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Development and Study of a Carbon–Mineral Catalyst Based on Natural Clay and Tire Crumb for the Oxidative Decomposition of Nonionic Surfactants with Hydrogen Peroxide in Wastewater

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Abstract

Samples of a carbon–mineral catalyst based on natural clay and tire crumb for the oxidative decomposition of nonionic surfactants (NSes) with hydrogen peroxide in wastewater have been developed and studied. The iron content in the samples has been varied in a range of 2.3–3.9 wt %. The effect of the pyrolysis temperature varied for the samples in a range of 350–800°C on changes in their textural characteristics, the number and type of acid sites on the surface, and the ζ-potential (zeta potential) of colloidal systems based on the synthesized samples has been studied. Using model solutions under steady-state and dynamic conditions, the effect of the pyrolysis temperature used for the samples on their catalytic properties in the oxidative decomposition of H2O2 and the neonol AF 9-10 NS with hydrogen peroxide has been studied. The best result in the oxidation of neonol AF 9-10 with hydrogen peroxide has been obtained in the presence of a carbon–mineral catalyst sample calcined at 650°C.

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ACKNOWLEDGMENTS

The authors thank Prof. A.A. Il’in and Prof. N.E. Gordina (Ivanovo State University of Chemistry and Technology) for their assistance in analyzing the acidic properties of the samples by the ammonia TPD method and interpreting the results obtained.

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Authors and Affiliations

  1. Mendeleev University of Chemical Technology of Russia, 125047, Moscow, Russia

    M. M. Fidchenko, M. B. Alekhina, A. N. Beznosyuk, A. D. Varnavskaya & E. V. Mishchenko

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  1. M. M. Fidchenko
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  2. M. B. Alekhina
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  3. A. N. Beznosyuk
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  4. A. D. Varnavskaya
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  5. E. V. Mishchenko
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Correspondence to M. M. Fidchenko.

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Translated by M. Timoshinina

Abbreviations and notation: NS, nonionic surfactant; OMS, organomineral sorbent; CMC, carbon–mineral catalyst; BET, Brunauer–Emmett–Teller method; TPD, temperature-programmed desorption.

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Fidchenko, M.M., Alekhina, M.B., Beznosyuk, A.N. et al. Development and Study of a Carbon–Mineral Catalyst Based on Natural Clay and Tire Crumb for the Oxidative Decomposition of Nonionic Surfactants with Hydrogen Peroxide in Wastewater. Kinet Catal 64, 260–269 (2023). https://doi.org/10.1134/S0023158423030035

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  • DOI: https://doi.org/10.1134/S0023158423030035

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