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Machine Learning Aided Design and Optimization of Thermal Metamaterials Chem. Rev. (IF 62.1) Pub Date : 2024-03-28 Changliang Zhu, Emmanuel Anuoluwa Bamidele, Xiangying Shen, Guimei Zhu, Baowen Li
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Visible-Light TiO2-Catalyzed Synthesis of Dihydrobenzofurans by Oxidative [3+2] Annulation of Phenols with Alkenyl Phenols Chem. Sci. (IF 8.4) Pub Date : 2024-03-28 Jingze Wu, Yaning Liu, Marisa C Kozlowski
An oxidative strategy for the preparation of dihydrobenzofurans via heterogeneous photocatalysis is reported. This method leverages the surface interaction between the alkenyl phenol and the TiO2 solid surface, which enables direct activation by visible light without the need for pre-functionalization or surface modification. The resulting alkenyl phenoxyl radical is proposed to be selectively captured
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Hypocretenolide: Collective Total Syntheses and Its Activities toward Metastatic Colon Cancer Chem. Sci. (IF 8.4) Pub Date : 2024-03-28 Bolin Chen, Xijing Zhang, Yufen Yang, Dongdong Xu, Qianwei Wu, Shibo Wang, Shiqi Bao, Xuemei Zhang, Yahui Ding, Liang Wang, Yue Chen
A concise and collective synthetic route to hypocretenolides was developed for the first time. This route features the one-pot addition-alkylation and intramolecular 1,3-dipolar cycloaddition to efficiently assemble the 5/7/6 ring system. Our syntheses enabled multigram preparation of hypocretenolide which facilitated further biological evaluation. Preliminary MTT cytotoxic results of hypocretenolide
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Copper(I)-free Syntheses of [11C/18F]Trifluoromethyl Ketones from Alkyl- or Aryl Esters and [11C/18F]Fluoroform Chem. Commun. (IF 4.9) Pub Date : 2024-03-28 Susovan Jana, Sanjay Telu, Jimmy E Jakobsson, Bo Yeun Yang, Victor W Pike
Herein, we report a copper(I)-free method for labeling the trifluoroacetyl group with positron-emitting carbon-11 (t1/2 = 20.4 min) or fluorine-18 (t1/2= 109.8 min) as part of our exploration of radiolabeled fluoroforms to access new radiolabeled chemotypes of interest for tracer development. Treatment of alkyl esters and aryl esters, containing electron-donating or electron-withdrawing groups, with
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Superoxide Dismutase Nanozymes: Current Status and Future Perspectives in Brain Disease Treatment and Detection Chem. Commun. (IF 4.9) Pub Date : 2024-03-28 Ying Chen, Bo Li, Kai Li, Yuqing Lin
Abstract: Superoxide dismutase (SOD) is a important metalloenzyme that catalyze the dismutation of superoxide radicals (O2.-) into hydrogen peroxide (H2O2) and oxygen (O2). However, the clinical application of SOD is severely limited due to its structural instability and high cost. Compared with natural enzymes, nanomaterials with enzyme-like activity, nanoenzymes, are more stable, economical, easy
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Mono-Component Pure-White Light-Emitting Diodes Based on Eco-Friendly ZnCuGaS:In@ZnS Quantum Dots with Near-Unity Quantum Yield and Balanced Red-Green-Blue Centers Adv. Mater. (IF 29.4) Pub Date : 2024-03-28 Jiangyuan Jiang, Shuai Zhang, Qingsong Shan, Linxiang Yang, Jing Ren, Yongjin Wang, Seokwoo Jeon, Hengyang Xiang, Haibo Zeng
White light-emitting diodes (WLEDs) are the key component in next-generation lighting and display devices. The inherent toxicity of Cd/Pb-based quantum dots (QDs) limits the further application in WLEDs. Recently, more attention has been focused on eco-friendly QDs and their WLEDs, especially the phosphor-free WLEDs based on mono-component, which profits from bias-insensitive color stability. However
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In Situ Nanofiber Formation Blocks AXL and GAS6 Binding to Suppress Ovarian Cancer Development Adv. Mater. (IF 29.4) Pub Date : 2024-03-28 Han Yin, Yue Hua, Songwei Feng, Yi Xu, Yue Ding, Sicong Liu, Dongsheng Chen, Furong Du, Gaolin Liang, Wenjun Zhan, Yang Shen
