Abstract
An investigation was carried out to study the feasibility of using synthesized acid-bearing carbonaceous catalyst (SO3H–C and PO4H2–C) derived from cassava peel for biodiesel production from waste cooking oil (WCO). The catalyst activity was tested using an autoclave type reactor and three different oil to alcohol ratios (1 : 3, 1 : 5 and 1 : 7) at four different temperatures (50–80°C) for 4 h. Two types of alcohol (i.e. methanol (CH3OH) and ethanol (C2H5OH) were used to understand the efficiency of using alcohol in the process. The study indicates that reaction using high ratio of alcohol (1 : 7) generally produced high yield of the biodiesel compared to other ratios. The yield of the biodiesel also increased with increasing temperature over all the reaction systems. The carbon modified with sulphuric acid catalyst showed the highest yield of ~ 90%, which was obtained at 80°C using a 1 : 7 ratio of WCO : alcohol. It was also observed that reaction with methanol produced better yields compared to ethanol reactions where significant differences were observed across both temperature and ratio. The catalysts were characterized using Fourier transform infrared spectroscopy, X-ray powder diffraction, surface area and pore volume analyses. The catalyst is of interest because it is green, non-toxic and synthesized using cassava peel waste.
REFERENCES
Dyrstad, J.M., Skonhoft, A., Christensen, M.Q., and Ødegaard, E.T., Energy Policy, 2019, vol. 125, pp. 103–109. https://doi.org/10.1016/j.enpol.2018.10.051
Garba, M.D. and Jackson, S.D., Appl. Petrochem. Res., 2017, vol. 7, no. 1, pp. 1–8. https://doi.org/10.1007/s13203-016-0173-y
Garba, M.D. and Jackson, S.D., Appl. Petroleum Res., 2019, vol. 9, no. 2, pp. 113–125. https://doi.org/10.1007/s13203-019-0231-3
Perera, F., Ashrafi, A., Kinney, P., and Mills, D., Environ. Res., 2019, vol. 172, pp. 55–72. https://doi.org/10.1016/j.envres.2018.12.016
Cui, D., Deng, Z., and Liu, Z., Appl. Energy, 2019, vol. 254, article no. 113537. https://doi.org/10.1016/j.apenergy.2019.113537
Garba, M.D., Usman, M., Khan, S., Shehzad, F., Galadima, A., Ehsan, M.F., Ghanem, A.S., and Humayun, M., J. Environ. Chem. Eng., 2021, vol. 9, no. 2, article no. 104756. https://doi.org/10.1016/j.jece.2020.104756
Canesin, E.A., de Oliveira, C.C., Matsushita, M., Felicidade Dias, L., Reghiany Pedrão, M., and de Souza, N.E., Electron. J. Biotechnol., 2014, vol. 17, no. 1, pp. 39–45. https://doi.org/10.1016/j.ejbt.2013.12.007
Garba, M.D. and Jackson, S.D., Appl. Petroleum Res., 2021, vol. 11, no. 1, pp. 79–88. https://doi.org/10.1007/s13203-020-00259-3
Asri, N.P., Sari, D.A.P., Poedjojono, B., and Suprapto, Mod. Appl. Sci., 2015, vol. 9, no. 7, pp. 99–106. https://doi.org/10.5539/mas.v9n7p99
Patil, P., Deng, S., Rhodes, J.I., and Lammers, P.J., Fuel, 2010, vol. 89, no. 2, pp. 360–364. https://doi.org/10.1016/j.fuel.2009.05.024
Nas, B. and Berktay, A., Energy Sources, 2007, vol. 2, no. 1, pp. 63–71. https://doi.org/10.1080/15567240500400903
Sahar, Sadaf, S., Iqbal, J., Ullah, I., Bhatti, H.N., Nourene, S., Habib-ur-Rehman, Nisar, J., and Iqbal, M., Sustainable Cities Soc., 2018, vol. 41, pp. 220–226. https://doi.org/10.1016/j.scs.2018.05.037
Canakci, M. and Van Gerpen, J., Trans. ASAE, 2003, vol. 46, no. 4, pp. 945–954. https://doi.org/10.13031/2013.13948
Kulkarni, M.G. and Dalai, A.K., Ind. Eng. Chem. Res., 2006, vol. 45, no. 9, p. 2901–2913. https://doi.org/10.1021/ie0510526
Dong, S., Zhu, M., and Dai, B., Green Sustainable Chem., 2012, vol. 2, no. 1, pp. 8–13. https://doi.org/10.4236/gsc.2012.21002
Yaakob, Z., Mohammad, M., Alherbawi, M., Alam, Z., and Sopian, K., Renewable Sustainable Energy Rev., 2013, vol. 18, pp. 184–193. https://doi.org/10.1016/j.rser.2012.10.016
Galadima, A. and Muraza, O., J. Cleaner Prod., 2020, vol. 263, article no. 121358. https://doi.org/10.1016/j.jclepro.2020.121358
Wang, X., Lei, Y., Yan, L., Liu, T., Zhang, Q., and He, K., Sci. Total Environ., 2019, vol. 676, pp. 18–30. https://doi.org/10.1016/j.scitotenv.2019.04.241
Ziarani, G.M., Lashgari, N., and Badiei, A., J. Mol. Catal. A: Chem., 2015, vol. 397, pp. 166–191. https://doi.org/10.1016/j.molcata.2014.10.009
Pirez, C., Caderon, J.-M., Dacquin, J.-P., Lee, A.F., and Wilson, K., ACS Catal., 2012, vol. 2, no. 8, pp. 1607–1614. https://doi.org/10.1021/cs300161a
Khire, S., Bhagwat, P.V., Fernandes, M., Gangundi, P.B., and Vadalia, H., Indian J. Chem. Technol., 2012, vol. 19, no. 5, pp. 342–350. http://nopr.niscpr.res.in/handle/123456789/14681.
