Abstract
To gain insight into the applicability as building blocks for optoelectronic device development, alkaline earth metal sulfides are investigated. MgS, CaS, SrS, and BaS have been systematically synthesized as colloidal particles in olelyamine. The particle sizes range from around 819 nm for MgS to 12.8 nm for CaS, 25.0 nm for SrS, and 21.6 nm for BaS. The heat-up synthesis uses commerically available precursors without complicated procedures. The structural and optical properties are investigated with X-ray diffraction, spectroscopic ellipsometry, UV–vis spectrophotometry, scanning electron microscopy, and energy dispersive X-ray spectroscopy.
Funding source: Deutsche Forschungsgemeinschaft
Award Identifier / Grant number: 465220299
Acknowledgements
The authors thank Julien Bachmann and Dirk M. Guldi for use of laboratories and instrumentation and Christian Knüpfer and Sjoerd Harder for providing metal salts at the initiation of the project. The authors thank Lara Kim Linke and Lisa Ngo for their support in laboratory work.
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Author contributions: All authors contributed to data collection, analysis, and writing of the article.
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Research funding: This work was supported by the “Engineering of Advanced Materials” (EAM) Cluster at FAU under a Starting Grant for RWC and by the Deutsche Forschungsgemeinschaft (DFG) – Project number 465220299.
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Conflict of interest statement: The authors declare no conflicts of interest regarding this article.
References
1. Ganesan, A. A., Houtepen, A. J., Crisp, R. W. Quantum dot solar cells: small beginnings have large impacts. Appl. Sci. 2018, 8, 1867; https://doi.org/10.3390/app8101867.Search in Google Scholar
2. Kant, N., Singh, P. Review of next generation photovoltaic solar cell technology and comparative materialistic development. Mater. Today: Proc. 2022, 56, 3460–3470; https://doi.org/10.1016/j.matpr.2021.11.116.Search in Google Scholar
3. Saparov, B. Next generation thin-film solar absorbers based on chalcogenides. Chem. Rev. 2022, 122, 10575–10577; https://doi.org/10.1021/acs.chemrev.2c00346.Search in Google Scholar PubMed
4. Moon, D. G., Rehan, S., Yeon, D. H., Lee, S. M., Park, S. J., Ahn, S., Cho, Y. S. A review on binary metal sulfide heterojunction solar cells. Sol. Energy Mater. Sol. Cells 2019, 200, 109963; https://doi.org/10.1016/j.solmat.2019.109963.Search in Google Scholar
5. Matthews, P. D., McNaughter, P. D., Lewis, D. J., O’Brien, P. Shining a light on transition metal chalcogenides for sustainable photovoltaics. Chem. Sci. 2017, 8, 4177–4187; https://doi.org/10.1039/c7sc00642j.Search in Google Scholar PubMed PubMed Central
6. Madarász, J., Leskelä, T., Rautanen, J., Niinistö, L. Oxidation of alkaline-earth-metal sulfide powders and thin films. J. Mater. Chem. 1996, 6, 781–787; https://doi.org/10.1039/jm9960600781.Search in Google Scholar
7. Egami, A., Onoye, T., Narita, K. Electrical conductivities of alkaline earth sulfides. Trans. Jpn. Inst. Met. 1981, 22, 399–409; https://doi.org/10.2320/matertrans1960.22.399.Search in Google Scholar
8. Lai, Y.-H., Cheung, W.-Y., Lok, S.-K., Wong, G. K. L., Ho, S.-K., Tam, K.-W., Sou, I.-K. Rocksalt MgS solar blind ultra-violet detectors. AIP Adv. 2012, 2, 012149; https://doi.org/10.1063/1.3690124.Search in Google Scholar
9. He, Q. L., Lai, Y. H., Liu, Y., Beltjens, E., Qi, J., Sou, I. K. High performance CaS solar-blind ultraviolet photodiodes fabricated by seed-layer-assisted growth. Appl. Phys. Lett. 2015, 107, 181903; https://doi.org/10.1063/1.4934944.Search in Google Scholar
10. Pervez, S., Iqbal, M. Z. Evaluation of battery-grade alkaline earth metal sulfide electrodes for energy storage applications. Int. J. Energy Res. 2022, 46, 8093–8101; https://doi.org/10.1002/er.7712.Search in Google Scholar
11. Sun, B., Yi, G., Chen, D., Zhou, Y., Cheng, J. Synthesis and characterization of strongly fluorescent europium-doped calcium sulfide nanoparticles. J. Mater. Chem. 2002, 12, 1194–1198; https://doi.org/10.1039/b109352e.Search in Google Scholar
