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Composites Based on MIL-100(Fe) and Diatomite for the Photo-Fenton Degradation of Phenol

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Abstract

Porous composites based on a MIL-100(Fe) metal–organic framework and a natural diatomite material have been synthesized. The composites are characterized by a specific surface area of 322 and 441 m2/g and a hierarchical pore structure represented by wide pores of the original diatomite and narrow meso- and micropores of the formed MIL-100(Fe) particles. The effect of synthesis approach on the structure of the composites and their catalytic properties in the photocatalytic degradation of phenol has been studied. In the composite synthesized with the preimpregnation of diatomite with an iron nitrate solution, MIL-100(Fe) particles are mostly formed inside the diatomite pores. The composite samples exhibit catalytic activity in the photo-Fenton degradation of phenol. The highest activity is exhibited by the sample synthesized without any preimpregnation of diatomite; this sample is characterized by the dominant formation of MIL-100(Fe) particles on the external surface of the diatomite.

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ACKNOWLEDGMENTS

The authors thank L.A. Selyunina (Faculty of Chemistry, National Research Tomsk State University) for conducting SEM studies.

Funding

This work was supported by the Russian Foundation for Basic Research and the Administration of the Tomsk oblast within the framework of research project no. 19-43-700008 r_a.

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Authors and Affiliations

  1. National Research Tomsk State University, 634050, Tomsk, Russia

    P. A. Matskan, E. V. Evdokimova & G. V. Mamontov

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  1. P. A. Matskan
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  2. E. V. Evdokimova
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  3. G. V. Mamontov
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Correspondence to P. A. Matskan.

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Translated by M. Timoshinina

Abbreviations and notation: MOF, metal–organic framework; SEM, scanning electron microscopy; TG, thermogravimetry; DSC, differential scanning calorimetry; XRD, X-ray diffraction analysis; BET, Brunauer–Emmett–Teller method; SBET, specific surface area; Smicro, specific surface area of micropores, Sext, specific surface area of the external surface (not involving the specific surface area of micropores); Vtot, total pore volume; Vmicro, micropore volume.

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Matskan, P.A., Evdokimova, E.V. & Mamontov, G.V. Composites Based on MIL-100(Fe) and Diatomite for the Photo-Fenton Degradation of Phenol. Kinet Catal 64, 421–430 (2023). https://doi.org/10.1134/S0023158423040067

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  • DOI: https://doi.org/10.1134/S0023158423040067

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