Anexelekto (AXL) is an attractive molecular target for ovarian cancer therapy because of its important role in ovarian cancer initiation and progression. To date, several AXL inhibitors have entered clinical trials for the treatment of ovarian cancer. However, the disadvantages of low AXL affinity and severe off-target toxicity of these inhibitors limit their further clinical applications. Herein,
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Photostrictive Actuators Based on Freestanding Ferroelectric Membranes Adv. Mater. (IF 29.4) Pub Date : 2024-03-28 Saptam Ganguly, David Pesquera, Daniel Moreno Garcia, Umair Saeed, Nona Mirzamohammadi, José Santiso, Jessica Padilla, José Manuel Caicedo Roque, Claire Laulhé, Felisa Berenguer, Luis Guillermo Villanueva, Gustau Catalan
Complex oxides offer a wide range of functional properties, and recent advances in fabrication of freestanding membranes of these oxides are adding new mechanical degrees of freedom to this already rich functional ecosystem. Here, we demonstrate photoactuation in freestanding thin film resonators of ferroelectric Barium Titanate (BaTiO3) and paraelectric Strontium Titanate (SrTiO3). The free-standing
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Emerging Trends of Nanofibrous Piezoelectric and Triboelectric Applications: Mechanisms, Electroactive Materials, and Designed Architectures Adv. Mater. (IF 29.4) Pub Date : 2024-03-28 Chuanwei Zhi, Shuo Shi, Hanbai Wu, Yifan Si, Shuai Zhang, Leqi Lei, Jinlian Hu
Over the past few decades, significant progress in piezo-/tribo-electric nanogenerators (PTEGs) has led to the development of cutting-edge wearable technologies. Nanofibers with good designability, controllable morphologies, large specific areas, and unique physicochemical properties provide a promising platform for PTEGs for various advanced applications. However, the further development of nanofiber-based
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Area Selective Chemical Vapor Deposition of Gold by Electron Beam Seeding Adv. Mater. (IF 29.4) Pub Date : 2024-03-28 Aleksei Tsarapkin, Krzysztof Maćkosz, Chinmai Sai Jureddy, Ivo Utke, Katja Höflich
Chemical vapor deposition (CVD) is an established method for producing high-purity thin films, but it typically necessitates the pre- and post-processing using a mask to produce structures. This paper presents a novel maskless patterning technique that enables area selective CVD of gold. A focused electron beam is used to decompose the metal-organic precursor Au(acac)Me2 locally, thereby creating an
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High Open-Circuit Voltage Organic Solar Cells with 19.2% Efficiency Enabled by Synergistic Side-Chain Engineering Adv. Mater. (IF 29.4) Pub Date : 2024-03-27 Renjie Xu, Yuanyuan Jiang, Feng Liu, Guangliu Ran, Kerui Liu, Wenkai Zhang, Xiaozhang Zhu
Restricted by the energy-gap law, state-of-the-art organic solar cells (OSCs) exhibit relatively low open-circuit voltage (VOC; 0.8–0.9 V) because of large nonradiative energy losses. Moreover, the trade-off between VOC and external quantum efficiency (EQE) of OSCs is more distinctive; the power conversion efficiencies (PCEs) of OSCs are still < 15% with VOCs of > 1.0 V. Herein, we carefully consider
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Enhanced piezoelectricity of MAPbI3 by the introduction of MXene and its utilization in boosting high-performance photodetectors Adv. Mater. (IF 29.4) Pub Date : 2024-03-27 Gaosi Han, Xiao-Fen Li, Andy Berbille, Yueming Zhang, Xiongxin Luo, Lindong Liu, Longyi Li, Zhong Lin Wang, Laipan Zhu
