Ternary orthorhombic Laves phases Sr2Pd3Sn, Eu2Pd3Sn and Eu2Pd3In

Joshua Wiethölter; Aylin Koldemir; Theresa Block; Maximilian Kai Reimann; Steffen Klenner; Rainer Pöttgen

doi:10.1515/zkri-2023-0014

Published by De Gruyter (O) April 17, 2023

Ternary orthorhombic Laves phases Sr₂Pd₃Sn, Eu₂Pd₃Sn and Eu₂Pd₃In

Joshua Wiethölter , Aylin Koldemir , Theresa Block , Maximilian Kai Reimann , Steffen Klenner and Rainer Pöttgen

From the journal Zeitschrift für Kristallographie - Crystalline Materials

https://doi.org/10.1515/zkri-2023-0014

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Abstract

The ternary Laves phases Sr₂Pd₃Sn, Eu₂Pd₃Sn and Eu₂Pd₃In were synthesized by induction melting of the elements in sealed tantalum ampoules. The polycrystalline products were characterized through their powder X-ray diffraction patterns. The structure of Eu₂Pd₃Sn was refined from single crystal X-ray diffractometer data: Mg₂MnGa₃ type, Cmcm, a = 583.36(5), b = 908.31(7), c = 958.06(8) pm, wR2 = 0.0366, 557 F² values, 23 variables. The palladium and tin atoms show the inverse coloring on the network of condensed tetrahedra of Mg₂MnGa₃, i.e., MnGa₃ versus Pd₃Sn. Refinement of the occupancy parameters revealed small defects for the europium site, leading to composition Eu_1.962(6)Pd₃Sn for the studied crystal. Sr₂Pd₃Sn is a Pauli paramagnet and Eu₂Pd₃Sn shows Curie-Weiss paramagnetism (7.86(1) µ_B Eu atom⁻¹ and Θ_P = 48.1(1) K). Ferromagnetic ordering is observed below T_C = 46.1(1) K. The ¹¹⁹Sn and ¹⁵¹Eu Mössbauer spectra of Sr₂Pd₃Sn and Eu₂Pd₃Sn are discussed with respect to electron density changes as a function of the tin content and the ionicity in the sequence of the stannides Sr₂Pd₃Sn/Eu₂Pd₃Sn → Sr₂Pd₂Sn/Eu₂Pd₂Sn → EuPdSn → EuPdSn₂.

Keywords: intermetallics; Laves phases; magnetic properties; Mössbauer spectroscopy

Corresponding author: Rainer Pöttgen, Institut für Anorganische und Analytische Chemie, Universität Münster, Corrensstrasse 30, 48149 Münster, Germany, E-mail: pottgen@uni-muenster.de

Acknowledgments

We thank Dipl.-Ing. J. Kösters for collecting the single crystal data, M. Sc. C. Paulsen for the EDX analyses and M. Sc. L. Schumacher for experimental help with the susceptibility measurements.

Author contributions: All authors have accepted responsibility for the entire content of this submitted manuscript and approved the submission.
Research funding: None declared.
Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

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Received: 2023-03-17

Accepted: 2023-03-31

Published Online: 2023-04-17

Published in Print: 2023-05-25

Ternary orthorhombic Laves phases Sr₂Pd₃Sn, Eu₂Pd₃Sn and Eu₂Pd₃In

Abstract

Acknowledgments

References

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