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New Approaches to the Synthesis of Ultralow-Palladium Automotive Emission Control Catalysts

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Abstract

Laser electrodispersion has been used as an alternative to the chemical synthesis of palladium-containing catalysts. The thus produced catalysts supported on alumina and HZSM-5 zeolite have high catalytic activity and stability at ultralow palladium content (0.03 wt %) in a model reaction of CO oxidation under conditions of prompt thermal aging. According to X-ray photoelectron spectroscopy and transmission electron microscopy data, palladium in the catalyst samples predominantly occurs in the Pd0 state as fine particles about 2.0 nm in size, which almost completely cover the support surface. The textural characteristics of both supports are retained after the deposition of palladium. The modification of zeolite with palladium increases the adsorption capacity for hydrocarbons, which gives rise to a sorption effect in the temperature dependences of the CO conversion. The palladium-containing alumina-based catalyst demonstrated the best stability during heat treatment up to 1000°C.

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ACKNOWLEDGMENTS

The work was performed using equipment purchased under the Development Program of Moscow State University.

Funding

The work was supported by the Ministry of Science and Higher Education of the Russian Federation under state assignments for the Ioffe Institute, RAS (project no. 0040-2019-0010); Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Science, Novosibirsk, Russia (project no. AAAA-A21-121011390054-1), and Moscow State University, Moscow, Russia (project no. АААА-А21-121011590090-7).

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Authors and Affiliations

  1. Moscow State University, 119991, Moscow, Russia

    T. N. Rostovshchikova & M. I. Shilina

  2. Ioffe Institute, Russian Academy of Sciences, 194021, St. Petersburg, Russia

    S. A. Gurevich & D. A. Yavsin

  3. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia

    G. B. Veselov & A. A. Vedyagin

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  1. T. N. Rostovshchikova
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  2. M. I. Shilina
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  3. S. A. Gurevich
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  5. G. B. Veselov
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Translated by V. Glyanchenko

This work was submitted to the special issue “Heterogeneous Catalysis and Environmental Protection.”

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Rostovshchikova, T.N., Shilina, M.I., Gurevich, S.A. et al. New Approaches to the Synthesis of Ultralow-Palladium Automotive Emission Control Catalysts. Dokl Phys Chem 506, 123–130 (2022). https://doi.org/10.1134/S001250162260019X

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