Wiktor Beker, Martyna Moskal, Bartosz A. Grzybowski
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Conjugated ladder polymers: Advances from syntheses to applications Chem (IF 23.5) Pub Date : 2024-04-23 James Shao-Jiun Yang, Lei Fang
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Reaction: Don’t hate the player in chemical AI; hate the game Chem (IF 23.5) Pub Date : 2024-04-23 Gordon Broderick
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Reaction: Navigating the promises and perils of AI-powered drug synthesis Chem (IF 23.5) Pub Date : 2024-04-23 Rick A. Bright
Rick Bright is the chief executive of Bright Global Health and former deputy assistant secretary for preparedness and response and director of BARDA at the US Department of Health and Human Services. An international expert in biodefense, emergency preparedness, pharmaceutical innovation, and public health, Dr. Bright is a member of the Council on Foreign Relations, senior fellow of the Foreign Policy
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A MOF nanoparticle@carbon aerogel integrated photothermal catalytic microreactor for CO2 utilization Chem. Commun. (IF 4.9) Pub Date : 2024-04-23 Junyi Chen, Lei Shao, Bing Zhang, Weiliang Tian, Yu Fu, Liying Zhang
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Rhodium-catalyzed three-component C(sp3)/C(sp2)−H activation enabled by two-fold directing groups strategy. Chem. Commun. (IF 4.9) Pub Date : 2024-04-23 Fucheng Hou, Jiale Zhang, Zirui Wang, Zhongyuan Li
The Rh-catalzyed three-component C(sp3)/C(sp2)−H activation has been achieved through a two-directing group strategy. This protocol provides a convenient and efficient pathway for the construction of diverse 8-alkyl quinoline derivatives in one-pot. Furthermore, mechanistic studies revealed the first C−H amidation was significant faster than the sequential C−H alkylation.
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Correction: A closer look at ligand specificity for cellular activation of NOD2 with synthetic muramyl dipeptide analogues Chem. Commun. (IF 4.9) Pub Date : 2024-04-23 Christopher Adamson, Yaquan Liang, Shiliu Feng, Allan Wee Ren Ng, Yuan Qiao
Correction for ‘A closer look at ligand specificity for cellular activation of NOD2 with synthetic muramyl dipeptide analogues’ by Christopher Adamson et al., Chem. Commun., 2024, 60, 2212–2215, https://doi.org/10.1039/D3CC05807G.
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Two structurally new Lindqvist hexaniobate-templated silver thiolate clusters Chem. Commun. (IF 4.9) Pub Date : 2024-04-23 Zichen Zhao, Mengyun Zhao, Lan Deng, Qing Li, Jing Zhang, Hai-Feng Su, Hongjin Lv, Guo-Yu Yang
Two structurally new Lindqvist hexaniobate-templated silver thiolate clusters, [Nb6O19@Ag45(iPrS)23(CH3COO)14] (Ag45) and (H3O)4[Nb6O19@Ag41KS2.5O2(H2O)7.5(iPrS)24(CH3COO)5] (Ag41), were synthesized using a facile one-pot solvothermal approach. Single crystal X-ray diffraction analyses revealed the presence of a classical Lindqvist-type [Nb6O19]8− anion template, the iPrS− and CH3COO− surface-protecting