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Factorial-Based Analysis of the Hydrothermal Transformations of Glucose

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Abstract—

Hydrothermal processing of glucose affording carbonaceous nanoparticles has been analyzed using the factorial design approach. The probed variables (pH and concentration of glucose in the solution, temperature and duration of the treatment) as well as some of their interactions have significantly affected the process outcome. The reactor volume has not significantly influenced the synthesis. The highest yield of the carbonaceous nanoparticles has been observed at low concentration of the precursor, high temperature and long duration of the process, irrespectively of the starting pH level. Longer treatment has also favored the formation of the insoluble product, especially in neutral and alkaline solutions. It has been concluded that a single replication of the factorial design is enough for reliable elucidation of the active factors, whereas their quantitative analysis should be preferably performed with at least two replicates of the design.

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Funding

This study was supported by the Russian Foundation for Basic Research (project no. 20-03-00692).

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Authors and Affiliations

  1. Department of Chemistry, Moscow State University, 119991, Moscow, Russia

    E. A. Karpushkin, A. A. Bugerya, L. I. Lopatina & V. G. Sergeyev

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  1. E. A. Karpushkin
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  2. A. A. Bugerya
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  3. L. I. Lopatina
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  4. V. G. Sergeyev
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Correspondence to E. A. Karpushkin.

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Karpushkin, E.A., Bugerya, A.A., Lopatina, L.I. et al. Factorial-Based Analysis of the Hydrothermal Transformations of Glucose. rev. and adv. in chem. 12, 195–213 (2022). https://doi.org/10.1134/S2634827622600220

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  • DOI: https://doi.org/10.1134/S2634827622600220

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