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Licensed Unlicensed Requires Authentication Published by De Gruyter August 3, 2023

Improved bleached eucalyptus kraft pulp-based tissue papers incorporating wet-strength resins

  • Marina Matos EMAIL logo , Ana M. Carta , Paula C. Pinto and Dmitry V. Evtuguin EMAIL logo
From the journal Holzforschung

Abstract

Common tissue paper manufacturing trends aim at partial or total replacement of softwood pulp with hardwood pulp for its production, such as bleached eucalyptus kraft pulp (BEKP), in order to optimize the process and the final product properties such as softness. However, the use of a single type of hardwood fiber results in lower strengths of both wet and dry webs. To maintain necessary strength and desired properties, the incorporation of several additives is often required. In this context, low molecular weight polyethylene glycol (PEG) and different wet strength resins, such as polyamideamine-epichlorohydrin (PAE) and glyoxalated polyacrylamide (GPAM) resins, were combined to achieve an innovated product with improved properties. In particular, wet and dry tensile strength was significantly improved when combining PEG and wet strength resins, especially observed in tissue papers prepared with PAE resin, high-charge cationic agent and bulk applied aqueous PEG solution. Noteworthy that water absorption capacity and softness of tissue paper were not critically affected by PEG incorporation, regardless of application method used (in bulk or by spray).


Corresponding authors: Marina Matos and Dmitry V. Evtuguin, CICECO-Aveiro Institute of Materials and Department of Chemistry, University of Aveiro, 3810-193 Aveiro, Portugal, E-mail: ,
Article note: This article is a special contribution associated to a presentation made in the 16th European Workshop on Lignocellulosics and Pulp (EWLP) 2022, Gothenburg, Sweden, Jun 28 to Jul 1, 2022.

Funding source: COMPETE 2020

Award Identifier / Grant number: nº 246/AXIS II/2017

  1. Author contributions: Marina Matos: Investigation, Visualization, Writing - original draft. Ana M. Carta: Methodology, Supervision, Resources, Writing - review & editing. Paula C. Pinto: Validation, Funding, Writing - review & editing. Dmitry V. Evtuguin.

  2. Conflict of interest statement: The authors declare that they have no conflicts of interest regarding this article.

  3. Research funding: This research was supported by Project InPaCTus – Innovative Products and Technologies from eucalyptus, Project N_ 21 874 funded by Portugal 2020 through European Regional Development Fund (ERDF) in the frame of COMPETE 2020 n_ 246/AXIS II/2017. Moreover, this study was also developed within the scope of the project CICECO-Aveiro Institute of Materials, UIDB/50011/2020, UIDP/50011/2020 & LA/P/0006/2020, financed by national funds through the Portuguese Foundation for Science and Technology/MEC (PIDDAC).

References

Bajpai, P. (2015). Pulp and paper chemicals. In: Pulp and paper industry: chemicals. Elsevier Inc., Oxford, UK, pp. 25–273.10.1016/B978-0-12-803408-8.00003-2Search in Google Scholar

Chatterjee, P.K. and Gupta, B.S. (2002). Porous structure and liquid flow models. In: Chatterjee, P.K. and Chatterjee, P.K. (Eds.), Absorbent technology. Elsevier, pp. 2–53.10.1016/S0920-4083(02)80004-4Search in Google Scholar

Clark, J.D.A. (1985). Pulp technology and treatment for paper. Pulp & paper book, 2nd ed. M. Freeman Publications, San Francisco.Search in Google Scholar

De Assis, T., Reisinger, L.W., Dasmohapatra, S., Pawlak, J., Jameel, H., Pal, L., Kavalew, D., and Gonzalez, R.W. (2018). Performance and sustainability vs. the shelf price of tissue paper kitchen towels. Bioresources 13: 6868–6892, https://doi.org/10.15376/biores.13.3.6868-6892.Search in Google Scholar

Foelkel, C. (2016). As fibras celulósicas de Eucaliptos na produção de papéis tissue de elevados níveis de maciez e absorção. In: Eucalyptus online book & newsletter, Vol. 52, pp. 4–18, http://www.eucalyptus.com.br/artigos/news52_Eucalyptus_tissue.pdf.Search in Google Scholar

Francolini, I., Galantini, L., Rea, F., Di Cosimo, C., and Di Cosimo, P. (2023). Polymeric wet-strength agents in the paper industry: an overview of mechanisms and current challenges. Int. J. Mol. Sci. 24: 9268, https://doi.org/10.3390/ijms24119268.Search in Google Scholar PubMed PubMed Central

