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Copper(II) o-Iminophenolate Complexes Based on Catecholaldimines

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Abstract

The exchange reactions of 4,6-di-tert-butylpyrocatechols containing in position 3 different N‑aryliminomethyl groups (aryl is p-halophenyl; halogen is fluorine (I), chlorine (II), bromine (III), and iodine (IV); p-tolyl (V)) with copper(II) acetate in a molar ratio of 2 : 1 afford planar square copper(II) o‑iminophenolate complexes of the general formula [(R-CatH)2Cu], where R is the aryl substituent in the Ar–N=CH group. The molecular structures of complexes I, III, and V in the crystalline state are determined by X-ray diffraction (XRD) (CIF files CCDC nos. 2227448 (I), 2226727 (III), and 2227449 (V)). The electrochemical properties of compounds I–V are studied by cyclic voltammetry.

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ACKNOWLEDGMENTS

This work was carried out using the equipment of the Center for Collective Use “Analytical Center of Razuvaev Institute of Organometallic Chemistry of Russian Academy of Sciences” supported by the grant “Provision of Development of Material Technical Infrastructure of Centers for Collective Use of Scientific Equipment” (unique identifier RF—2296.61321X0017, agreements no. 075-15-2021-670).

Funding

This work was supported by the Council on Grants at the President of the Russian Federation, grant no. SP-2139.2021.1.

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Authors and Affiliations

  1. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhny Novgorod, Russia

    S. V. Baryshnikova, M. V. Arsen’ev, R. V. Rumyantsev & A. I. Poddel’skii

  2. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    I. A. Yakushev

Authors
  1. S. V. Baryshnikova
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  2. M. V. Arsen’ev
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  3. R. V. Rumyantsev
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  4. I. A. Yakushev
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  5. A. I. Poddel’skii
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Corresponding author

Correspondence to S. V. Baryshnikova.

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Translated by E. Yablonskaya

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Baryshnikova, S.V., Arsen’ev, M.V., Rumyantsev, R.V. et al. Copper(II) o-Iminophenolate Complexes Based on Catecholaldimines. Russ J Coord Chem 49, 429–436 (2023). https://doi.org/10.1134/S107032842360016X

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  • DOI: https://doi.org/10.1134/S107032842360016X

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