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Kinetic Study of Hydrodesulfurization, Hydrodenitrogenation, and Hydrogenation of Heavy Oil Feedstock Compounds on Sulfide Ni6PMonW(12–n)/Al2O3 Hydrotreating Catalysts

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Abstract

Kinetic studies of hydrodesulfurization (HDS) and hydrodenitrogenation (HDN) reactions were performed. The hydrogenating activity of the synthesized Ni6PMonW(12–n)/Al2O3 catalysts was compared with that of the commercial reference catalyst in the process of hydrotreating of heavy mixed oil feedstock. It was shown that the HDS reaction is described by a pseudosecond order equation, and HDN, by a pseudofirst order equation. The obtained hydrogenates meet the requirements to the quality of feedstock for catalytic cracking plants in terms of coking capacity and sulfur and nitrogen contents.

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Funding

This study was supported by the Russian Federation government; act no. 220 of April 9, 2010; grant no. 14.Z50.31.0038 of February 20, 2017.

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  1. Samara State Technical University, 443100, Samara, Russia

    A. V. Moiseev, N. M. Maximov, P. S. Solmanov & V. A. Tyshchenko

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  1. A. V. Moiseev
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Correspondence to A. V. Moiseev.

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ADDITIONAL INFORMATION

This work was presented at the IV Russian Congress on Catalysis “ROSCATALYSIS” (September 20–25, 2021, Kazan, Russia).

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Translated by L. Smolina

Abbreviations and notation: HDS is hydrodesulfurization; HDN, hydrodenitrogenation; HydA, hydrogenation of polycyclic aromatics; BET, Brunauer–Emmett–Teller method; HPA, heteropolyacid; PAHs, polycyclic aromatic hydrocarbons; FSV, feed space velocity; VG, vacuum gasoil; HCGO, heavy coker gasoil; DA, deasphalizate; AHCs, aromatic hydrocarbons; HPLC, high-performance liquid chromatography; TPD, temperature-programmed desorption; DTA, differential thermal analysis; TGA, thermogravimetric analysis; KHBG, hydrogen/feedstock volume ratio.

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Moiseev, A.V., Maximov, N.M., Solmanov, P.S. et al. Kinetic Study of Hydrodesulfurization, Hydrodenitrogenation, and Hydrogenation of Heavy Oil Feedstock Compounds on Sulfide Ni6PMonW(12–n)/Al2O3 Hydrotreating Catalysts. Kinet Catal 64, 168–179 (2023). https://doi.org/10.1134/S0023158423020052

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