Skip to content
Licensed Unlicensed Requires Authentication Published by De Gruyter July 3, 2023

Effect of alkali charge on the performance of Eucalyptus globulus kraft pulps for tissue applications

  • Ana Henriques and Dmitry V. Evtuguin EMAIL logo
From the journal Holzforschung

Abstract

The present study aimed to evaluate the effect of active alkali charge, in kraft cooking of Eucalyptus globulus wood, on the properties of the laboratory-produced tissue paper. Eucalyptus wood chips were cooked under similar conditions at four different active alkali (AA) levels of 16, 19, 21, and 23 % and DEDED sequence was used for subsequent ECF bleaching. Pulps were analyzed for their intrinsic viscosity, chemical composition, and fiber morphology, while the corresponding papers (20 g/m2) were examined for their strength properties, absorptivity, and softness. It was demonstrated that changes in the AA upon cooking, not only affected the chemical composition of the obtained pulps and their intrinsic viscosity, but also the fiber’s shape (e.g., curl and kink). These changes caused variations in the properties of laboratory-produced tissue papers. Thus, the increase in AA led to paper with lower tensile strength, but with better softness. Even though the increase of AA in cooking led to bulkier papers, their absorptivity was not significantly enhanced. This was explained, at least in part, by the lower water retention of the pulps obtained from cooking with higher AA.


Corresponding author: Dmitry V. Evtuguin, CICECO/Department of Chemistry, University of Aveiro, 3810-193 Aveiro, Portugal, E-mail:
This article is a special contribution associated to a presentation made in the 16th European Workshop on Lignocellulosics and Pulp (EWLP) 2022, Gothenburg, Sweden, Jun 28 to Jul 1, 2022.

Funding source: Compete 2020

Award Identifier / Grant number: nº246/AXIS II/2017

  1. Author contributions: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: This work was carried out under the Project Inpactus – innovative products and technologies from eucalyptus, project no. 21874 funded by Portugal 2020 through European Regional Development Fund (ERDF) in the frame of COMPETE 2020 nº246/AXIS II/2017 and also by the project CICECO-Aveiro Institute of Materials, UIDB/50011/2020 & UIDP/50011/2020, financed by national funds through the FCT/MEC and when appropriate co-financed by FEDER under the PT2020 Partnership Agreement.

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

References

Azevedo, C.A., Rebola, S.M., Domingues, E.M., Figueiredo, F.M.L., and Evtuguin, D.V. (2020). Relationship between surface properties and fiber network parameters of Eucalyptus kraft pulps and their absorption capacity. Surfaces 3: 265–281, https://doi.org/10.3390/surfaces3030020.Search in Google Scholar

Biermann, C.J. (1996). Wood and fiber fundamentals. In: Biermann, C.J. (Ed.), Handbook of pulping and papermaking. Academic Press, San Diego.10.1016/B978-012097362-0/50006-6Search in Google Scholar

Brännvall, E. (2009). Overview of pulp and paper processes. In: Ek, M., Gellerstedt, G., and Henriksson, G. (Eds.), Pulp and paper chemistry and technology, Vol. 2. Walter de Gruyter GmbH & Co, Berlin, pp. 121–148.Search in Google Scholar

Chatterjee, P.K. and Gupta, B.S. (2002). Porous structure and liquid flow models. In: Chatterjee, P.K., and Gupta, B.S. (Eds.), Absorbent technology, 1st ed. Elsevier, Amsterdam, pp. 2–53.10.1016/S0920-4083(02)80004-4Search in Google Scholar

Carvalho, M.G., Ferreira, P., Santos, J., Amaral, J., and Figueiredo, M. (2005). Effect of extended cooking and oxygen pre-bleaching on the surface energy of Eucalyptus globulus kraft pulps. J. Pulp Pap. Sci. 31: 90–94.Search in Google Scholar

d’A. Clark, J. (Ed.) (1985). Pulp technology and treatment for paper, 2nd ed. Miller Freeman Publ. Inc, San Francisco.Search in Google Scholar

Daniel, A.I.D., Pascoal Neto, C., Evtuguin, D.V., and Silvestre, A.J.D. (2003). Hexenuronic acid contents of Eucalyptus globulus kraft pulps: variation with pulping conditions and effect on ECF bleachability. Tappi J. 2: 3–8.Search in Google Scholar

