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Assessment of Performance and Deactivation Resistance of Catalysts in the Pyrolysis of Polyethylene and Post-Consumer Polyolefin Waste Macromol. React. Eng. (IF 1.5) Pub Date : 2024-03-20 Katiane de Jesus Mesquita, José Carlos Pinto, Henrique Poltronieri Pacheco
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Dispersion Polymerization of N-Vinyl-2-Pyrrolidone in Supercritical Carbon Dioxide in the Presence of Thiol-Terminated Poly(vinyl acetate-co-vinyl propionate) Macromol. React. Eng. (IF 1.5) Pub Date : 2024-03-08 Shoucun Zhang, Shengyan Wang, Wenli Wu, Jinlong Wu, Jianghua Du
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Mass Transfer in Emulsion Polymerization: High Solids Content Latex and Mixing Effects Macromol. React. Eng. (IF 1.5) Pub Date : 2024-02-18 Mariana Guadalupe Torres Aladro, Estela Kamile Gelinski, Nida Sheibat-Othman, Timothy F. L. McKenna
The impact of different agitator configurations used during the emulsion polymerization of vinylidene fluoride (VDF) was studied with the goal of achieving a solids content of 55 wt % while minimizing particle coagulation and maintaining low levels of surfactant. The design and number of impellers, their spacing and the agitation speed were shown to have a strong influence on the transfer of gaseous
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Digital Twin for the SBR Cold Emulsion Copolymerization Process Macromol. React. Eng. (IF 1.5) Pub Date : 2024-02-02 Roymel R. Carpio, Thiago Feital, Maurício M. Câmara, Flávio Gerhardt, Leo Lincoln Oliveira, José Carlos Pinto
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Impact of Ionic Strength (Sodium Chloride Concentration) on Homopolymerization and Copolymerization Kinetics of Acrylamide and 2-Acrylamido-2-Methylpropane Sulfonic Acid Macromol. React. Eng. (IF 1.5) Pub Date : 2024-01-25 Ian D. Conrod, Baris Topcuoglu, Alexander Penlidis, Alison J. Scott
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Polymer Versus Polymerization Fouling: Basic Deposition Mechanisms During Emulsion Polymerization by the Example of a Vinyl Acetate and Versa 10 Copolymer Macromol. React. Eng. (IF 1.5) Pub Date : 2024-01-09 Annika Klinkert, Zoe Friedrich, Elisabeth Glatt, Wolfgang Augustin, Stephan Scholl
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Mechanical, Rheological, and Heat Seal Properties of 1-Octene Grafted Low Density Polyethylene Films Macromol. React. Eng. (IF 1.5) Pub Date : 2023-12-26 Fatemeh Salmani, Rasoul Shemshadi, Issa Mousazadeh Moghaddampour, Shervin Ahmadi, Ghasem Naderi, Razi Sahraeian, Seyed Mohamad Reza Paran
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Investigating The Kinetics of Anionic Polymerization of Butadiene in Presence of 1,2-diethoxypropane Using Online Near-Infrared Spectroscopy Macromol. React. Eng. (IF 1.5) Pub Date : 2023-12-20 Luis Rodriguez-Guadarrama
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What Can Industrial Catalytic Olefin Polymerization Plants Tell Us About Reaction Kinetics? From Production Rate and Residence Time to Catalyst Reaction Performance. Macromol. React. Eng. (IF 1.5) Pub Date : 2023-11-29 Vasileios Touloupidis, João B. P. Soares
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On-Line Monitoring Device for Gas Phase Composition Based on Machine Learning Models and Its Application in the Gas Phase Copolymerization of Olefins Macromol. React. Eng. (IF 1.5) Pub Date : 2023-10-20 Xu Huang, Shaojie Zheng, Zhen Yao, Bogeng Li, Wenbo Yuan, Qiwei Ding, Zong Wang, Jijiang Hu
