Abstract
The interaction of penta(para-tolyl)antimony with oximes and carboxylic acids in benzene synthesized oximates and carboxylates of tetra(para-tolyl)antimony p-Tol4SbX (X = ON=CHR, R = CHCHPh (1), С6H4(Br-3) (2); X = OC(O)R', R' = CH2OС6H3Cl2-2,4 (3), CF2CF2C(O)OH (4). The structure of compounds 1–4 was established by X-ray diffraction analysis (XRD). According to XRD data, the antimony atoms in complexes 1–3 have the coordination of a distorted trigonal bipyramid with three aryl ligands in the equatorial plane, while the CSbO axial angles are 178.94(5)°, 174.4(2)° and 176.95(5)°. Crystal 4 consists of distorted tetrahedral cations of tetra(para-tolyl)stibonium (CSbC angles 106.6(2)°−112.46(19)°) and singly charged anions of tetrafluoroethanedioic acid. Complete tables of atomic coordinates, bond lengths, and bond angles for compounds 1, 2, 3, 4 have been deposited at the Cambridge Crystallographic Data Center (CCDC 2130472, 2131085, 2131084, 2126158; deposit@ccdc.cam.ac.uk; http://www.ccdc.cam.ac.uk).
REFERENCES
Kocheshkov, K.A., Skoldinov, A.P., and Zemlyansky, N.N., Metody elementoorganicheskoi khimii. Sur’ma, vismut (Methods of Organoelement Chemistry: Antimony, Bismuth), Moscow: Nauka, 1976.
Sharutin, V.V., Poddel’sky, A.I., and Sharutina, O.K., Russ. J. Coord. Chem., 2020, vol. 46, no. 10, p. 663. https://doi.org/10.1134/S1070328420100012
Akatova, K.N., Bochkova, R.I., Lebedev, V.A., Sharutin, V.V., and Belov, N.V., Dokl. Akad. Nauk SSSR, 1983, vol. 268, no. 6, p. 1389.
Sharutin, V.V., Sharutina, O.K., Pakusina, A.P., Smirnova, S.A., and Pushilin, M.A., Russ. J. Coord. Chem., 2005, vol. 31, no. 2, p. 117.
Sharutin, V.V., Sharutina, O.K., Platonova, T.P., Pakusina, A.P., Gerasimenko, A.V., Gerasimenko, E.A., Bukvetsky, B.V., and Popov, D.Yu., Russ. J. Coord. Chem., 2003, vol. 29, no. 1, p. 13.
Sharutin, V.V., Sharutina, O.K., Panova, L.P., and Belsky, V.K., Russ. J. Gen. Chem., 1997, vol. 67, no. 9, p. 1531.
Sharutin, V.V., Pakusina, A.P., Egorova, I.V., Ivanenko, T.K., Gerasimenko, A.V., and Sergienko, A.S., Russ. J. Coord. Chem., 2003, vol. 29, no. 5, p. 336.
Sharutin, V.V., Sharutina, O.K., Pakusina, A.P., and Belsky, V.K., Russ. J. Gen. Chem., 1997, vol. 67, no. 9, p. 1536.
Sharutin, V.V., Sharutina, O.K., Tarasova, T.A., Harsika, A.N., and Belsky, V.K., Russ. J. Gen. Chem., 1999, vol. 69, no. 12, p. 1979.
Sharutin, V.V., Sharutina, O.K., Platonova, T.P., Pakusina, A.P., and Toichkina, O.N., Russ. J. Gen. Chem., 2000, vol. 70, no. 11, p. 1932.
Sharutin, V.V., Sharutina, O.K., Molokova, O.V., Pakusina, A.P., Gerasimenko, A.V., and Sergienko, A.S., Russ. J. Coord. Chem., 2002, vol. 28, no. 8, p. 581.
Sharutin, V.V., Sharutina, O.K., Molokova, O.V., Ettenko, E.N., Krivolapov, D.B., Gubaidullin, A.T., and Litvinov, I.A., Russ. J. Gen. Chem., 2001, vol. 71, no. 8, p. 1317.