Ershova, O., Costa, E.V., Fernandes, A.J.S., Domingues, M.R., Evtuguin, D.V., and Sixta, H. (2012). Effect of urea on cellulose degradation under conditions of alkaline pulping. Cellulose 19: 2195–2204, https://doi.org/10.1007/s10570-012-9791-4.Search in Google Scholar

Evtuguin, D., Tomás, J., Silva, A., and Pascoal Neto, C. (2003). Characterization of an acetylated heteroxylan from Eucafsxly1ptus globulus Labill. Carbohydr. Res. 338: 597–604, https://doi.org/10.1016/s0008-6215(02)00529-3.Search in Google Scholar PubMed

Foelkel, C. (2016). As fibras celulósicas de eucaliptos na produção de papéis tissue de elevados níveis de maciez e absorção. Eucalyptus online book & newsletter no. 52, AB, Brazil, Available at: http://www.eucalyptus.com.br/artigos/news52_Eucalyptus_tissue.pdf (Accessed 18 March 2022).Search in Google Scholar

Gigac, J. and Fišerová, M. (2008). Influence of pulp refining on tissue paper properties. Tappi J. 7: 27–32.10.32964/TJ7.8.27Search in Google Scholar

Gomes, T., Mendes de Sousa, A.P., Belenkiy, J.I., and Evtuguin, D.V. (2020). Xylan accessibility of bleached eucalypt pulp in alkaline solutions. Holzforschung 74: 141–148, https://doi.org/10.1515/hf-2019-0023.Search in Google Scholar

International Organization for Standardization (1995). Pulps – determination of stock concentration (ISO 4119-1995).Search in Google Scholar

International Organization for Standardization (2005). Pulps – preparation of laboratory sheets for physical testing – part 1: conventional sheet-former method (ISO 5269-1-2005).Search in Google Scholar

International Organization for Standardization (2010). Tissue paper and tissue products – part 8: water-absorption time and water absorption capacity, basket-immersion test method (ISO 12625-8-2010).Search in Google Scholar

International Organization for Standardization (2014). Tissue paper and tissue products – part 3: determination of thickness, bulking thickness and apparent bulk density and bulk (ISO 12625-3-2014).Search in Google Scholar

International Organization for Standardization (2016). Tissue paper and tissue products – part 6: determination of grammage (ISO 12625-6-2016).Search in Google Scholar

Kline, J.E. (Ed.) (1991). Paper and paperboard: manufacturing and converting fundamentals. Miller Freeman Publications, California, USA.Search in Google Scholar

Koch, G. (2006). Raw material for pulp. In: Sixta, H. (Ed.). Handbook of pulp. Wiley VCH, Weinheim, Germany, pp. 21–68.10.1002/9783527619887.ch2Search in Google Scholar

Launer, H. and Wilson, W. (1939). Determination of pentosans in pulps and paper. J. Res. Natl. Bur. Stand. 22: 471–484, https://doi.org/10.6028/jres.022.021.Search in Google Scholar

Marinho, N.P., Klock, U., Lengowski, C., Muñiz, G.I., and Zamarian, C. (2017). Características da polpa kraft extraída da espécie Acácia-negra na produção de papel. Floresta e Ambiente 24: e00099214, https://doi.org/10.1590/2179-8087.099214.Search in Google Scholar

Morais, F.P., Bértolo, R.A.C., Curto, J.M.R., Amaral, M.E.C.C., Carta, A.M.M.S., and Evtyugin, D.V. (2019). Comparative characterization of eucalyptus fibers and softwood fibers for tissue papers applications. Mater. Lett. X 4: 100028, https://doi.org/10.1016/j.mlblux.2019.100028.Search in Google Scholar

Page, H., Seth, S., Jordan, D., and Barbe, C. (1985). Curls, crimps, kinks and microcompressions in pulp fibers – their origin, measurement and significance. In: Punton, V.W. (Ed.). Papermaking raw materials. Mechanical Engineering Publications, London, pp. 183–227.Search in Google Scholar

Pinto, P.C., Evtuguin, D.V., and Pascoal Neto, C. (2005). Structure of hardwood glucuronoxylans: modifications and impact on pulp retention during wood kraft pulping. Carbohydr. Res. 60: 489–497, https://doi.org/10.1016/j.carbpol.2005.03.001.Search in Google Scholar

