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Heteroleptic Zinc Catecholate Complexes with N-Donor Ligands

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Abstract

New heteroleptic zinc catecholate complexes based on 3,6-di-tert-butyl-o-benzoquinone and containing metal-coordinated N-donor ligands (2,2'-bipyridine and phenanthroline) were prepared by ligand exchange. According to X-ray diffraction data, both complexes were dimers with multiple intermolecular π–π interactions between the aromatic moieties of neighboring molecules (CCDC nos. 2222704 (I), 2222705 (II)). The electronic transmission spectra of crystalline samples of I and II and their solutions show broad absorption bands in the visible region with a maximum at about 500 nm.

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ACKNOWLEDGMENTS

This study was performed using the equipment of the Center for Collective Use, Analytical Center of the Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, supported by the grant “Provision of the Development of the Material and Technical Infrastructure of the Centers for the Collective Use of Research Equipment” (unique identifier RF–2296.61321X0017, contract no. 075-15-2021-670). X-ray diffraction study of complexes I and II was carried out using the equipment of the Center for Collective Use of Physical Investigation Methods of the Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences.

Funding

This study was supported by the Russian Science Foundation (grant no. 22-13-00351).

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Authors and Affiliations

  1. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhny Novgorod, Russia

    A. V. Maleeva, O. Yu. Trofimova & A. V. Piskunov

  2. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia

    I. A. Yakushev

  3. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia

    R. R. Aysin

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  1. A. V. Maleeva
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  2. O. Yu. Trofimova
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  3. I. A. Yakushev
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  4. R. R. Aysin
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  5. A. V. Piskunov
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Correspondence to A. V. Maleeva or A. V. Piskunov.

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The authors declare that they have no conflicts of interest.

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Translated by Z. Svitanko

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Maleeva, A.V., Trofimova, O.Y., Yakushev, I.A. et al. Heteroleptic Zinc Catecholate Complexes with N-Donor Ligands. Russ J Coord Chem 49, 420–428 (2023). https://doi.org/10.1134/S1070328423600134

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  • DOI: https://doi.org/10.1134/S1070328423600134

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