Sharutin, V.V., Sharutina, O.K., Osipov, P.E., Vorobieva, E.B., Muslin, D.V., and Belsky, V.K., Russ. J. Gen. Chem., 2000, vol. 70, no. 6, p. 931.
Sopshina, D.M., Vestn. Yuzhno-Ural. Gos. Univ., Ser. Khim., 2022, vol. 14, no. 1, p. 50. https://doi.org/10.14529/chem220106
Efremov, A.N. and Sharutin, V.V., Vestn. Yuzhno-Ural. Gos. Univ., Ser. Khim., 2021, vol. 13, no. 1, p. 47. https://doi.org/10.14529/chem210105
Sharutina, O.K., Vestn. Yuzhno-Ural. Gos. Univ., Ser. Khim., 2021, vol. 13, no. 4, p. 63. https://doi.org/10.14529/chem210404
Senchurin, V.S. and Orlenko, E.D., Vestn. Yuzhno-Ural. Gos. Univ., Ser. Khim., 2019, vol. 11, no. 2, p. 66. https://doi.org/10.14529/chem190207
Sharutin, V.V., Sharutina, O.K., Bondar, E.A., Pakusina, A.P., Adonin, N.Yu., and Starichenko, V.F., Russ. J. Coord. Chem., 2002, vol. 28, no. 5, p. 356.
Sharutin, V.V., Sharutina, O.K., Efremov, A.N., and Andreev, P.V., Russ. J. Inorg. Chem., 2017, vol. 62, no. 10, p. 1330. https://doi.org/10.7868/S0044457X17100075
Sharutin, V.V. and Sharutina, O.K., Russ. J. Inorg. Chem., 2017, vol. 62, no. 7, p. 925. https://doi.org/10.7868/S0044457X17070224
Sharutin, V.V., Sharutina, O.K., Senchurin, V.S., and Somov, N.V., Russ. J. Inorg. Chem., 2016, vol. 61, no. 8, p. 1017. https://doi.org/10.7868/S0044457X16080146
Sharutin, V.V., Sharutina, O.K., and Efremov, A.N., Russ. J. Struct. Chem., 2020, vol. 61, no. 9, p. 1490. https://doi.org/10.26902/JSC_id60682
Sharutin, V.V., Sharutina, O.K., and Efremov, A.N., Russ. J. Inorg. Chem., 2020, vol. 65, no. 1, p. 49. https://doi.org/10.31857/S0044457X20010158
Sharutin, V.V., Sharutina, O.K., Efremov, A.N., and Artemyeva, E.V., Russ. J. Inorg. Chem., 2020, vol. 65, no. 4, p. 482. https://doi.org/10.31857/S0044457X20040170
Bruker SMART and SAINT-Plus, Data Collection and Processing Software for the SMART system, ver. 5.0, Madison: Bruker AXS, 1998.
Bruker SHELXTL/PC, An Integrated System for Solving, Refining and Displaying Crystal Structures from Diffraction Data, ver. 5.10, Madison: Bruker AXS, 1998.
Dolomanov, O.V., Bourhis, L.J., Gildea, R.J., Howard, J.A.K., and Puschmann, H., J. Appl. Crystallogr., 2009, vol. 42, p. 339. https://doi.org/10.1107/S0021889808042726
Cordero, B., Gómez, V., Platero-Prats, A.E., Revés, M., Echeverría, J., Cremades, E., Barragána, F., and Alvarez, S., Dalton Trans., 2008, no. 21, p. 2832. https://doi.org/10.1039/B801115J
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
The authors declare that they have no conflicts of interest.
Additional information
Translated by S. Avodkova
Rights and permissions
About this article
Cite this article
Sharutin, V.V. The Synthesis and Structural Features of Tetra(para-tolyl)antimony Derivatives. rev. and adv. in chem. 12, 248–254 (2022). https://doi.org/10.1134/S2634827623700046
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S2634827623700046