12. Sun, Y.-Y., Agiorgousis, M. L., Zhang, P., Zhang, S. Chalcogenide perovskites for photovoltaics. Nano Lett. 2015, 15, 581–585; https://doi.org/10.1021/nl504046x.Search in Google Scholar PubMed
13. Sopiha, K. V., Comparotto, C., Márquez, J. A., Scragg, J. J. S. Chalcogenide perovskites: tantalizing prospects, challenging materials. Adv. Opt. Mater. 2021, 10, 2101704; https://doi.org/10.1002/adom.202101704.Search in Google Scholar
14. Jess, A., Yang, R., Hages, C. J. On the phase stability of chalcogenide perovskites. Chem. Mater. 2022, 34, 6894–6901; https://doi.org/10.1021/acs.chemmater.2c01289.Search in Google Scholar
15. Marino, E., Kodger, T. E., Crisp, R. W., Timmerman, D., MacArthur, K. E., Heggen, M., Schall, P. Repairing nanoparticle surface defects. Angew. Chem. 2017, 129, 13983–13987; https://doi.org/10.1002/ange.201705685.Search in Google Scholar
16. Roth, A. N., Chen, Y., Adamson, M. A. S., Gi, E., Wagner, M., Rossini, A. J., Vela, J. Alkaline-earth chalcogenide nanocrystals: solution-phase synthesis, surface Chemistry, and stability. ACS Nano 2022, 16, 12024–12035; https://doi.org/10.1021/acsnano.2c02116.Search in Google Scholar PubMed
17. Zhao, Y., Rabouw, F. T., Donegá, C. D. M., Meijerink, A., van Walree, C. A. Single-source precursor synthesis of colloidal CaS and SrS nanocrystals. Mater. Lett. 2012, 80, 75–77; https://doi.org/10.1016/j.matlet.2012.04.066.Search in Google Scholar
18. Jain, A., Ong, S. P., Hautier, G., Chen, W., Richards, W. D., Dacek, S., Cholia, S., Gunter, D., Skinner, D., Ceder, G., Persson, K. A. Commentary: the Materials Project: a materials genome approach to accelerating materials innovation. APL Mater. 2013, 1, 011002; https://doi.org/10.1063/1.4812323.Search in Google Scholar
19. Güntert, O. J., Faessler, A. Präzisionsbestimmung der Gitterkonstanten der Erdalkalisulfide MgS, CaS, SrS und BaS. Z. Kristallogr. 1956, 107, 357–361; https://doi.org/10.1524/zkri.1956.107.5-6.357.Search in Google Scholar
20. Herzinger, C. M., Johs, B., McGahan, W. A., Woollam, J. A., Paulson, W. Ellipsometric determination of optical constants for silicon and thermally grown silicon dioxide via a multi-sample, multi-wavelength, multi-angle investigation. J. Appl. Phys. 1998, 83, 3323–3336; https://doi.org/10.1063/1.367101.Search in Google Scholar
21. Holzwarth, U., Gibson, N. The Scherrer equation versus the ’Debye-Scherrer equation. Nat. Nanotechnol. 2011, 6, 534; https://doi.org/10.1038/nnano.2011.145.Search in Google Scholar PubMed
22. Miranda, M. A. R., Sasaki, J. M. The limit of application of the Scherrer equation. Acta Crystallogr. Sect. A: Found. Crystallogr. 2018, 74, 54–65; https://doi.org/10.1107/s2053273317014929.Search in Google Scholar
23. Chase, M. W.Jr. NIST-JANAF Thermochemical Tables, Monograph 9, 4th ed.; American Chemical Society: Washington, DC, Vol. 9, 1998; pp. 1–1951.Search in Google Scholar
24. Zilevu, D., Creutz, S. E. Shape-controlled synthesis of colloidal nanorods and nanoparticles of barium titanium sulfide. Chem. Mater. 2021, 33, 5137–5146; https://doi.org/10.1021/acs.chemmater.1c01193.Search in Google Scholar
25. Zilevu, D., Parks, O. O., Creutz, S. E. Solution-phase synthesis of the chalcogenide perovskite barium zirconium sulfide as colloidal nanomaterials. Chem. Commun. 2022, 58, 10512–10515; https://doi.org/10.1039/d2cc03494h.Search in Google Scholar PubMed
26. Manteiga Vázquez, F., Yu, Q., Klepzig, L. F., Siebbeles, L. D. A., Crisp, R. W., Lauth, J. Probing excitons in ultrathin PbS nanoplatelets with enhanced near-infrared emission. J. Phys. Chem. Lett. 2021, 12, 680–685; https://doi.org/10.1021/acs.jpclett.0c03461.Search in Google Scholar PubMed
27. Crisp, R. W., Kroupa, D. M., Marshall, A. R., Miller, E. M., Zhang, J., Beard, M. C., Luther, J. M. Metal Halide Solid-State Surface Treatment for High Efficiency PbS and PbSe QD Solar Cells. Sci. Rep. 2015, 5, 9945; https://doi.org/10.1038/srep09945.Search in Google Scholar PubMed PubMed Central