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Toward Reactive Processing of Polyamide 6 Based Blends with Polyethylene Grafted with Maleic Anhydride and Acrylic Acid: Effect of Functionalization Degree Macromol. React. Eng. (IF 1.5) Pub Date : 2023-10-18 Carlos Bruno Barreto Luna, Eduardo da Silva Barbosa Ferreira, Anna Raffaela de Matos Costa, Yeda Medeiros Bastos de Almeida, João Baptista da Costa Agra de Melo, Edcleide Maria Araújo
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Monomer Transport in Emulsion Polymerization IV Gaseous Monomers Macromol. React. Eng. (IF 1.5) Pub Date : 2023-10-19 Julia Merlin, F. Joseph Schork
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Dimensions of Large-Sized Network Polymers Formed in Miniemulsion Polymerization Macromol. React. Eng. (IF 1.5) Pub Date : 2023-10-06 Hidetaka Tobita
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Liquid–Liquid Equilibrium in Xylene Solubles (XS) Analysis of Polypropylene Macromol. React. Eng. (IF 1.5) Pub Date : 2023-10-02 Afrânio Melo, Fernando L. P. Pessoa, José Carlos Pinto
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Functionalization of Polymer Networks to Target Trans-Resveratrol in Winemaking Residues Supported by Statistical Design of Experiments Macromol. React. Eng. (IF 1.5) Pub Date : 2023-08-18 Amir Bzainia, Rolando C. S. Dias, Mário Rui P. F. N. Costa
Back Cover: Polymer networks are synthesized to selectively target trans-resveratrol. By employing a statistical design of experiments, the polymerizations are conducted using ultraviolet light initiation, thus yielding materials with molecularly imprinted binding sites tailored for trans-resveratrol. These materials are successfully applied in purifying trans-resveratrol from winemaking residues,
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A Thermodynamic Simulation Package for Catalytic Polyolefin Reactors: Development and Applications Macromol. React. Eng. (IF 1.5) Pub Date : 2023-08-18 Arash Alizadeh, Vasileios Touloupidis, João B. P. Soares
Front Cover: In article number 2200057, Arash Alizadeh, Vasileios Touloupidis, and João B. P. Soares have developed a thermodynamic simulation package for the catalytic polymerization of olefins in autoclave slurry, loop slurry, gas-phase, and autoclave solution reactors. The simulator uses the Sanchez–Lacombe theory as one of the major thermodynamic models in the polymer industry. Simulations under
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Celebrating the 60th birthday of José Carlos Pinto Macromol. React. Eng. (IF 1.5) Pub Date : 2023-08-18 Martina C. C. Pinto, Márcio Nele
This Macromolecular Reaction Engineering special issue is dedicated to Celebrate the 60th birthday of José Carlos Pinto, or Zé, as he likes to be called by his friends and colleagues. We were honored and delighted to organize this special issue of Macromolecular Reaction Engineering with Dr. Spiegel to celebrate the importance of Zé’s contribution to developing polymer technology throughout his 35
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Synthesis and Analysis of Well-Defined Copolymers via by Combination ROP Technique Macromol. React. Eng. (IF 1.5) Pub Date : 2023-08-07 Umit Yildiko, Aslihan Aycan Tanriverdi, Ahmet Cagri Ata, Ismail Cakmak, Ahmet Turan Tekes
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Branched Comonomers in LLDPE—Influence of Short Chain Branch Shape on Crystallinity Macromol. React. Eng. (IF 1.5) Pub Date : 2023-07-04 Lukas Göpperl, Roberta Cipullo, Clemens Schwarzinger, Christian Paulik
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Temperature-Optimized Synthesis of SiO2-Reinforced N-(Alkyl)Acrylamide-Based Semi-IPN Hybrid Gels Functionalized with Methacrylic Acid Units Macromol. React. Eng. (IF 1.5) Pub Date : 2023-06-16 Birgül Kalkan, Merve Mocan, Nermin Orakdogen
