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Promoting H2 generation of BiFeO3 photocathode by a catalyst-sensitizer dyad linked with Sn(dipicolinate)2 Chem. Commun. (IF 4.9) Pub Date : 2024-04-25 Meiqi Yan, Yingzheng Li, Chang Liu, Ziqi Zhao, Yu Shan, Fei Li, Licheng Sun, Fusheng Li
An innovative method for the fabrication of catalyst-sensitizer dyad-based photoelectrode was developed by using the coordinated interaction between the pyridine-2,6-dicarboxylic group and Sn4+. A dyad (C1+PDI) was loaded on the mesoporous BiFeO3 (BFO) photocathode for light-driven H2 generation. The dyad could expand the light absorption range and promote the surface charge separation of BFO, resulting
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Ultrafast Au(III)-Mediated Arylation of Cysteine J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-24 Evan A. Doud, James A. R. Tilden, Joseph W. Treacy, Elaine Y. Chao, Hayden R. Montgomery, Grace E. Kunkel, Eileen J. Olivares, Nima Adhami, Tyler A. Kerr, Yu Chen, Arnold L. Rheingold, Joseph A. Loo, Christopher G. Frost, K. N. Houk, Heather D. Maynard, Alexander M. Spokoyny
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Excited State Dynamics in Unidirectional Photochemical Molecular Motors J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-24 Palas Roy, Andy S. Sardjan, Wesley R. Browne, Ben L. Feringa, Stephen R. Meech
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Three-Dimensional Crystalline Organic Framework Stabilized by Molecular Mortise-and-Tenon Jointing J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-24 Xinru Sheng, Zeju Wang, Guan Sheng, Chongzhi Zhu, Ding Xiao, Tianyu Shan, Xuedong Xiao, Ming Liu, Guangfeng Li, Yihan Zhu, Jonathan L. Sessler, Feihe Huang
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Molecular Motors’ Magic Methyl and Its Pivotal Influence on Rotation J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-24 Yohan Gisbert, Maximilian Fellert, Charlotte N. Stindt, Alexander Gerstner, Ben L. Feringa
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Doubly Spiro-Conjugated Chiral Carbocycles Exhibiting SOMO–HOMO Inversion in Persistent Radical Cations J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-24 Takumi Sakamaki, Yan Zhang, Shota Fukuma, Carlos M. Cruz, Abel Cárdenas Valdivia, Araceli G. Campaña, Juan Casado, Rui Shang, Eiichi Nakamura
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An Atomic and Molecular Insight into How PFOA Reduces α-Helicity, Compromises Substrate Binding, and Creates Binding Pockets in a Model Globular Protein J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-24 Anju Yadav, Lela Vuković, Mahesh Narayan
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Degradable π-Conjugated Polymers J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-24 Azalea Uva, Sofia Michailovich, Nathan Sung Yuan Hsu, Helen Tran
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Spotlights on Recent JACS Publications, Volume 146, Issue 18 J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-24 ACS Contributing Correspondents
This article has not yet been cited by other publications.
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Probing Ion–Receptor Interactions in Halide Complexes of Octamethyl Calix[4]Pyrrole J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-23 Lane M. Terry, Madison M. Foreman, Anne P. Rasmussen, Anne B. McCoy, J. Mathias Weber
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Tuning Photoredox Catalysis of Ruthenium with Palladium: Synthesis of Heterobimetallic Ru–Pd Complexes That Enable Efficient Photochemical Reduction of CO2 J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-23 Siteng Yang, Yuto Morita, Yuta Nakamura, Nobuharu Iwasawa, Jun Takaya
New Ru–Pd heterobimetallic complexes were synthesized and structurally characterized utilizing 6,6″-bis(phosphino)-2,2′:6′,2″-terpyridine as a scaffold for the metal–metal bond. The dicationic Ru–Pd complex was found to exhibit high catalytic activity as a photocatalyst for photochemical reduction of CO2 to CO under visible light irradiation. This study established a new design of transition metal
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Machine Learning for Experimental Reactivity of a Set of Metal Clusters toward C–H Activation J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-23 Xi-Guan Zhao, Qi Yang, Ying Xu, Qing-Yu Liu, Zi-Yu Li, Xiao-Xiao Liu, Yan-Xia Zhao, Sheng-Gui He