Recently, perovskite photodetectors (PDs) have been risen to prominence due to substantial research interest. Beyond merely tweaking the composition of materials, a cutting-edge advancement lies in leveraging the innate piezoelectric polarization properties of perovskites themselves. Here, the investigation shows utilizing Ti3C2Tx, a typical MXene, as an intermediate layer for significantly boosting
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Interface-Targeting Carrier-Catalytic Integrated Design Contributing to Lithium Dihalide-Rich SEI toward High Interface Stability for Long-Life Solid-State Lithium-Metal Batteries Angew. Chem. Int. Ed. (IF 16.6) Pub Date : 2024-03-28 Xuan yi Zhou, Fen fen Huang, Xue dong Zhang, Biao Zhang, Ying jie Cui, Ze hua Wang, Qiong Yang, Zeng sheng Ma, Jun Liu
The generation of solid electrolyte interphase (SEI) largely determines the comprehensive performance of all-solid-state batteries. Herein, a novel “carrier-catalytic” integrated design is strategically exploited to in situ construct a stable LiF-LiBr rich SEI by improving the electron transfer kinetics to accelerate the bond-breaking dynamics. Specifically, the high electron transport capacity of
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Anti-Selective Carbosilylation: Nickel-Catalyzed Multicomponent Reaction of Solid Me3SiZnI Angew. Chem. Int. Ed. (IF 16.6) Pub Date : 2024-03-28 Revathi Chandrasekaran, Keerthika Selvam, Thayalan Rajeshkumar, Tamilselvi Chinnusamy, Laurent Maron, Ramesh Rasappan
The stereodefined and highly substituted vinylsilanes are essential building blocks for constructing complex organic molecules. Transition metal-mediated silylmetalation of alkynes was developed to overcome the limitations of conventional hydrosilylations; however, a very limited study was carried out to utilize transient vinylmetal species in cross-coupling reactions. Moreover, they produce syn-adduct
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Secondary Amine Catalysis in Enzyme Design: Broadening Protein Template Diversity through Genetic Code Expansion Angew. Chem. Int. Ed. (IF 16.6) Pub Date : 2024-03-28 Thomas L Williams, Irshad M Taily, Lewis Hatton, Andrey A Berezin, Yi-Lin Wu, Vicent Moliner, Katarzyna Świderek, Yu-Hsuan Tsai, Louis Y P Luk
Secondary amines, due to their reactivity, can transform protein templates into catalytically active entities, accelerating the development of artificial enzymes. However, existing methods, predominantly reliant on modified ligands or N-terminal prolines, impose significant limitations on template selection. Here, genetic code expansion was used to break this boundary, enabling secondary amines to
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Photocatalytic CO2 Reduction Using an Osmium Complex as a Panchromatic Self-Photosensitized Catalyst: Utilization of Blue, Green, and Red Light Angew. Chem. Int. Ed. (IF 16.6) Pub Date : 2024-03-28 Kenji Kamada, Jieun Jung, Chihiro Yamada, Taku Wakabayashi, Keita Sekizawa, Shunsuke Sato, Takeshi Morikawa, Shunichi Fukuzumi, Susumu Saito
The photocatalytic reduction of carbon dioxide (CO2) represents an attractive approach for solar-energy storage and leads to the production of renewable fuels and valuable chemicals. Although some osmium (Os) photosensitizers absorb long wave-lengths in the visible-light region, a self-photosensitized, mono-nuclear Os catalyst for red-light-driven CO2 reduction has not yet been exploited. Here, we
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Mercury-Group 13 Metal Covalent Bonds: A Systematic Comparison of Aluminyl, Gallyl and Indyl Metallo-ligands Angew. Chem. Int. Ed. (IF 16.6) Pub Date : 2024-03-28 Liam Griffin, Mathias Ellwanger, Agamemnon Crumpton, Matthew Roy, Andreas Heilmann, Simon Aldridge
Bimetallic compounds containing direct metal-group 13 element bonds have been shown to display unprecedented patterns of cooperative reactivity towards small molecules, which can be influenced by the identity of the group 13 element. In this context, we present here a systematic appraisal of group 13 metallo-ligands of the type [(NON)E]- (NON = 4,5-bis(2,6-diisopropylanilido)-2,7-di-tert-butyl-9,9-dimethylxanthene)
