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Licensed Unlicensed Requires Authentication Published by De Gruyter (O) November 21, 2022

Structural study of ceramic samples of the PbTiO3–BaTiO3–BaZrO3 system with a high PbTiO3 content studied by the Rietveld method

  • Vladimir Sirotinkin EMAIL logo , Alexandr Bush and Vladislav Kozlov

Abstract

The xBa(Ti(1−y)Zry)O3–(1−x)PbTiO3 ceramic samples with x = 0.3, y = 0.95; x = 0.3, y = 0.7; x = 0.3, y = 0.3; x = 0.3, y = 0.05; x = 0.5, y = 0.05 were synthesized by a solid state reaction technique. The XRD patterns of these samples have anisotropic broadening of diffraction peaks. The crystallographic data were analyzed by the Rietveld method. During the refinement process the Stephens’s approach was used. All the samples studied are solid solutions with the tetragonal perovskite structure. The degree of tetragonal distortion of these solid solutions decreases with an increase in the Zr content. The microstructure analysis showed that the broadening of the diffraction peaks on the XRD patterns is due to both strains and small crystallite sizes.


Corresponding author: Vladimir Sirotinkin, A. A. Baikov Institute of Metallurgy and Materials Science (IMET), Moscow 119991, Russia, E-mail:

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: None declared.

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

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Received: 2022-04-17
Accepted: 2022-10-26
Published Online: 2022-11-21
Published in Print: 2023-01-27

© 2022 Walter de Gruyter GmbH, Berlin/Boston

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