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Water Hydrogen-Bond Mediated Layer by Layer Alignment of Lipid Rafts as a Precursor of Intermembrane Processes J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-23 Suho Lee, Ji Hyun Bak, Yuno Lee, Dae-Woong Jeong, Jaehee Lee, KeunMin Ken Lee, Hasaeam Cho, Hyun Hwi Lee, Changbong Hyeon, Myung Chul Choi
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Reconstructable Carbon Monolayer-MoS2 Intercalated Heterostructure Enabled by Atomic Layers-Confined Topotactic Transformation for Ultrafast Lithium Storage J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-23 Kexuan Liao, Lu Chen, Ruijin Meng, Yutong Feng, Shuo Meng, Hang Lu, Jie Ma, Chengxin Peng, Chi Zhang, Jinhu Yang
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Biosynthesis of Enfumafungin-type Antibiotic Reveals an Unusual Enzymatic Fusion Pattern and Unprecedented C–C Bond Cleavage J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-23 Zhi-Qin Cao, Gao-Qian Wang, Rui Luo, Yao-Hui Gao, Jian-Ming Lv, Sheng-Ying Qin, Guo-Dong Chen, Takayoshi Awakawa, Xue-Feng Bao, Qing-Hua Mei, Xin-Sheng Yao, Dan Hu, Ikuro Abe, Hao Gao
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Nonaggregated Anions Enable the Undercooled Aqueous Electrolyte for Low-Temperature Applications J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-23 Qiu Zhang, Yong Lu, Xiaomeng Liu, Weiwei Xie, Jun Chen
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Photoredox Nucleophilic (Radio)fluorination of Alkoxyamines J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-23 Sebastiano Ortalli, Joseph Ford, Andrés A. Trabanco, Matthew Tredwell, Véronique Gouverneur
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Catalytic, Spectroscopic, and Theoretical Studies of Fe4S4-Based Coordination Polymers as Heterogenous Coupled Proton–Electron Transfer Mediators for Electrocatalysis J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-23 Ningxin Jiang, Andrea Darù, Špela Kunstelj, Jenny G. Vitillo, Maia E. Czaikowski, Alexander S. Filatov, Anna Wuttig, Laura Gagliardi, John S. Anderson
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Rational Design of NIR-II G-Quadruplex Fluorescent Probes for Accurate In Vivo Tumor Metastasis Imaging J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-22 Ren-Xuan Wang, Yifeng Ou, Yushi Chen, Tian-Bing Ren, Lin Yuan, Xiao-Bing Zhang
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Enzyme-Inspired Ligand Engineering of Gold Nanoclusters for Electrocatalytic Microenvironment Manipulation J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-22 Zhihe Liu, Junmei Chen, Bo Li, De-en Jiang, Lei Wang, Qiaofeng Yao, Jianping Xie
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Customizable Organic Charge-Transfer Cocrystals for the Dual-Mode Optoelectronics in the NIR (II) Window J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-22 Yue Yu, Xing-Yu Xia, Chao-Fei Xu, Zhao-Ji Lv, Xue-Dong Wang, Liang-Sheng Liao
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Overdestabilization vs Overstabilization in the Theoretical Analysis of f-Orbital Covalency J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-22 Kirill D. Shumilov, Andrew J. Jenkins, Henry S. La Pierre, Bess Vlaisavljevich, Xiaosong Li
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Can the Rate of a Catalytic Turnover Be Altered by Ligands in the Absence of Direct Binding Interactions? J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-22 Jacklyn N. Hall, Stephen P. Vicchio, A. Jeremy Kropf, Massimiliano Delferro, Praveen Bollini
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Free Radicals Generated in Perfluorocarbon–Water (Liquid–Liquid) Interfacial Contact Electrification and Their Application in Cancer Therapy J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-22 Haimei Li, Zichen Wang, Xu Chu, Yi Zhao, Guangqin He, Yulin Hu, Yi Liu, Zhong Lin Wang, Peng Jiang
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The Mechanism of Rh(I)-Catalyzed Coupling of Benzotriazoles and Allenes Revisited: Substrate Inhibition, Proton Shuttling, and the Role of Cationic vs Neutral Species J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-22 Nora Jannsen, Fabian Reiß, Hans-Joachim Drexler, Katharina Konieczny, Torsten Beweries, Detlef Heller
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Selective Cleavage of α-Olefins to Produce Acetylene and Hydrogen J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-22 Meijia Xu, Zheng-Yang Hu, Xiaoyang Liang, Yifan Zhu, Honghe Ding, Jun Hu, Jinfeng Xu, Zhen Zhu, Zi-ang Wu, Xinwei Zhao, Weijun Guo, Kaiqi Nie, Yifan Ye, Junfa Zhu, Zhi-Pan Liu, Xiong Zhou, Kai Wu