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Hydrogels with Differentiated Hydrogen-Bonding Networks for Bioinspired Stress Response Angew. Chem. Int. Ed. (IF 16.6) Pub Date : 2024-03-28 Wei Zhao, Zhouyue Lei, Baohu Wu, peiyi Wu
Stress response, an intricate and autonomously coordinated reaction in living organisms, holds a reversible, multi-path, and multi-state nature. However, existing stimuli-responsive materials often exhibit single-step and monotonous reactions due to the limited integration of structural components. Inspired by the cooperative interplay of extensor and flexor cells within Mimosa's pulvini, we present
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Regio- and Stereo-Selective Isomerization of Borylated 1,3-Dienes Enabled by Selective Energy Transfer Catalysis Angew. Chem. Int. Ed. (IF 16.6) Pub Date : 2024-03-28 Byeongseok Kweon, Lukas Blank, Julia Soika, Amélia Messara, Constantin Daniliuc, Ryan Gilmour
Configurationally-defined dienes are pervasive across the bioactive natural product spectrum, where they typically manifest themselves as sorbic acid-based fragments. These C5 motifs reflect the biosynthesis algorithms that facilitate their construction. To complement established biosynthetic paradigms, a chemical platform to facilitate the construction of stereochemically defined, functionalizable
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Intermolecular Hydrogen Bonding Networks Stabilized Organic Supramolecular Cathode for Ultra-High Capacity and Ultra-Long Cycle Life Rechargeable Aluminum Batteries Angew. Chem. Int. Ed. (IF 16.6) Pub Date : 2024-03-28 Zhaohui Yang, Pengyu Meng, Min Jiang, Xinlong Zhang, Jiao Zhang, Chaopeng Fu
Rechargeable aluminum batteries (RABs) are a promising candidate for large-scale energy storage, attributing to the abundant reserves, low cost, intrinsic safety, and high theoretical capacity of Al. However, the cathode materials reported thus far still face challenges such as limited capacity, sluggish kinetics, and undesirable cycle life. Herein, we propose an organic cathode benzo[i] benzo[6,7]
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Magneto-chiral Nonlinear Optical Effect with Large Anisotropic Response in Two-Dimensional Halide Perovskite Angew. Chem. Int. Ed. (IF 16.6) Pub Date : 2024-03-27 DAICHI OKADA, Fumito Araoka
The chiral organic-inorganic halide perovskites (OIHPs) are vital candidates for superior nonlinear optical (NLO) effects associated with circularly polarized (CP) light. NLO in chiral materials often couples with magnetic dipole (MD) transition, as well as the conventional electric dipole (ED) transition. However, the importance of MD transition in NLO process of chiral OIHPs has not yet been well
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Achieving Strong Circularly Polarized Luminescence through Cascade Cationic Insertion in Lead-free Hybrid Metal Halides Angew. Chem. Int. Ed. (IF 16.6) Pub Date : 2024-03-27 Tao Song, Cheng-Qiang Wang, Haolin Lu, Xi-Jiao Mu, Bo-Long Wang, Ji-zhong Liu, Bo Ma, Jing Cao, Chuan-Xiang Sheng, Guankui Long, Qiang Wang, Hao-Li Zhang
Generating circularly polarized luminescence (CPL) with simultaneous high photoluminescence quantum yield (PLQY) and dissymmetry factor (glum) is difficult due to usually unmatched electric transition dipole moment (µ) and magnetic transition dipole moment (m) of materials. Herein we tackle this issue by playing a “cascade cationic insertion” trick to achieve strong CPL (with PLQY of ~ 100%) in lead-free
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How a spreadsheet helped me to land my dream job Nature (IF 64.8) Pub Date : 2024-03-28
A shared spreadsheet, passed from generation to generation, helps graduate students in management navigate the academic job market. Whatever your field of study, you can make one, too.
