Abstract—
A method is proposed for the preparation of antiwear additives based on quaternary ammonium salts of dialkyldithiocarbamic acids by non-catalytic interaction of stoichiometric amounts of the corresponding diamine, carbon disulfide, and tetraalkylammonium chloride in the presence of sodium hydroxide in which the interaction of the initial components is carried out in one stage. All synthesized additives are highly soluble in polyorganosilicone oils, and at a concentration of 0.5–1.0 wt % they exhibit antiwear activity, which is expressed in a significant decrease (in some cases more than twice) in the diameter of the wear scar when tested on a four-ball friction machine. It has been shown that an increase in the length of alkyl groups in the anionic part of the additives leads to a more effective antiwear effect, the same trend manifests itself with an increase in the number of carbon atoms of alkyl groups in ammonium salts. The influence of the concentration of additives on the antiwear properties of lubricating compositions has been studied. The proposed type of additive is a promising friction modifier for silicone lubricants.
REFERENCES
Aziz, T., Fan, H., Khan, F.U., Haroon, M., and Cheng, L., Modified silicone oil types, mechanical properties and applications, Polymer Bull., 2019, vol. 76, no. 4, pp. 2129–2145. https://doi.org/10.1007/s00289-018-2471-2
Vinogradov, G.V., Nametkin, N.S., and Nossov, M.I., Anti-wear and anti-friction properties of polyorganosiloxanes and their mixtures with hydrocarbons, Wear, 1965, vol. 8, no. 2, pp. 93–111. https://doi.org/10.1016/0043-1648(65)90257-7
Pavelko, G.F., Bordubanova, E.G., Zaimovskaya, T.A., Bondarenko, G.N., Lyadov, A.S., and Parenago, O.P., Anomalous dependence of wear properties on mixture composition of hydrocarbon oils with polyorganosiloxanes, J. Frict. Wear, 2018, no. 3, pp. 241–244.
Spikes, H., Friction modifier additives, Tribol. Lett., 2015, vol. 60, no. 1. https://doi.org/10.1007/s11249-015-0589-z
Fan, K., Li, J., Ma, H., Wu, H., Ren, T., Kasrai, M., and Bancroft, G.M., Tribological characteristics of ashless dithiocarbamate derivatives and their combinations with ZDDP as additives in mineral oil, Tribol. Int., 2008, vol. 41, no. 12, pp. 1226–1231. https://doi.org/10.1016/j.triboint.2008.03.010
Kano, M., Yasuda, Y., and Ye, J.P., The effect of ZDDP and MoDTC additives in engine oil on the friction properties of DLC-coated and steel cam followers, Lubric. Sci., 2004, vol. 17, no. 1, pp. 95–103. https://doi.org/10.1002/ls.3010170108
Parenago, O.P., Oganesova, E.Yu., Lyadov, A.S., and Sharaeva, A.A., Synthesis of environmentally safe antiwear additives to lubricating materials: State of the art and prospects, Russ. J. Appl. Chem., 2020, vol. 93, no. 11, pp. 1629–1637. https://doi.org/10.1134/S1070427220110014
Spikes, H., Low- and zero-sulphated ash, phosphorus and sulphur anti-wear additives for engine oils, Lubric. Sci., 2008, vol. 20, pp. 103–136. https://doi.org/10.1002/ls.57
Zeng, X., Lia, J., Wua, X., Rena, T., and Liu, W., The tribological behaviors of hydroxyl-containing dithiocarbamate-triazine derivatives as additives in rapeseed oil, Tribol. Int., 2007, vol. 40, no. 3, pp. 560–566. https://doi.org/10.1016/j.triboint.2006.05.005
Huang, W., Hou, B., Zhang, P., and Dong, J., Tribological performance and action mechanism of s-[2-(acetamido) thiazol-1-yl] dialkyl dithiocarbamate as additive in rapeseed oil, Wear, 2004, vol. 256, nos. 11–12, pp. 1106–1113. https://doi.org/10.1016/S0043-1648(03)00532-5
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The study was carried out within the framework of the state assignment of the Institute of Petrochemical Synthesis, Russian Academy of Sciences.
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Lyadov, A.S., Oganesova, E.Y., Kochubeev, A.A. et al. New Type of Antiwear Additives Based on Quaternary Ammonium Salts of Dialkyldithiocarbamic Acids for Silicone Lubricants. J. Frict. Wear 44, 10–12 (2023). https://doi.org/10.3103/S1068366623010075
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DOI: https://doi.org/10.3103/S1068366623010075