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Growth Process of Fe–O Nanoclusters with Different Sizes Biosynthesized by Protein Nanocages J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-20 Wenming Wang, Hongfang Xi, Dan Fu, Danyang Ma, Wenjun Gong, Yaqin Zhao, Xiaomei Li, Lijie Wu, Yu Guo, Guanghua Zhao, Hongfei Wang
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Consequences of Vibrational Strong Coupling on Supramolecular Polymerization of Porphyrins J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-20 Kripa Joseph, Bas de Waal, Stef A. H. Jansen, Joost J. B. van der Tol, Ghislaine Vantomme, E. W. Meijer
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Chiral Bisphosphine-Catalyzed Asymmetric Staudinger/aza-Wittig Reaction: An Enantioselective Desymmetrizing Approach to Crinine-Type Amaryllidaceae Alkaloids J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-20 Hongzhi Yang, Jingyang Zhang, Sen Zhang, Zhengwen Xue, Shengkun Hu, Yi Chen, Yefeng Tang
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Breaking a Molecular Scaling Relationship Using an Iron–Iron Fused Porphyrin Electrocatalyst for Oxygen Reduction J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-19 Daiki Nishiori, Jan Paul Menzel, Nicholas Armada, Edgar A. Reyes Cruz, Brent L. Nannenga, Victor S. Batista, Gary F. Moore
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Promises and Perils of Big Data: Philosophical Constraints on Chemical Ontologies J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-19 Rebekah Duke, Ryan McCoy, Chad Risko, Julia R. S. Bursten
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Formation of Chromophores from cis-Pinonaldehyde Aged in Highly Acidic Conditions J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-19 Cynthia Wong, Jessica E. Pazienza, Scott D. Rychnovsky, Sergey A. Nizkorodov
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Supramolecular Assembly in Live Cells Mapped by Real-Time Phasor-Fluorescence Lifetime Imaging J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-19 Yong Ren, Zhixuan Zhou, Konrad Maxeiner, Anke Kaltbeitzel, Iain Harley, Jiaqi Xing, Yingke Wu, Manfred Wagner, Katharina Landfester, Ingo Lieberwirth, Tanja Weil, David Y. W. Ng
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Suppressing Metal Leaching and Sintering in Hydroformylation Reaction by Modulating the Coordination of Rh Single Atoms with Reactants J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-19 Zhounan Yu, Shengxin Zhang, Leilei Zhang, Xiaoyan Liu, Zhenghao Jia, Lin Li, Na Ta, An Wang, Wei Liu, Aiqin Wang, Tao Zhang
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Multiphosphorylation-Dependent Recognition of Anti-pS2 Antibodies against RNA Polymerase II C-Terminal Domain Revealed by Chemical Synthesis J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-19 Emanuele Piemontese, Alina Herfort, Yulia Perevedentseva, Heiko M. Möller, Oliver Seitz
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Artificial Photosynthases: Single-Chain Nanoparticles with Manifold Visible-Light Photocatalytic Activity for Challenging “in Water” Organic Reactions J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-19 Davide Arena, Ester Verde-Sesto, Iván Rivilla, José A. Pomposo
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Manganese(III) Nitrate Complexes as Bench-Stable Powerful Oxidants J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-04-19 Ananya Saju, Matthew R. Crawley, Samantha N. MacMillan, David C. Lacy
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A Comparison of Molecular Iodine Evolution on the Chemistry of Lead and Tin Perovskites Energy Environ. Sci. (IF 32.5) Pub Date : 2024-04-24 Thomas Webb, Saif Ahmed Haque
The development of perovskite solar cells (PSCs) has gone from strength to strength over the last decade, enabling low-cost, flexible and high-efficiency photovoltaic devices. However, the significance of molecular iodine (I2) evolution within the perovskite layer on device longevity is only recently becoming realised. In lead-based perovskites, the formation of I2 is determinantal to both the photovoltaic
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Urea Electrochemical Production Using Carbon Dioxide and Nitrate: State of the Art and Perspectives Energy Environ. Sci. (IF 32.5) Pub Date : 2024-04-24 Mohsin Muhyuddin, Giovanni Zuccante, Piercarlo Mustarelli, Jonathan Filippi, Alessandro Lavacchi, Lior Elbaz, Yu-Han Chen, Plamen Atanassov, Carlo Santoro