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Video: Cancer-busting vaccines Nature (IF 64.8) Pub Date : 2024-03-27
Treatments that could train the immune system to identify and destroy cancer cells are on the way.
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No sweat: Moisture-wicking device keeps wearable-tech dry Nature (IF 64.8) Pub Date : 2024-03-27
Breathable patch could allow for comfortable and multifunctional wearable electronics.
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CGRP sensory neurons promote tissue healing via neutrophils and macrophages Nature (IF 64.8) Pub Date : 2024-03-27 Yen-Zhen Lu, Bhavana Nayer, Shailendra Kumar Singh, Yasmin K. Alshoubaki, Elle Yuan, Anthony J. Park, Kenta Maruyama, Shizuo Akira, Mikaël M. Martino
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Formation of memory assemblies through the DNA-sensing TLR9 pathway Nature (IF 64.8) Pub Date : 2024-03-27 Vladimir Jovasevic, Elizabeth M. Wood, Ana Cicvaric, Hui Zhang, Zorica Petrovic, Anna Carboncino, Kendra K. Parker, Thomas E. Bassett, Maria Moltesen, Naoki Yamawaki, Hande Login, Joanna Kalucka, Farahnaz Sananbenesi, Xusheng Zhang, Andre Fischer, Jelena Radulovic
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Five million years of Antarctic Circumpolar Current strength variability Nature (IF 64.8) Pub Date : 2024-03-27 Frank Lamy, Gisela Winckler, Helge W. Arz, Jesse R. Farmer, Julia Gottschalk, Lester Lembke-Jene, Jennifer L. Middleton, Michèlle van der Does, Ralf Tiedemann, Carlos Alvarez Zarikian, Chandranath Basak, Anieke Brombacher, Levin Dumm, Oliver M. Esper, Lisa C. Herbert, Shinya Iwasaki, Gaston Kreps, Vera J. Lawson, Li Lo, Elisa Malinverno, Alfredo Martinez-Garcia, Elisabeth Michel, Simone Moretti, Christopher
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Optomechanical realization of the bosonic Kitaev chain Nature (IF 64.8) Pub Date : 2024-03-27 Jesse J. Slim, Clara C. Wanjura, Matteo Brunelli, Javier del Pino, Andreas Nunnenkamp, Ewold Verhagen
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TRBC1-targeting antibody–drug conjugates for the treatment of T cell cancers Nature (IF 64.8) Pub Date : 2024-03-27 Tushar D. Nichakawade, Jiaxin Ge, Brian J. Mog, Bum Seok Lee, Alexander H. Pearlman, Michael S. Hwang, Sarah R. DiNapoli, Nicolas Wyhs, Nikita Marcou, Stephanie Glavaris, Maximilian F. Konig, Sandra B. Gabelli, Evangeline Watson, Cole Sterling, Nina Wagner-Johnston, Sima Rozati, Lode Swinnen, Ephraim Fuchs, Drew M. Pardoll, Kathy Gabrielson, Nickolas Papadopoulos, Chetan Bettegowda, Kenneth W. Kinzler
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Depleting myeloid-biased haematopoietic stem cells rejuvenates aged immunity Nature (IF 64.8) Pub Date : 2024-03-27 Jason B. Ross, Lara M. Myers, Joseph J. Noh, Madison M. Collins, Aaron B. Carmody, Ronald J. Messer, Erica Dhuey, Kim J. Hasenkrug, Irving L. Weissman
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Structural basis of exoribonuclease-mediated mRNA transcription termination Nature (IF 64.8) Pub Date : 2024-03-27 Yuan Zeng, Hong-Wei Zhang, Xiao-Xian Wu, Yu Zhang