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Effects of Internal Electron Donor on Distribution and Reactivity of Active Centers in Ethylene/1-Hexene Copolymerization with MgCl2-Supported Ziegler-Natta Catalyst Macromol. React. Eng. (IF 1.5) Pub Date : 2023-06-14 Tao Xu, Zhisheng Fu, Zhiqiang Fan
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Toward Reactive Processing of Polyamide 6 Based Blends with Polyethylene Grafted with Maleic Anhydride and Acrylic Acid: Effect of Functionalization Degree Macromol. React. Eng. (IF 1.5) Pub Date : 2023-06-13 Carlos Bruno Barreto Luna, Eduardo da Silva Barbosa Ferreira, Anna Raffaela de Matos Costa, Yeda Medeiros Bastos de Almeida, João Baptista da Costa Agra de Melo, Edcleide Maria Araújo
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Flow Activation Energy Estimation by Thermo-Rheological Method Macromol. React. Eng. (IF 1.5) Pub Date : 2023-05-25 Qiao Lin, Nadine Allanic, Manuel Girault, Pierre Mousseau
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An Adaptive Soft Sensor for On-Line Monitoring the Mass Conversion in the Emulsion Copolymerization of the Continuous SBR Process Macromol. React. Eng. (IF 1.5) Pub Date : 2023-05-24 Carlos I. Sanseverinatti, Mariano M. Perdomo, Luis A. Clementi, Jorge R. Vega
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Synthesis of Vinyl Acetate Monomer Over PdCu Alloys: The Role of Surface Oxygenation in the Reaction Path Macromol. React. Eng. (IF 1.5) Pub Date : 2023-05-19 Alberth Renne Gonzalez Caranton, Martin Schmal, Noemi Raquel Checca Huaman, José Carlos da Silva Pinto
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Generalization and Evaluation of the Analytical Solution of Intraparticle Diffusion Models in Finite Batch Adsorption Macromol. React. Eng. (IF 1.5) Pub Date : 2023-05-18 Gabriel Miglioranza, Marcio Schwaab
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Copolymerization of ω-Alkenyltrimethylsilane with Ethylene by MgCl2/TiCl4 Catalyst: Effect of Alkenyl Length on Comonomer Incorporation Macromol. React. Eng. (IF 1.5) Pub Date : 2023-05-05 Fengtao Chen, Yawei Qin, Jin-Yong Dong
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Exploiting the Use of Salvia Hispanica L. (chia) Oil as a Renewable Raw Material to Produce Air-Drying Alkyd Resins: A Comparative Study Macromol. React. Eng. (IF 1.5) Pub Date : 2023-04-27 Anthony F. Glenn, Gabriel F. S. Brito, Graciane Resende, Lumena L. Jaques, Raíssa G. M. R. Barroso, Thainá Araruna, Fabricio Machado
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Transient Open-Closed Loop Experimental Validation of a Nonlinear Two-Phase Flow Distributed System Macromol. React. Eng. (IF 1.5) Pub Date : 2023-04-25 Márcia Peixoto Vega, Mateus Azevedo Dalbone de Carvalho, Gabrielle Fontella de Moraes Oliveira, Lindoval Domiciano Fernandes
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New Insights on the Kinetics of Persulfate-Initiated Itaconic Acid Free-Radical Polymerization Macromol. React. Eng. (IF 1.5) Pub Date : 2023-04-24 Jorge Herrera-Ordonez
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Mechanical Properties and Blocking Resistance of Films Cast from Core–Shell Latex Particles Macromol. React. Eng. (IF 1.5) Pub Date : 2023-04-15 Adrián Perez, Emily Kynaston, Christopher Lindsay, Nicholas Ballard
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Use of Chicken Litter for In Situ Polymerization of Poly(Butylene Succinate) (PBS) Based Polymer Composites Macromol. React. Eng. (IF 1.5) Pub Date : 2023-04-15 Carla Oliveira Nascimento, Vinícius De Melo Benites, Elaine Christine de Magalhães Cabral-Albuquerque, José Carlos Pinto, Rosana Lopes Fialho
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Polyethylene Slurries: Swelling and Solubility Macromol. React. Eng. (IF 1.5) Pub Date : 2023-04-05 Amel Ben Mrad, Nida Sheibat-Othman, Ana Paula Alves Amorim, Roberta Lopes do Rosario, Timothy F. L. McKenna