Complete decarbonization of hard-to-abate industrial sectors is critical to reach the carbon neutrality goal set for 2050. The production of nitrogen-containing fertilizers (N-fertilizers) is responsible for 2.1% of the overall global carbon dioxide emissions. Urea is the most common N-fertilizer, and it is currently produced through the Bosch-Meiser process starting from ammonia (NH3) and carbon dioxide
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Silicon nanowire/ionic hydrogel-based hybrid moist-electric generators with enhanced voltage output and operational stability Energy Environ. Sci. (IF 32.5) Pub Date : 2024-04-24 Wenjing Duan, Beibei Shao, Zhiqi Wang, Kun Ni, Shanfei Liu, Xianrong Yuan, Yusheng Wang, Baoquan Sun, Xiaohong Zhang, Ruiyuan Liu
Moist electric generators (MEGs) are promising portable power sources for harvesting energy from atmospheric moisture. However, the lack of an efficient device design and the associated working mechanisms related to ion interactions have resulted in relatively low electrical performance and short output times. In this study, we developed an efficient organic–inorganic hybrid MEG by in situ preparation
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Metalation of metal–organic frameworks: fundamentals and applications Chem. Soc. Rev. (IF 46.2) Pub Date : 2024-04-24 Hai-Yu Li, Xiang-Jing Kong, Song-De Han, Jiandong Pang, Tao He, Guo-Ming Wang, Xian-He Bu
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Structural disorder determines capacitance in nanoporous carbons Science (IF 56.9) Pub Date : 2024-04-19 Xinyu Liu, Dongxun Lyu, Céline Merlet, Matthew J. A. Leesmith, Xiao Hua, Zhen Xu, Clare P. Grey, Alexander C. Forse
The difficulty in characterizing the complex structures of nanoporous carbon electrodes has led to a lack of clear design principles with which to improve supercapacitors. Pore size has long been considered the main lever to improve capacitance. However, our evaluation of a large series of commercial nanoporous carbons finds a lack of correlation between pore size and capacitance. Instead, nuclear
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High energy density in artificial heterostructures through relaxation time modulation Science (IF 56.9) Pub Date : 2024-04-19 Sangmoon Han, Justin S. Kim, Eugene Park, Yuan Meng, Zhihao Xu, Alexandre C. Foucher, Gwan Yeong Jung, Ilpyo Roh, Sangho Lee, Sun Ok Kim, Ji-Yun Moon, Seung-Il Kim, Sanggeun Bae, Xinyuan Zhang, Bo-In Park, Seunghwan Seo, Yimeng Li, Heechang Shin, Kate Reidy, Anh Tuan Hoang, Suresh Sundaram, Phuong Vuong, Chansoo Kim, Junyi Zhao, Jinyeon Hwang, Chuan Wang, Hyungil Choi, Dong-Hwan Kim, Jimin Kwon, Jin-Hong
Electrostatic capacitors are foundational components of advanced electronics and high-power electrical systems owing to their ultrafast charging-discharging capability. Ferroelectric materials offer high maximum polarization, but high remnant polarization has hindered their effective deployment in energy storage applications. Previous methodologies have encountered problems because of the deteriorated
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Evolution of the flat band and the role of lattice relaxations in twisted bilayer graphene Nat. Mater. (IF 41.2) Pub Date : 2024-04-24 Qian Li, Hongyun Zhang, Yijie Wang, Wanying Chen, Changhua Bao, Qinxin Liu, Tianyun Lin, Shuai Zhang, Haoxiong Zhang, Kenji Watanabe, Takashi Taniguchi, Jose Avila, Pavel Dudin, Qunyang Li, Pu Yu, Wenhui Duan, Zhida Song, Shuyun Zhou
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Impact of global heterogeneity of renewable energy supply on heavy industrial production and green value chains Nat. Energy (IF 56.7) Pub Date : 2024-04-24 Philipp C. Verpoort, Lukas Gast, Anke Hofmann, Falko Ueckerdt
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Constructing artificial gap junctions to mediate intercellular signal and mass transport Nat. Chem. (IF 21.8) Pub Date : 2024-04-24 Yong-Hong Fu, Yi-Fei Hu, Tao Lin, Guo-Wei Zhuang, Ying-Lan Wang, Wen-Xue Chen, Zhan-Ting Li, Jun-Li Hou
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First glowing animals lit up the oceans half a billion years ago Nature (IF 64.8) Pub Date : 2024-04-24
Family tree of ‘octocorals’ pushes origin of bioluminescence back to 540 million years ago, when the first animal species developed eyes.
