Skip to main content
SpringerLink
Log in

Second Example of a Cubane-Like Nickel(II) Complex in a Series of N-Derivatives of Taurine

  • Published:
Russian Journal of Coordination Chemistry Aims and scope Submit manuscript

Abstract

A new homometallic cubane-like nickel(II) complex based on N-2-(2-pyridyl)ethyl-2-aminoethanesulfonic acid [Ni4L4(OH)4]·2H2O (I) is synthesized, and its structure is studied by X-ray diffraction (XRD) (CIF file CCDC no. 2211359). In crystals of the complex, the metallocenters are joined into tetrahedra with the Ni…Ni distances (3.144–3.201 Å) supplemented to cubanes by the μ3-bridging oxygen atoms of the hydroxy groups. The coordination environment of each metallocenter is a distorted octahedron. The ligand is deprotonated, exists in the facial conformation, and performs the tridentate function to form two six-membered conjugated chelate cycles.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.

Similar content being viewed by others

REFERENCES

  1. Pestov, A.V., Slepukhin, P.A., and Charushin, V.N., Russ. Chem. Rev., 2015, vol. 84, no. 3, p. 310. https://doi.org/10.1070/RCR4461

    Article  CAS  Google Scholar 

  2. Petrova, Y.S. and Neudachina, L.K., Russ. J. Inorg. Chem., 2013, vol. 58, no. 5, p. 617. https://doi.org/10.1134/S0036023613050173

    Article  CAS  Google Scholar 

  3. Zemlyakova, E.O., Pestov, A.V., Slepukhin, P.A., et al., Russ. J. Coord. Chem., 2018, vol. 44, no. 11, p. 667. https://doi.org/10.1134/S107032841811009X

    Article  CAS  Google Scholar 

  4. Ul’yanova, M.I., Baskakova, S.A., Aksenova, T.V., et al., Russ. J. Coord. Chem., 2015, vol. 41, p. 240. https://doi.org/10.1134/S1070328415040090

    Article  CAS  Google Scholar 

  5. Pestov, A.V., Slepukhin, P.A., Koryakova, O.V., et al., Russ. J. Coord. Chem., 2014, vol. 40, p. 216. https://doi.org/10.1134/S107032841404006X

    Article  CAS  Google Scholar 

  6. Yusuf, M., Fariduddin, Q., Hayat, S., et al., Bull. Environ. Contam. Toxicol., 2011, vol. 86, no. 1, p. 1.

    Article  CAS  PubMed  Google Scholar 

  7. Fabiano, C.C., Tezotto, T., Favarin, J., et al., Front. Plant Sci., 2015, vol. 6, no. 654.

  8. Li, J.X., Jiang, Y.M., and Chen, M.J., J. Coord. Chem., 2008, vol. 61, no. 11, p. 1765.

    Article  CAS  Google Scholar 

  9. Hosler, E.R., Herbst, R.W., Maroney, M.J., et al., Dalton Trans., 2012, vol. 41, no. 3, p. 804.

    Article  CAS  PubMed  Google Scholar 

  10. Chohan, B.S. and Maroney, M.J., Inorg. Chem., 2006, vol. 45, no. 5, p. 1906.

    Article  CAS  PubMed  Google Scholar 

  11. Henderson, R.K., Bouwman, E., Spek, A.L., et al., Inorg. Chem., 1997, vol. 36, no. 21, p. 4616.

    Article  CAS  PubMed  Google Scholar 

  12. Pestov, A.V., Slepukhin, P.A., and Yatluk, Y.G., Russ. J. Coord. Chem., 2011, vol. 37, no. 8, p. 619. https://doi.org/10.1134/S1070328411070116

    Article  CAS  Google Scholar 

  13. Dolomanov, O.V., Bourhis, L.J., Gildea, R.J., et al., J. Appl. Crystallogr., 2009, vol. 42, no. 2, p. 339.

    Article  CAS  Google Scholar 

  14. Sheldrick, G.M., Acta Crystallogr., Sect. C: Struct. Chem., 2015, vol. 71, p. 3.

    Article  Google Scholar 

Download references

ACKNOWLEDGMENTS

1Н NMR and FT-IR spectra were recorded using the equipment of the Center for Collective Use “Spectroscopy and Analysis of Organic Compounds.”

Funding

This study was supported by the Russian Science Foundation, project no. 22-26-20068; https://rscf.ru/project/22-26-20068.

Author information

Authors and Affiliations

  1. Postovskii Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences, Yekaterinburg, Russia

    E. O. Zemlyakova, L. A. Khamidullina, I. S. Puzyrev, P. D. Tobysheva, P. A. Slepukhin & A. V. Pestov

  2. Ural Federal University named after the first President of Russia B.N. Yeltsin, Yekaterinburg, Russia

    L. A. Khamidullina, Yu. S. Petrova, L. K. Neudachina & A. V. Pestov

Authors
  1. E. O. Zemlyakova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. L. A. Khamidullina
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. I. S. Puzyrev
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. P. D. Tobysheva
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Yu. S. Petrova
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. L. K. Neudachina
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. P. A. Slepukhin
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. A. V. Pestov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to I. S. Puzyrev.

Ethics declarations

The authors declare that they have no conflicts of interest.

Additional information

Translated by E. Yablonskaya

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Zemlyakova, E.O., Khamidullina, L.A., Puzyrev, I.S. et al. Second Example of a Cubane-Like Nickel(II) Complex in a Series of N-Derivatives of Taurine. Russ J Coord Chem 49, 446–452 (2023). https://doi.org/10.1134/S1070328423600195

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070328423600195

Keywords:

Search

Navigation