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Coordination Polymers of Lithium Based on 1,2-Bis[(2,6-diisopropyl-4-diethylmalonophenyl)imino]acenaphthene

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Abstract

1,2-Bis[(2,6-diisopropyl-4-diethylmalonophenyl)imino]acenaphthene (Dem-Bian) with zinc chloride forms complex [(Dem-Bian)ZnCl2] (I). The reaction of complex I with n-BuLi proceeds with the deprotonation of the malonate fragments and gives 1D coordination polymer [ZnCl2(Dem-Bian)Li(DME)2]n (II). The reaction of [(Dem-Bian)CuCl] with n-BuLi affords 1D polymer [(Dem-Bian)Li2(DME)2]n (III). Compounds I–III are characterized by elemental analysis and IR spectroscopy. Derivatives I and II are characterized by 1Н NMR spectroscopy. The crystal structures of compounds II and III are determined by X-ray diffraction (XRD). Their thermal stability is studied by thermogravimetric analysis.

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ACKNOWLEDGMENTS

This work was carried out using the equipment of the Center for Collective Use “Analytical Center of Razuvaev Institute of Organometallic Chemistry of Russian Academy of Sciences” supported by the grant “Provision of Development of Material Technical Infrastructure of Centers for Collective Use of Scientific Equipment” (unique identifier RF−2296.61321X0017, agreement no. 075-15-2021-670).

Funding

This work was supported by the Russian Science Foundation, project no. 19-13-00336-П.

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Authors and Affiliations

  1. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhny Novgorod, Russia

    N. L. Bazyakina, V. G. Sokolov, M. V. Moskalev, E. V. Baranov & I. L. Fedushkin

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  1. N. L. Bazyakina
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  2. V. G. Sokolov
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  3. M. V. Moskalev
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  4. E. V. Baranov
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  5. I. L. Fedushkin
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Correspondence to I. L. Fedushkin.

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Translated by E. Yablonskaya

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Bazyakina, N.L., Sokolov, V.G., Moskalev, M.V. et al. Coordination Polymers of Lithium Based on 1,2-Bis[(2,6-diisopropyl-4-diethylmalonophenyl)imino]acenaphthene. Russ J Coord Chem 49, 397–406 (2023). https://doi.org/10.1134/S1070328422600620

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