28. Shannon, R. D. Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides. Acta Crystallogr. Sect. A 1976, 32, 751–767; https://doi.org/10.1107/s0567739476001551.Search in Google Scholar
29. Zhang, B., Xia, G., Chen, W., Gu, Q., Sun, D., Yu, X. Controlled-size hollow magnesium sulfide nanocrystals anchored on graphene for advanced lithium storage. ACS Nano 2018, 12, 12741–12750; https://doi.org/10.1021/acsnano.8b07770.Search in Google Scholar PubMed
30. Joo, J., Kim, T., Lee, J., Choi, S.-I., Lee, K. Morphology-controlled metal sulfides and phosphides for electrochemical water splitting. Adv. Mater. 2019, 31, 1806682; https://doi.org/10.1002/adma.201806682.Search in Google Scholar PubMed
31. Weigand, C., Crisp, R., Ladam, C., Furtak, T., Collins, R., Grepstad, J., Weman, H. Electrical, optical and structural properties of Al-doped ZnO thin films grown on GaAs(111)B substrates by pulsed laser deposition. Thin Solid Films 2013, 545, 124–129; https://doi.org/10.1016/j.tsf.2013.07.052.Search in Google Scholar
32. Crisp, R. W., Panthani, M. G., Rance, W. L., Duenow, J. N., Parilla, P. A., Callahan, R., Dabney, M. S., Berry, J. J., Talapin, D. V., Luther, J. M. Nanocrystal grain growth and device architectures for high-efficiency CdTe ink-based photovoltaics. ACS Nano 2014, 8, 9063–9072; https://doi.org/10.1021/nn502442g.Search in Google Scholar PubMed
33. Crisp, R. W., Pach, G. F., Kurley, J. M., France, R. M., Reese, M. O., Nanayakkara, S. U., MacLeod, B. A., Talapin, D. V., Beard, M. C., Luther, J. M. Tandem solar cells from solution-processed CdTe and PbS quantum dots using a ZnTe–ZnO tunnel junction. Nano Lett. 2017, 17, 1020–1027; https://doi.org/10.1021/acs.nanolett.6b04423.Search in Google Scholar PubMed
34. Dobrozhan, O., Danylchenko, P., Novgorodtsev, A., Opanasyuk, A. Optical and recombination losses in Cu 2 ZnSn(S,Se) 4 -based thin-film solar cells with CdS, ZnSe, ZnS window and ITO, ZnO charge-collecting layers. J. Nanoelectron. Optoelectron. 2018, 13, 195–207; https://doi.org/10.1166/jno.2018.2192.Search in Google Scholar
35. Sreevidya, K. L., Abraham, N., Sajeev, C. Simulation studies of CZTS thin film solar cell using different buffer layers. Mater. Today: Proc. 2021, 43, 3684–3691; https://doi.org/10.1016/j.matpr.2020.11.405.Search in Google Scholar
36. Crisp, R. W., Hashemi, F. S. M., Alkemade, J., Kirkwood, N., Grimaldi, G., Kinge, S., Siebbeles, L. D. A., van Ommen, J. R., Houtepen, A. J. Atomic layer deposition of ZnO on InP quantum dot films for charge separation, stabilization, and solar cell formation. Adv. Mater. Interfaces 2020, 7, 1901600; https://doi.org/10.1002/admi.201901600.Search in Google Scholar
37. Edwards, P. P., Porch, A., Jones, M. O., Morgan, D. V., Perks, R. M. Basic materials physics of transparent conducting oxides. Dalton Trans. 2004, 19, 2995–3002; https://doi.org/10.1039/b408864f.Search in Google Scholar PubMed
38. Chen, Y., Fan, S. W., Xu, P. Defect induced ambipolar conductivity in wide-bandgap semiconductor SrS: theoretical perspectives. Appl. Phys. Lett. 2022, 121, 252102-1–252102-6; https://doi.org/10.1063/5.0125543.Search in Google Scholar
39. Chen, Y., Fan, S. W., Gao, G. Y. Theoretical insights into the defect performance of the wide bandgap semiconductor BaS. Phys. Chem. Chem. Phys. 2023, 25, 11745–11755; https://doi.org/10.1039/d3cp00240c.Search in Google Scholar PubMed
40. Chen, Y., Fan, S. W., Gao, G. Y. Design ambipolar conductivity on wide-gap semiconductors: the case of Al- and Na-doped CaS. Mater. Sci. Semicond. Process. 2022, 151, 107024; https://doi.org/10.1016/j.mssp.2022.107024.Search in Google Scholar
41. Stavrinadis, A., Pelli Cresi, J. S., D’Acapito, F., Magen, C., Boscherini, F., Konstantatos, G. Aliovalent doping in colloidal quantum dots and its manifestation on their optical properties: surface attachment versus structural incorporation. Chem. Mater. 2016, 28, 5384–5393; https://doi.org/10.1021/acs.chemmater.6b01445.Search in Google Scholar
Supplementary Material
This article contains supplementary material (https://doi.org/10.1515/zkri-2023-0006).
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