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Modeling the Formation of Rigid Polyurethane Foams Using Hydrofluorolefin as Expanding Agent Macromol. React. Eng. (IF 1.5) Pub Date : 2023-04-04 Beatriz N. Cassens, Reinaldo Giudici
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Alkylaluminum/Urea Hybrid Cocatalysts and Their Use in Iron-Catalyzed Oligomerization of Ethylene Macromol. React. Eng. (IF 1.5) Pub Date : 2023-03-28 Ying Zhang, Jian Ye, Yinzhi Jiang, Shuqin Jiang, Wei Xiao, Dongchu Wei
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Temperature-Optimized Synthesis of SiO2-Reinforced N-(Alkyl)Acrylamide-Based Semi-IPN Hybrid Gels Functionalized with Methacrylic Acid Units Macromol. React. Eng. (IF 1.5) Pub Date : 2023-03-23 Birgül Kalkan, Merve Mocan, Nermin Orakdogen
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Encapsulated Colorimetric Indicators used as Additives During the Polymerization of Smart Polyethylene Macromol. React. Eng. (IF 1.5) Pub Date : 2023-03-22 Cesar A. Heck, João Henrique Z. dos Santos
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Synthesis of Waterborne Anticorrosive Coatings Based on The Incorporation of Phosphate Groups to Polyurethane-Acrylate Hybrids Macromol. React. Eng. (IF 1.5) Pub Date : 2023-03-16 Aitor Barquero, Oihane Llorente, Daniela Minudri, María Paulis, Jose Ramon Leiza
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Monitoring of Emulsion Polymerization in the Presence of Ionic Liquids Using NIR Spectroscopy Macromol. React. Eng. (IF 1.5) Pub Date : 2023-03-14 Leila Medeiros Santos, Claudio Dariva, Caroline Martins Masso, Montserrat Fortuny, Alexandre Ferreira Santos
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Surface Molecularly Imprinted Cellulose-Synthetic Hybrid Particles Prepared via ATRP for Enrichment of Flavonoids in Olive Leaf Macromol. React. Eng. (IF 1.5) Pub Date : 2023-03-13 Catarina P. Gomes, Rolando C. S. Dias, Mário Rui P. F. N. Costa
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Low Salinity Water–Polymer Flooding in Carbonate Oil Reservoirs: A Critical Review Macromol. React. Eng. (IF 1.5) Pub Date : 2023-03-11 Fabio Pedro Nascimento, Verônica de Jesus Pereira, Ladislane dos Santos Bastos, Gloria Meyberg Nunes Costa, Silvio Alexandre Beisl Vieira de Melo
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Multivariable Rheological Models for Commercial Polypropylene with High Molar Masses Macromol. React. Eng. (IF 1.5) Pub Date : 2023-03-11 Carlos A. Castor, André I. O. de A. Fialho, Bruno F. Oechsler, José C. Pinto
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Copolymerization of ω-Alkenyltrimethylsilane/Propylene with Heterogeneous Ziegler-Natta Catalyst: How Dose Alkenyl Length Affect Comonomer Incorporation? Macromol. React. Eng. (IF 1.5) Pub Date : 2023-02-26 Fengtao Chen, Zhijian Zhang, Yawei Qin, Jin-Yong Dong
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Evaluation of Hyperthermic Potential and Acute Toxicity of PLGA-PEG/Magnetite Microspheres Loaded with Oxaliplatin Using Mice as a Test System Macromol. React. Eng. (IF 1.5) Pub Date : 2023-02-25 Emiliane Daher Pereira, Fernando Gomes de Souza Junior, José Carlos Pinto, Sergio Thode Filho, Kaushik Pal, Alexandre dos Santos Pyrrho, Renata Cerruti da Costa, Bruno Pereira da Cunha, Fabíola da Silveira Maranhão, Thuanny Moraes de Almeida
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Polymerization of N-Butyl Vinyl Ether Catalyzed by Iron-Containing Imidazolium-Based Ionic Liquid Macromol. React. Eng. (IF 1.5) Pub Date : 2023-02-24 Tamara Agner, Amadeo Zimermann, Fabricio Machado, Brenno A. D. Neto, Pedro H. H. de Araújo, Claudia Sayer
