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Aggregation behavior of the Mixed Systems based on Imidazolium Surfactant Containing Carbamate Fragment and Polyacrylic Acid

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Abstract

Polymer-colloid complexes (PCC) based on imidazolium surfactant containing a carbamate fragment, and a hexadecyl chain (IAC-16) and polyacrylic acid (PAA) were formed and characterized. Mixed systems have been studied at the varied amphiphile concentration, while PAA additive was kept constant at 1, 3, and 5 mM. The aggregation properties, phase behavior, particle size of the IAC-16/PAA binary systems were estimated by tensiometry, conductometry, fluorescence spectroscopy, spectrophotometry, and dynamic light scattering (DLS). The PAA addition initiates the PCC formation at a concentration 20 times lower than for the individual IAC-16. DLS data showed that the hydrodynamic diameters of aggregates for the IAC-16/PAA binary systems are about 90–200 nm and do not depend on the PAA and surfactant concentration. It was found that electrostatic interactions are of key importance in the IAC-16/PAA systems.

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Notes

  1. For Figs. S1–S6 see supporting information.

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ACKNOWLEDGMENTS

This work was financially supported by Russian Science Foundation (project no. 19-73-30012).

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Authors and Affiliations

  1. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences, 420088, Kazan, Russia

    D. Kusnetsova, E. Vasilieva, D. Kuznetsov, E. Buzmakova & L. Zakharova

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  1. D. Kusnetsova
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  2. E. Vasilieva
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  3. D. Kuznetsov
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  4. E. Buzmakova
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  5. L. Zakharova
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Correspondence to D. Kusnetsova.

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Kusnetsova, D., Vasilieva, E., Kuznetsov, D. et al. Aggregation behavior of the Mixed Systems based on Imidazolium Surfactant Containing Carbamate Fragment and Polyacrylic Acid. rev. and adv. in chem. 12, 123–125 (2022). https://doi.org/10.1134/S2634827622020027

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  • DOI: https://doi.org/10.1134/S2634827622020027

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