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Las Boriqueñas remembers the forgotten Puerto Rican women who tested the first pill Nature (IF 64.8) Pub Date : 2024-04-24
Clinical trials of the first oral contraceptive recalled in a bold theatre production.
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Ecologists: don’t lose touch with the joy of fieldwork Nature (IF 64.8) Pub Date : 2024-04-24
Amid the data deluge provided by lab-based techniques, such as environmental-DNA analysis, true connection still comes only in the outdoors.
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WHO redefines airborne transmission: what does that mean for future pandemics? Nature (IF 64.8) Pub Date : 2024-04-24
The World Health Organization was criticized for being too slow to classify COVID-19 as airborne. Will the new terminology help next time?
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A chemical method for selective labelling of the key amino acid tryptophan Nature (IF 64.8) Pub Date : 2024-04-24
A technique that accurately identifies tryptophan side chains in proteins helps reveal interactions with positively charged molecules.
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Monkeypox virus: dangerous strain gains ability to spread through sex, new data suggest Nature (IF 64.8) Pub Date : 2024-04-23
A cluster of mpox cases in the Democratic Republic of the Congo sparks worries of a wider outbreak.
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AI & robotics briefing: Winged robot demystifies insect flight Nature (IF 64.8) Pub Date : 2024-04-23
Robot fly helps to unravel the workings of the insect wing hinge. Plus, AI traces mysterious metastatic cancers to their source and general rules for AI in publishing are coming.
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A single hydrogen bond that tunes flavin redox reactivity and activates it for modification Chem. Sci. (IF 8.4) Pub Date : 2024-04-24 Debarati Das, Anne-Frances Miller
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Visualizing partial solvation at the air–water interface Chem. Sci. (IF 8.4) Pub Date : 2024-04-24 Kenneth D. Judd, Sean W. Parsons, Dmitry B. Eremin, Valery V. Fokin, Jahan M. Dawlaty
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Biosynthesis of the Bacterial Antibiotic 3,7-Dihydroxytropolone through Enzymatic Salvaging of Catabolic Shunt Products Chem. Sci. (IF 8.4) Pub Date : 2024-04-24 Lars Höing, Sven T. Sowa, Marina Toplak, Jakob Klaus Reinhardt, Roman P Jakob, Timm Maier, Markus A. Lill, Robin Teufel
The non-benzenoid aromatic tropone ring is a structural motif of numerous microbial and plant natural products with potent bioactivities. In bacteria, tropone biosynthesis involves early steps of the widespread CoA-dependent phenylacetic acid (paa) catabolon, from which a shunt product is sequestered and surprisingly further utilized as universal precursor for structurally and functionally diverse
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De-epimerizing DyKAT of β-Lactones Generated by Isothiourea-Catalysed Enantioselective [2+2] Cycloaddition Chem. Sci. (IF 8.4) Pub Date : 2024-04-24 Aífe Conboy, Alister S. Goodfellow, Kevin Kasten, Joanne Dunne, David Bradford Cordes, Michael Buehl, Andrew D Smith
Moderate diastereoselectivity (typically 70:30 dr) is observed in the isothiourea-catalysed [2+2]-cycloaddition of C(1)-ammonium enolates with pyrazol-4,5-diones to generate spirocyclic β lactones, but subsequent ring-opening with morpholine generatesβ hydroxyamide products with enhanced stereoselectivity (up to >95:5 dr). Stereoconvergence is observed in the ring-opening of diastereoisomeric β lactones
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Materials Discovery with Extreme Properties via Reinforcement Learning-Guided Combinatorial Chemistry Chem. Sci. (IF 8.4) Pub Date : 2024-04-24 Hyunseung Kim, Haeyeon Choi, Dongju Kang, Won Bo Lee, Jonggeol Na
The goal of most materials discovery is to discover materials that are superior to those currently known. Fundamentally, this is close to extrapolation, which is a weak point for most machine learning models that learn the probability distribution of data. Herein, we develop reinforcement learning-guided combinatorial chemistry, which is a rule-based molecular designer driven by trained policy for
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Nickel/Photoredox-Catalyzed Three-Component Silylacylation of Acrylates via Chlorine Photoelimination Chem. Sci. (IF 8.4) Pub Date : 2024-04-24 Yejin Koo, Sungwoo Hong
The extensive utility of organosilicon compounds across a wide range of disciplines has sparked significant interest in their efficient synthesis. Although catalytic 1,2-silyldifunctionalization of alkenes provides a promising method for the assembly of intricate organosilicon frameworks with atom and step economy, its advancement is hindered by the requirement of an external hydrogen atom transfer