Abstract
A metal-organic framework (MOF) {[Cd(EtOIPA)(bpp)(H2O)]·2H2O} n (1) has been synthesized under basic hydrothermal conditions by using of 5-ethoxyisophthalic acid (EtOIPAH2) and 1,3-bis(4-pyridyl)propane (bpp) as reagents for cadmium nitrate. Compound 1 was characterized by elemental analysis, single-crystal X-ray diffraction and UV/Vis spectroscopy. In 1, the bpp ligands extend the EtOIPA-Cd chains along the ab plane to form a 2-fold 3D interpenetrating network. Compound 1 emits blue phosphorescence at room temperature with a long lifetime of 4.2 ms.
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Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.
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Research funding: The authors disclose receipt of the following financial support for the research, authorship, and/or publication of this article: We acknowledge financial support from the National Natural Science Foundation of China (Nos. 21971100 and 22171123), Project for Science & Technology Innovation Talents in Universities of Henan Province (No. 21HASTIT006). Scientific Research Projects of Henan Province (Grants 212102210638 and 2019GGJS198).
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Conflict of interest statement: The authors declare no potential conflicts of interest with respect to the research, authorship, and/or publication of this article.
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