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High-fidelity spin qubit operation and algorithmic initialization above 1 K Nature (IF 64.8) Pub Date : 2024-03-27 Jonathan Y. Huang, Rocky Y. Su, Wee Han Lim, MengKe Feng, Barnaby van Straaten, Brandon Severin, Will Gilbert, Nard Dumoulin Stuyck, Tuomo Tanttu, Santiago Serrano, Jesus D. Cifuentes, Ingvild Hansen, Amanda E. Seedhouse, Ensar Vahapoglu, Ross C. C. Leon, Nikolay V. Abrosimov, Hans-Joachim Pohl, Michael L. W. Thewalt, Fay E. Hudson, Christopher C. Escott, Natalia Ares, Stephen D. Bartlett, Andrea Morello
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Controlling the helicity of light by electrical magnetization switching Nature (IF 64.8) Pub Date : 2024-03-27 Pambiang Abel Dainone, Nicholas Figueiredo Prestes, Pierre Renucci, Alexandre Bouché, Martina Morassi, Xavier Devaux, Markus Lindemann, Jean-Marie George, Henri Jaffrès, Aristide Lemaitre, Bo Xu, Mathieu Stoffel, Tongxin Chen, Laurent Lombez, Delphine Lagarde, Guangwei Cong, Tianyi Ma, Philippe Pigeat, Michel Vergnat, Hervé Rinnert, Xavier Marie, Xiufeng Han, Stephane Mangin, Juan-Carlos Rojas-Sánchez
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Graphene nanoribbons grown in hBN stacks for high-performance electronics Nature (IF 64.8) Pub Date : 2024-03-27 Bosai Lyu, Jiajun Chen, Sen Wang, Shuo Lou, Peiyue Shen, Jingxu Xie, Lu Qiu, Izaac Mitchell, Can Li, Cheng Hu, Xianliang Zhou, Kenji Watanabe, Takashi Taniguchi, Xiaoqun Wang, Jinfeng Jia, Qi Liang, Guorui Chen, Tingxin Li, Shiyong Wang, Wengen Ouyang, Oded Hod, Feng Ding, Michael Urbakh, Zhiwen Shi
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A figure of merit for efficiency roll-off in TADF-based organic LEDs Nature (IF 64.8) Pub Date : 2024-03-27 S. Diesing, L. Zhang, E. Zysman-Colman, I. D. W. Samuel
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The complex polyploid genome architecture of sugarcane Nature (IF 64.8) Pub Date : 2024-03-27 A. L. Healey, O. Garsmeur, J. T. Lovell, S. Shengquiang, A. Sreedasyam, J. Jenkins, C. B. Plott, N. Piperidis, N. Pompidor, V. Llaca, C. J. Metcalfe, J. Doležel, P. Cápal, J. W. Carlson, J. Y. Hoarau, C. Hervouet, C. Zini, A. Dievart, A. Lipzen, M. Williams, L. B. Boston, J. Webber, K. Keymanesh, S. Tejomurthula, S. Rajasekar, R. Suchecki, A. Furtado, G. May, P. Parakkal, B. A. Simmons, K. Barry, R
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Targeting DCAF5 suppresses SMARCB1-mutant cancer by stabilizing SWI/SNF Nature (IF 64.8) Pub Date : 2024-03-27 Sandi Radko-Juettner, Hong Yue, Jacquelyn A. Myers, Raymond D. Carter, Alexis N. Robertson, Priya Mittal, Zhexin Zhu, Baranda S. Hansen, Katherine A. Donovan, Moritz Hunkeler, Wojciech Rosikiewicz, Zhiping Wu, Meghan G. McReynolds, Shourya S. Roy Burman, Anna M. Schmoker, Nada Mageed, Scott A. Brown, Robert J. Mobley, Janet F. Partridge, Elizabeth A. Stewart, Shondra M. Pruett-Miller, Behnam Nabet
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Climate velocities and species tracking in global mountain regions Nature (IF 64.8) Pub Date : 2024-03-27 Wei-Ping Chan, Jonathan Lenoir, Guan-Shuo Mai, Hung-Chi Kuo, I-Ching Chen, Sheng-Feng Shen
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Revealing uncertainty in the status of biodiversity change Nature (IF 64.8) Pub Date : 2024-03-27 T. F. Johnson, A. P. Beckerman, D. Z. Childs, T. J. Webb, K. L. Evans, C. A. Griffiths, P. Capdevila, C. F. Clements, M. Besson, R. D. Gregory, G. H. Thomas, E. Delmas, R. P. Freckleton