Pirralho, M., Flores, D., Sousa, V.B., Quilhó, T., Knapic, S., and Pereira, H. (2014). Evaluation on paper making potential of nine Eucalyptus species based on wood anatomical features. Ind. Crops Prod. 54: 327–334, https://doi.org/10.1016/j.indcrop.2014.01.040.Search in Google Scholar

Rebola, S.M., Ferreira, J., and Evtuguin, D.V. (2020). Potential of bleached eucalyptus kraft pulp for applications in nonwoven fibrous fabrics. J. Eng. Fibers Fabr. 15: 1–13, https://doi.org/10.1177/1558925020980146.Search in Google Scholar

Rebola, S.M., Azevedo, C., and Evtuguin, D.V. (2021). Effect of cooking and bleaching conditions on the properties of eucalyptus kraft fluff pulps. Cellulose 28: 4411–4426, https://doi.org/10.1007/s10570-021-03789-8.Search in Google Scholar

Rebuzzi, F. and Evtuguin, D.V. (2006). Effect of glucuronoxylan on the hornification of Eucalyptus globulus bleached pulps. Macromol. Symp. 232: 121–128, https://doi.org/10.1002/masy.200551414.Search in Google Scholar

Retulainen, E., Moss, P., and Nieminen, K. (1993). Effect of fines on the properties of fiber networks. In: Proceedings of 10th fundamental research symposium, Vol. 2. Oxford, UK, pp. 727–734.Search in Google Scholar

Roberts, J.C. (1996). An introduction to paper. In: Roberts, J.C. (Ed.). The chemistry of paper. Royal Society of Chemistry, Cambridge, UK, pp. 1–10.10.1039/9781847552068-00001Search in Google Scholar

Santiago, A.S. and Pascoal Neto, C. (2007). Assessment of potential approaches to improve Eucalyptus globulus kraft pulping yield. J. Chem. Technol. Biotechnol. 82: 424–430, https://doi.org/10.1002/jctb.1685.Search in Google Scholar

Scallan, A.M. and Tigerström, A.C. (1992). Swelling and elasticity of the cell walls of pulp fibres. J. Pulp Pap. Sci. 18: J188–J193.Search in Google Scholar

Scandinavian Pulp, Paper, and Board Testing Committee (1998). Viscosity in cupriethylenediamine solution. SCAN-CM 15: 88.Search in Google Scholar

Sousa, C.T., Evtuguin, D.V., and Amaral, J.L. (2017). Hardwood kraft pulp structural features affecting refinability. Holzforschung 71: 619–624, https://doi.org/10.1515/hf-2016-0205.Search in Google Scholar

TAPPI Test Method (2018). Brightness of pulp, paper and paperboard (directional reflectance at 457 nm) (test method T452 om-18-2018).Search in Google Scholar

TAPPI Test Method (2018). Carboxyl content of pulp (Tappi T 237 om-93-2018).Search in Google Scholar

TAPPI Test Method (2013). Kappa number of pulp (Tappi 236 cm-85-2013).Search in Google Scholar

Trepanier, R. (2017). Pulp fiber quality and the relationship with paper tissue properties. In: Proceedings of tissue conference & expo 2017: the power of TAPPI & RISI, Miami Beach, Florida, USA, pp. 74–78.Search in Google Scholar

Young, R.A. (1994). Comparison of the properties of chemical cellulose pulps. Cellulose 2: 107–130, https://doi.org/10.1007/bf00819662.Search in Google Scholar

Zhang, Y., Sjögren, B., Engstrand, P., and Htun, M. (1994). Determination of charged groups in mechanical pulp fibres and their influence on pulp properties. J. Wood Chem. Technol. 14: 83–102, https://doi.org/10.1080/02773819408003087.Search in Google Scholar

Received: 2023-01-14
Accepted: 2023-06-01
Published Online: 2023-07-03
Published in Print: 2023-08-28

© 2023 Walter de Gruyter GmbH, Berlin/Boston

Downloaded on 30.4.2024 from https://www.degruyter.com/document/doi/10.1515/hf-2023-0006/html
Scroll to top button