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Aerobic Oxidative Cyclization of 2-Mercaptobenzamide to 1,2-Benzoisothiazolin-3-one in the Presence of Mn(OAc)2

  • CATALYSIS IN CHEMICAL AND PETROCHEMICAL INDUSTRY
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Abstract

One of a widely used broad-spectrum industrial bactericidal and mildew prevention agents is 1,2-benzoisothiazolin-3-one (BIT). In present study, it was demonstrated that aerobic oxidative cyclization of 2‑mercaptobenzamide (MBA) and 2,2'-disulfanediyldibenzamide (DSBA) in the presence of Mn(OAc)2 as catalyst allowed to obtain BIT. The mechanism reaction was suggested. It was found that DSBA and MBA can be converted to the BITwith 99% yield at 1.0 mol % Mn(OAc)2 under 0.3 MPa of oxygen and 100°C for 8 h. Experimental data point that this protocol is both economical and environmentally friendly.

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Authors and Affiliations

  1. Green Catalysis Center, College of Chemistry, Zhengzhou University, 450001, Zhengzhou, China

    Xuchen Shang, Pan He, Yingchao Dou, Bo Yang & Guanyu Yang

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  1. Xuchen Shang
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  2. Pan He
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Correspondence to Xuchen Shang, Pan He, Yingchao Dou, Bo Yang or Guanyu Yang.

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Xuchen Shang, He, P., Dou, Y. et al. Aerobic Oxidative Cyclization of 2-Mercaptobenzamide to 1,2-Benzoisothiazolin-3-one in the Presence of Mn(OAc)2. Catal. Ind. 15, 36–42 (2023). https://doi.org/10.1134/S2070050423010087

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