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The complex circumstellar environment of supernova 2023ixf Nature (IF 64.8) Pub Date : 2024-03-27 E. A. Zimmerman, I. Irani, P. Chen, A. Gal-Yam, S. Schulze, D. A. Perley, J. Sollerman, A. V. Filippenko, T. Shenar, O. Yaron, S. Shahaf, R. J. Bruch, E. O. Ofek, A. De Cia, T. G. Brink, Y. Yang, S. S. Vasylyev, S. Ben Ami, M. Aubert, A. Badash, J. S. Bloom, P. J. Brown, K. De, G. Dimitriadis, C. Fransson, C. Fremling, K. Hinds, A. Horesh, J. P. Johansson, M. M. Kasliwal, S. R. Kulkarni, D. Kushnir
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Single-cell multiplex chromatin and RNA interactions in ageing human brain Nature (IF 64.8) Pub Date : 2024-03-27 Xingzhao Wen, Zhifei Luo, Wenxin Zhao, Riccardo Calandrelli, Tri C. Nguyen, Xueyi Wan, John Lalith Charles Richard, Sheng Zhong
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A three-dimensional liquid diode for soft, integrated permeable electronics Nature (IF 64.8) Pub Date : 2024-03-27 Binbin Zhang, Jiyu Li, Jingkun Zhou, Lung Chow, Guangyao Zhao, Ya Huang, Zhiqiang Ma, Qiang Zhang, Yawen Yang, Chun Ki Yiu, Jian Li, Fengjun Chun, Xingcan Huang, Yuyu Gao, Pengcheng Wu, Shengxin Jia, Hu Li, Dengfeng Li, Yiming Liu, Kuanming Yao, Rui Shi, Zhenlin Chen, Bee Luan Khoo, Weiqing Yang, Feng Wang, Zijian Zheng, Zuankai Wang, Xinge Yu
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Interchain-expanded extra-large-pore zeolites Nature (IF 64.8) Pub Date : 2024-03-27 Zihao Rei Gao, Huajian Yu, Fei-Jian Chen, Alvaro Mayoral, Zijian Niu, Ziwen Niu, Xintong Li, Hua Deng, Carlos Márquez-Álvarez, Hong He, Shutao Xu, Yida Zhou, Jun Xu, Hao Xu, Wei Fan, Salvador R. G. Balestra, Chao Ma, Jiazheng Hao, Jian Li, Peng Wu, Jihong Yu, Miguel A. Camblor
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Evidence for chiral graviton modes in fractional quantum Hall liquids Nature (IF 64.8) Pub Date : 2024-03-27 Jiehui Liang, Ziyu Liu, Zihao Yang, Yuelei Huang, Ursula Wurstbauer, Cory R. Dean, Ken W. West, Loren N. Pfeiffer, Lingjie Du, Aron Pinczuk
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High-threshold and low-overhead fault-tolerant quantum memory Nature (IF 64.8) Pub Date : 2024-03-27 Sergey Bravyi, Andrew W. Cross, Jay M. Gambetta, Dmitri Maslov, Patrick Rall, Theodore J. Yoder
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A brainstem–hypothalamus neuronal circuit reduces feeding upon heat exposure Nature (IF 64.8) Pub Date : 2024-03-27 Marco Benevento, Alán Alpár, Anna Gundacker, Leila Afjehi, Kira Balueva, Zsofia Hevesi, János Hanics, Sabah Rehman, Daniela D. Pollak, Gert Lubec, Peer Wulff, Vincent Prevot, Tamas L. Horvath, Tibor Harkany
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Thermonuclear explosions on neutron stars reveal the speed of their jets Nature (IF 64.8) Pub Date : 2024-03-27 Thomas D. Russell, Nathalie Degenaar, Jakob van den Eijnden, Thomas Maccarone, Alexandra J. Tetarenko, Celia Sánchez-Fernández, James C. A. Miller-Jones, Erik Kuulkers, Melania Del Santo
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Daily briefing: Tweeting about your paper doesn’t boost citations Nature (IF 64.8) Pub Date : 2024-03-27
Posting about a paper on X seems to boost engagement but not citations. Plus, researchers pinpoint humans’ first home outside Africa and what the science says about the Baltimore bridge collapse.