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Modeling of the Copolymerization of Propylene with 1-Hexene to Predict the Copolymer Molecular Weight and Composition Macromol. React. Eng. (IF 1.5) Pub Date : 2023-02-20 Franco Herrero, Adriana Brandolin, Claudia Sarmoria, Mariano Asteasuain
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Optimization of Grade Transitions in Bulk Poly(propylene) Polymerizations Macromol. React. Eng. (IF 1.5) Pub Date : 2023-02-10 Jonildo S. Silva, Príamo A. Melo, José Carlos Pinto
In the present paper, a dynamic optimization problem regarding grade transitions in bulk poly(propylene) polymerization processes is formulated and solved for the first time. Initially, a detailed dynamic process model is presented and implemented, comprising mass and energy balances, some of the polymer properties (such as the melting flow index and the xylene solubles) and regulatory control loops
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Validation of an Extended Kinetic Model of Free-Radical N-Vinylpyrrolidone Polymerization Macromol. React. Eng. (IF 1.5) Pub Date : 2023-01-29 Stefan Welzel, Jule Burmeister, Oliver Höppchen, Ulrich Nieken
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Influence of Synthesis Parameters on the Magnetic, Thermal, and Morphological Properties of Poly(Glycidyl Methacrylate-co-Divinylbenzene)/Magnetite Macromol. React. Eng. (IF 1.5) Pub Date : 2023-01-28 Carla Nascimento Queiroz, Henrique Almeida Cunha, Manoel Ribeiro da Silva, Márcia Gomes de Oliveira, Jacira Aparecida Castanharo, Ivana Lourenço de Mello Ferreira, Marcos Antonio da Silva Costa
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Influence of Benzoyl Peroxide and Divinylbenzene Concentrations on the Properties of Poly(glycidyl methacrylate-co-divinylbenzene) Magnetic Microspheres Macromol. React. Eng. (IF 1.5) Pub Date : 2023-01-20 Washington José Fernandes Formiga, Manoel Ribeiro da Silva, Henrique Almeida Cunha, Jacira Aparecida Castanharo, Ivana Lourenço de Mello de Ferreira, Marcos Antonio da Silva Costa
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Modeling and Parameter Estimation for Gas-Phase Polyethylene Product Properties Using Dynamic and Steady-State Data Macromol. React. Eng. (IF 1.5) Pub Date : 2023-01-15 Lauren A. Gibson, Yan Jiang, Timothy Boller, Hsu Chiang, Kimberley B. McAuley
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Functionalization of Polymer Networks to Target Trans-Resveratrol in Winemaking Residues Supported by Statistical Design of Experiments Macromol. React. Eng. (IF 1.5) Pub Date : 2023-01-07 Amir Bzainia, Rolando C. S. Dias, Mário Rui P. F. N. Costa
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Current Status and Perspectives on the Green Synthesis of Succinic Polyesters for Value-Added Applications Macromol. React. Eng. (IF 1.5) Pub Date : 2022-12-31 Fernando Elias Gucker, Claudia Sayer, Débora de Oliveira, Pedro H. Hermes de Araújo, Bruno Francisco Oechsler
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Virtual Analyzers for MI and Density Based on Neural Networks Improved through an Integrated Strategy Involving a Constructive Algorithm and Definition of Initial Weights Macromol. React. Eng. (IF 1.5) Pub Date : 2022-12-24 Adilton Lopes da Silva, Cristiano Hora Fontes, Marcelo Embiruçu
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Commemorating Timothy McKenna's 60th Birthday Macromol. React. Eng. (IF 1.5) Pub Date : 2022-12-16 João B. P. Soares
I am pleased to celebrate the 60th birthday of our colleague and friend, Tim McKenna, in this special issue of Macromolecular Reaction Engineering (MRE). I am also thrilled that I am not the only one to reach this milestone, even though I preceded him by a couple of years. Welcome to the club, old man. The number and scope of articles submitted to this special MRE issue reflect Tim's many accomplishments