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New data on minerals with the GIS framework-type structure: gismondine-Sr from the Bellerberg volcano, Germany, and amicite and Ba-rich gismondine from the Hatrurim Complex, Israel

Published online by Cambridge University Press:  21 April 2023

Katarzyna Skrzyńska Open the ORCID record for Katarzyna Skrzyńska [Opens in a new window] ,
Georgia Cametti ,
Rafał Juroszek Open the ORCID record for Rafał Juroszek [Opens in a new window] ,
Christof Schӓfer  and
Irina Galuskina Open the ORCID record for Irina Galuskina [Opens in a new window]
Katarzyna Skrzyńska*
Affiliation:
University of Silesia, Faculty of Natural Sciences, Institute of Earth Sciences, Sosnowiec 41-200, Poland
Georgia Cametti
Affiliation:
University of Bern, Institute of Geological Science, Bern 3012, Switzerland
Rafał Juroszek
Affiliation:
University of Silesia, Faculty of Natural Sciences, Institute of Earth Sciences, Sosnowiec 41-200, Poland
Christof Schӓfer
Affiliation:
Independent researcher, Untereisesheim, 74257, Germany
Irina Galuskina
Affiliation:
University of Silesia, Faculty of Natural Sciences, Institute of Earth Sciences, Sosnowiec 41-200, Poland
*
Corresponding author: Katarzyna Skrzyńska; Email: katarzyna.skrzynska@us.edu.pl
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Abstract

Gismondine-Sr, recently discovered in the Hatrurim Complex in Israel, has been recognised in a xenolith sample from the Bellerberg volcano in Germany. The empirical crystal-chemical formula indicates elevated K content: (Sr1.74Ca1.05Ba0.09K1.56Na0.49)Σ4.93[Al7.98Si8.06O32]⋅9.62H2O. Additionally, Ba-rich gismondine and amicite have been found in the low-temperature mineral association of the pyrometamorphic rock from the Hatrurim Complex. The Raman spectra of the studied zeolites and the crystal structure of gismondine-Sr from the second occurrence are presented. A review of zeolites with GIS framework-type structure leads to the following conclusions: (1) garronite-Na and gobbinsite are equivalent and constitute a solid solution with garronite-Ca; (2) gismondine-Ca, -Sr, and amicite belong to one mineral series; (3) two zeolites series with different R-factors (defined as Si/(Si+Al+Fe)) can be distinguished within GIS topology: the garronite series (R > 0.6) including garronite-Ca and gobbinsite, with general formula (MyD0.5(x–y))[AlxSi(16–x)O32]⋅nH2O, where M and D refer to monovalent and divalent cations, respectively; and the gismondine series, including amicite, gismondine-Sr and gismondine-Ca, with R ≈ 0.5, and the general formula (MyD0.5(8–y))[Al8Si8O32]⋅nH2O. The Raman band between 475 cm–1 and 485 cm–1 is distinctive for the garronite series, whereas the band around 460 cm–1 is characteristic of the gismondine series. On the basis of these findings, a revision of GIS zeolites nomenclature is suggested.

Keywords

GIS structuregismondinegarroniteamicitegobbinsiteRaman spectroscopyBellerberg volcanoHatrurim Complexmineral serieszeolitic minerals
Type
Article
Information
Mineralogical Magazine , Volume 87 , Issue 3 , June 2023 , pp. 443 - 454
Copyright
Copyright © The Author(s), 2023. Published by Cambridge University Press on behalf of The Mineralogical Society of the United Kingdom and Ireland

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Footnotes

Associate Editor: G. Diego Gatta

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