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The real time-travel paradox was the friends we made along the way Nature (IF 64.8) Pub Date : 2024-03-27
Life at the cutting edge.
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Climate change has slowed Earth’s rotation — and could affect how we keep time Nature (IF 64.8) Pub Date : 2024-03-27
The effect of melting polar ice could delay the need for a ‘leap second’ by three years.
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Divisive Sun-dimming study at Harvard cancelled: what’s next? Nature (IF 64.8) Pub Date : 2024-03-27
As the climate crisis rages on, advocacy for testing controversial solar geoengineering technology is ramping up.
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The surprising history of the Southern Ocean’s super current Nature (IF 64.8) Pub Date : 2024-03-27 Natalie J. Burls
Reconstructions of the strength of the Antarctic circumpolar current.
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Anti-ageing antibodies revive the immune system Nature (IF 64.8) Pub Date : 2024-03-27 Yasar Arfat T. Kasu, Robert A. J. Signer
Rejuvenating an aged immune system with antibody therapy.
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Maple-scented cacti and pom-pom cats: how pranking at work can lift lab spirits Nature (IF 64.8) Pub Date : 2024-03-27
Whether for April Fools’ Day or year-round, practical jokes allow scientists to tap into creative thinking while building group camaraderie.
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P-O functional group anchoring Pt-Co electrocatalyst for high-durability PEMFCs Energy Environ. Sci. (IF 32.5) Pub Date : 2024-03-28 Shengnan Hu, Weicheng Xu, Na Tian, Sumin Chen, Mengying Li, Junfei Shen, Jinxia Lin, Shuailong Guo, Xiaoyang Huang, Zhi-You Zhou, Shi-Gang Sun
Bimetallic Pt-M (M = transition metals) nanoparticles are promising for the development of proton exchange membrane fuel cells (PEMFCs), but their applications are limited by the inevitable nanoparticle aggregation due to Ostwald ripening process during the cathodic oxygen reduction reaction (ORR). Here, we report a novel strategy involving the incorporation of P-O functional groups into the pore channels
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Organohypervalent heterocycles Chem. Soc. Rev. (IF 46.2) Pub Date : 2024-03-28 Ravi Kumar, Toshifumi Dohi, Viktor V. Zhdankin
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Pillar[6]MaxQ functions as an in vivo sequestrant for rocuronium and vecuronium Chem. Commun. (IF 4.9) Pub Date : 2024-03-28 Wanping Zhang, Emmanuel A. Bazan-Bergamino, Anton P. Doan, Xiangjun Zhang, Lyle Isaacs
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Highly substituted benzo[b]furan synthesis through substituent migration Chem. Commun. (IF 4.9) Pub Date : 2024-03-28 Akihiro Kobayashi, Shinya Tabata, Suguru Yoshida
An unusual benzofuran synthesis from 2,6-disubstituted phenols and alkynyl sulfoxides is disclosed. Various highly substituted benzofurans were synthesized via the charge-accelerated [3,3]-sigmatropic rearrangement and subsequent substituent migration. Multiaryl-substituted benzofurans and fully substituted benzofurans were achieved on the basis of the unique reaction mechanism.