Abstract
The solid solutions LaNiIn1–xSn
x
and CeNiIn1–xSn
x
were studied by means of X-ray powder diffraction and EDX analyses in the full concentration range for samples annealed at T = 870 K. The limited solubility of the fourth component in the starting compounds with equiatomic composition, and the limits and the unit cell parameters of the solid solutions have been determined. The crystal structure of CeNiIn0.57Sn0.43 was refined from single-crystal X-ray diffraction data: ZrNiAl-type structure; hexagonal space group P
Acknowledgment
The authors are grateful to P. Yu. Demchenko for his help in obtaining separate diffractograms, to V. M. Kordan for his help in studying the microstructures of selected samples and to Dipl.-Ing. U. Ch. Rodewald for collecting the single-crystal data. N. Dominyuk is indebted to DAAD for a research stipend.
-
Author contributions: All authors have accepted responsibility for the entire content of this submitted manuscript and approved the submission.
-
Research funding: This work was partly supported by the Simons Foundation (Award Number: 1037973).
-
Conflict of interest statement: The authors declare no conflicts of interest regarding this article.
References
1. Kalychak, Y. M., Zaremba, V. I., Pöttgen, R., Lukachuk, M., Hoffmann, R.-D. Rare earth–transition metal–indides. In Handbook on the Physics and Chemistry of Rare Earths; Gschneidner, K. A.Jr., Bünzli, J.-C., Pecharsky, V. K., Eds., Vol. 34. Elsevier: Amsterdam, 2005; pp. 1–133.10.1016/S0168-1273(04)34001-8Search in Google Scholar
2. Villars, P., Cenzual, K., Eds. Pearson’s Crystal Data: Crystal Structure Database for Inorganic Compounds (Release 2022/23); ASM International®: Materials Park, Ohio (USA), 2022.Search in Google Scholar
3. Skolozdra, R. V. Stannides of rare-earth and transition metals. In: Handbook on the Physics and Chemistry of Rare Earths; Gschneidner, K. A.Jr., Eyring, L., Eds., Vol. 24. Elsevier Science: Amsterdam, 1997; pp. 399−517.10.1016/S0168-1273(97)24009-2Search in Google Scholar
4. Bodak, O. I., Gladyshevsky, E. I. Ternary System Containing Rare Earth Metals; Vyshcha Shkola: Directory, Lviv, 1985; p. 328.Search in Google Scholar
5. Janka, O., Niehaus, O., Pöttgen, R., Chevalier, B. Z. Naturforsch. 2016, 71b, 737–764; https://doi.org/10.1515/znb-2016-0101.Search in Google Scholar
6. Gupta, S., Suresh, K. G. J. Alloys Compd. 2015, 618, 562–606; https://doi.org/10.1016/j.jallcom.2014.08.079.Search in Google Scholar
7. Szytuła, A., Tyvanchuk, Y., Jaworska-Gołąb, T., Zarzycki, A., Kalychak, Y., Gondek, Ł., Stüsser, N. Chem. Met. Alloys 2008, 1, 97–101; https://doi.org/10.30970/cma1.0012.Search in Google Scholar
8. Kuang, J. P., Cui, H. J., Li, J. Y., Yang, F. M., Nakotte, H., Brück, E., de Boer, F. R. J. Magn. Magn. Mater. 1999, 104–107, 1475–1476; https://doi.org/10.1016/0304-8853(92)90669-f.Search in Google Scholar
9. Fujii, H., Inoue, T., Andoh, Y., Takabatake, T., Satoh, K., Maeno, Y., Fujita, T., Sakurai, J., Yamaguchi, Y. Phys. Rev. B 1989, 39, 6840–6843; https://doi.org/10.1103/physrevb.39.6840.Search in Google Scholar PubMed
10. Skolozdra, R. V., Koretskaya, O. E., Gorelenko, Y. K. Inorg. Mater. 1984, 20, 520–523.Search in Google Scholar
11. Nakamoto, G., Takabatake, T., Fujii, H., Minami, A., Maezawa, K., Oguro, I., Menovsky, A. A. J. Phys. Soc. Jpn. 1995, 64, 4834–4840; https://doi.org/10.1143/jpsj.64.4834.Search in Google Scholar
12. Raymond, S., Regnault, L. P., Kadowaki, H., Nakamoto, G., Takabatake, T., Flouquet, J. Phys. B 1997, 230–232, 667–669; https://doi.org/10.1016/s0921-4526(96)00784-3.Search in Google Scholar