Arata, K., Green Chem., 2009, vol. 11, no. 11, pp. 1719–1728. https://doi.org/10.1039/B822795K
Da Conceição, L.R.V., Reis, C.E.R., de Lima, R., Cortez, D.V., and de Castro, H.F., RSC Adv., 2019, vol. 9, no. 41, pp. 23450–23458. https://doi.org/10.1039/C9RA04300D
Shen, S., Cai, B., Wang, C., Li, H., Dai, G., and Qin, H., Appl. Catal., A, 2014, vol. 473, pp. 70–74. https://doi.org/10.1016/j.apcata.2013.12.037
Qi, X., Liu, N., and Lian, Y., RSC Adv., 2015, vol. 5, no. 23, pp. 17526–17531. https://doi.org/10.1039/C4RA15296D
Malins, K., Brinks, J., Kampars, V., and Malina, I., Appl. Catal., A, 2016, vol. 519, pp. 99–106. https://doi.org/10.1016/j.apcata.2016.03.020
Chellappan, S., Nair, V., Sajith, V., and Aparna, K., Bioresour. Technol. Rep., 2018, vol. 2, pp. 38–44. https://doi.org/10.1016/j.biteb.2018.04.002
Suganuma, S., Nakajima, K., Kitano, M., Hayashi, S., and Hara, M., ChemSusChem, 2012, vol. 5, no. 9, pp. 1841–1846. https://doi.org/10.1002/cssc.201200010
Sandouqa, A., Al-Hamamre, Z., and Asfar, J., Renewable Energy, 2019, vol. 132, pp. 667–682. https://doi.org/10.1016/j.renene.2018.08.029
Fadhil, A.B., Aziz, A.M., and Al-Tamer, M.H., Energy Convers. Manage., 2016, vol. 108, pp. 255–265. https://doi.org/10.1016/j.enconman.2015.11.013
Hu, X., Gunawan, R., Mourant, D., Hasan, M.D.M., Wu, L., Song, Y., Lievens, C., and Li, C.-Z., Fuel Process. Technol., 2017, vol. 155, pp. 2–19. https://doi.org/10.1016/j.fuproc.2016.08.020
Musa, I.A., Egypt. J. Pet., 2016, vol. 25, no. 1, pp. 21–31. https://doi.org/10.1016/j.ejpe.2015.06.007
Yaşar, F., Fuel, 2020, vol. 264, article no. 116817. https://doi.org/10.1016/j.fuel.2019.116817
Thangaraj, B., Solomon, P.R., Muniyandi, B., Ranganathan, S., and Lin, L., Clean Energy, 2019, vol. 3, no. 1, pp. 2–23. https://doi.org/10.1093/ce/zky020
Bardhan, P., Deka., A., Bhattacharya, S.S., Mandal, M., and Kataki, R., in Value-Chain of Biofuels: Fundamentals, Technology, and Standardization, Yusup, S., and Rashidi, N.A., Eds., Amsterdam: Elsevier, 2022, ch. 18, pp. 395–427. https://doi.org/10.1016/B978-0-12-824388-6.00003-8
Demirbas, A., Bioresour. Technol., 2008, vol. 99, no. 5, pp. 1125–1130. https://doi.org/10.1016/j.biortech.2007.02.024
Folayan, A.J., Anawe, P.A.L., Aladejare, A.E., and Ayeni, A.O., Energy Rep., 2019, vol. 5, pp. 793–806. https://doi.org/10.1016/j.egyr.2019.06.013
Zhou, Y., Niu, S., and Li, J., Energy Convers. Manage., 2016, vol. 114, pp. 188–196. https://doi.org/10.1016/j.enconman.2016.02.027
Oliveira, C.F., Dezaneti, L.M., Garcia, F.A.C., de Macedo, J.L., Dias, J.A., Dias, S.C.L., and Alvim, K.S.P., Appl. Catal., A, 2010, vol. 372, no. 2, pp. 153–161. https://doi.org/10.1016/j.apcata.2009.10.027
Marchetti, J.M. and Errazu, A.F., Fuel, 2008, vol. 87, nos. 15–16, pp. 3477–3480. https://doi.org/10.1016/j.fuel.2008.05.011
Zaidi, A., Gainer, J.L., Carta, G., Mrani, A., Kadiri, T., Belarbi, Y., and Mir, A., J. Biotechnol., 2002, vol. 93, no. 3. pp. 209–216. https://doi.org/10.1016/S0168-1656(01)00401-1
Alshehri, F., Weinert, H.M., and Jackson, S.D., React. Kinet., Mech. Catal., 2017, vol. 122, no. 2, pp. 699–714. https://doi.org/10.1007/s11144-017-1251-6
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Mustapha D. Garba, Sunusi, A.M., Hassan, S.A. et al. Biodiesel Production from Waste Cooking Oil, Using an Acid Modified Carbon Catalyst Derived from Cassava Peels. Catal. Ind. 15, 99–107 (2023). https://doi.org/10.1134/S2070050423010038
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DOI: https://doi.org/10.1134/S2070050423010038