13. Singleton, J., Hill, S. O., Ardavan, A., Matsui, H., Blundell, S. J., Hayes, W., Goy, P., Bucher, E., Hohl, H., Nakamoto, G., Menovsky, A. A., Takabatake, T. Phys. B 1996, 216, 333–335; https://doi.org/10.1016/0921-4526(95)00509-9.Search in Google Scholar
14. Brückl, A., Neumaier, K., Einzel, D., Andres, K., Flaschin, S., Kalvius, G. M., Nakamoto, G., Takabatake, T. J. Low Temp. Phys. 1999, 115, 291–306; https://doi.org/10.1023/a:1021883621341.10.1023/A:1021883621341Search in Google Scholar
15. Mair, S., von Nidda, H.-A. K., Lohmann, M., Loidl, A. Phys. Rev. B 1999, 60, 16409–16414; https://doi.org/10.1103/physrevb.60.16409.Search in Google Scholar
16. Adroja, D. T., Rainford, B. D., Neville, A. J., Mandal, P., Jansen, A. G. M. J. Magn. Magn. Mater. 1996, 161, 157–168; https://doi.org/10.1016/s0304-8853(96)00034-0.Search in Google Scholar
17. Schröder, A., Aeppli, G., Mason, T. E., Bucher, E. Phys. B 1997, 234–236, 861–863; https://doi.org/10.1016/s0921-4526(96)01136-2.Search in Google Scholar
18. Takabatake, T., Nakazawa, Y., Ishikawa, M., Sakakibara, T., Koga, K., Oguro, I. J. Magn. Magn. Mater. 1988, 76–77, 87–88; https://doi.org/10.1016/0304-8853(88)90325-3.Search in Google Scholar
19. Kalvius, G. M., Kratzer, A., Grosse, G., Noakes, D. R., Wäppling, R., von Löhneysen, H., Takabatake, T., Echizen, Y. Phys. B 2000, 289–290, 256–260; https://doi.org/10.1016/s0921-4526(00)00387-2.Search in Google Scholar
20. Echizen, Y., Umeo, K., Takabatake, T. Solid State Commun. 1999, 111, 153–157; https://doi.org/10.1016/s0038-1098(99)00160-x.Search in Google Scholar
21. Drew, A. J., Lee, S. L., Ogrin, F. Y., Charalambous, D., Bancroft, N., Paul, D. M., Takabatake, T., Baines, C. Phys. B 2006, 374–375, 270–273; https://doi.org/10.1016/j.physb.2005.11.072.Search in Google Scholar
22. Yartys, V. A., Olavesen, T., Hauback, B. C., Fjellvåg, H., Brinks, H. W. J. Alloys Compd. 2002, 330–332, 141–145; https://doi.org/10.1016/s0925-8388(01)01523-7.Search in Google Scholar
23. Nolze, G., Kraus, W. Powder Diffr. 1998, 13, 256–259.10.1017/S0885715600020856Search in Google Scholar
24. Stoe WinXpow (Version 1.2), STOE & Cie GmbH: Darmstadt, Germany, 2001.Search in Google Scholar
25. Rodríguez-Carvajal, J. Commission on Powder Diffraction, IUCr Newsletter 2001, 26, 12–19.Search in Google Scholar
26. Sheldrick, G. M. Shelxl-97: Program for Crystal Structure Refinement; University of Göttingen: Göttingen, Germany, 1997.Search in Google Scholar
27. Krypyakevych, P. I., Markiv, V. Y., Mel’nyk, E. V. Dopov. AN URSR, Ser. A 1967, 750–753.Search in Google Scholar
28. Shoemaker, C. B., Shoemaker, D. P. Acta Crystallogr. 1965, 18, 900–905; https://doi.org/10.1107/s0365110x65002189.Search in Google Scholar
29. Emsley, J. The Elements, 2nd ed.; Clarendon Press: Oxford, 1991.Search in Google Scholar
30. Zaremba, N., Schepilov, Y., Nychyporuk, G., Muts, I., Pavlyuk, V., Zaremba, V. Visn. Lviv Univ. Ser. Chem. 2020, 61, 44–51; https://doi.org/10.30970/vch.6101.044.Search in Google Scholar
31. Zaremba, N., Nychyporuk, G., Schepilov, Y., Panakhyd, O., Muts, I., Hlukhyy, V., Pavlyuk, V. Ukr. Chem. J. 2018, 84, 76–84.Search in Google Scholar
32. Zaremba, N., Nychyporuk, G., Schepilov, Y., Serkiz, R., Hlukhyy, V., Pavlyuk, V. Visn. Lviv Univ. Ser. Chem. 2019, 60, 82–90; https://doi.org/10.30970/vch.6001.082.Search in Google Scholar
33. Zaremba, N. V. Ph.D. Thesis, Lviv National University, Lviv, 2020.Search in Google Scholar
34. Chumalo, N., Demchuk, V., Nychyporuk, G., Zaremba, V. Visn. Lviv Univ. Ser. Chem. 2010, 51, 24–30.Search in Google Scholar
© 2023 Walter de Gruyter GmbH, Berlin/Boston