Fruijtier-Pölloth, C. (2005). Safety assessment on polyethylene glycols (PEGs) and their derivatives as used in cosmetic products. Toxicology 214: 1–38, https://doi.org/10.1016/j.tox.2005.06.001.Search in Google Scholar PubMed

Gigac, J. and Fiserova, M. (2008). Influence of pulp refining on tissue paper properties. Tappi J. 2008: 27–32, https://doi.org/10.32964/tj7.8.27.Search in Google Scholar

John, M.R.S. (2012). Enhancement of dry strength in high performance linerboard using a dual additive approach. In: Paper conference and trade show 2012 (PaperCon 2012). Tappi Press, New Orleans, Louisiana, USA, pp. 453–472.Search in Google Scholar

Morais, F.P., Bértolo, R.A.C., Curto, J.M.R., Amaral, M.E.C.C., Carta, A.M.M.S., and Evtyugin, D.V. (2019). Comparative characterization of eucalyptus fibers and softwood fibers for tissue papers applications. Mater. Lett.: X 4: 100028, https://doi.org/10.1016/j.mlblux.2019.100028.Search in Google Scholar

Naithani, V., Tyagi, P., Jameel, H., Lucia, L.A., and Pal, L. (2020). Ecofriendly and innovative processing of hemp hurds fibers for tissue and towel paper. Bioresources 15: 706–720, https://doi.org/10.15376/biores.15.1.706-720.Search in Google Scholar

Obokata, T. and Isogai, A. (2007). The mechanism of wet-strength development of cellulose sheets prepared with polyamideamine-epichlorohydrin (PAE) resin. Colloids Surf., A 302: 525–531, https://doi.org/10.1016/j.colsurfa.2007.03.025.Search in Google Scholar

Park, J.Y., Melani, L., Lee, H., and Kim, H.J. (2019). Effect of chemical additives on softness components of hygiene paper. Nord. Pulp Pap. Res. J. 34: 173–181, https://doi.org/10.1515/npprj-2019-0002.Search in Google Scholar

Roberts, J.C. (1996). The chemistry of paper, 1st ed The Royal Society of Chemistry, Cambridge.Search in Google Scholar

Siqueira, E.J., Salon, M.C.B., Belgacem, M.N., and Mauret, E. (2015). Carboxymethylcellulose (CMC) as a model compound of cellulose fibers and polyamideamine epichlorohydrin (PAE)-CMC interactions as a model of PAE-fibers interactions of PAE-based wet strength papers. J. Appl. Polym. Sci. 42144: 1–10, https://doi.org/10.1002/app.42144.Search in Google Scholar

Stankovská, M., Fišerová, M., Gigac, J., and Opálená, E. (2020). Blending impact of hardwood pulps with softwood pulp on tissue paper properties. Wood Res. 65: 447–458, https://doi.org/10.37763/wr.1336-4561/65.3.447458.Search in Google Scholar

Sundararajan, S., Samui, A.B., and Kulkarni, P.S. (2017). Shape-stabilized poly(ethylene glycol) (PEG)-cellulose acetate blend preparation with superior PEG loading via microwave-assisted blending. Sol. Energy 144: 32–39, https://doi.org/10.1016/j.solener.2016.12.056.Search in Google Scholar

Tissue Paper Market (2023). Tissue paper market – growth, trends, COVID-19 impact, and forecasts (2023–2028). Research and Markets. https://www.researchandmarkets.com/reports/5026151/tissue-paper-market-growth-trends-covid-19#rela1-5157622 .Search in Google Scholar

Valencia, C., Valencia, Y., and Tovar, C.D.G. (2020). Synthesis and application of a cationic polyamine as yankee dryer coating agent for the tissue paper-making process. Polymers 12: 1–14.10.3390/polym12010173Search in Google Scholar PubMed PubMed Central

Wang, L. and Zhang, Y. (2013). Influence of anionic trash catcher pretreatment on the effectiveness of dry strengthening agent. Bioresources 8: 6078–6086, https://doi.org/10.15376/biores.8.4.6078-6086.Search in Google Scholar

Yang, D., Diflavio, J.L., Gustafsson, E., and Pelton, R. (2018). Wet-peel: a tool for comparing wet-strength resins. Nord. Pulp Pap. Res. J. 33: 632–646, https://doi.org/10.1515/npprj-2018-0013.Search in Google Scholar

Yang, H., Yan, R., Chen, H., Lee, D.H., and Zheng, C. (2007). Characteristics of hemicellulose, cellulose and lignin pyrolysis. Fuel 86: 1781–1788, https://doi.org/10.1016/j.fuel.2006.12.013.Search in Google Scholar

Yuan, Z. and Hu, H. (2012). Preparation and characterization of crosslinked glyoxalated polyacrylamide paper-strengthening agent. J. Appl. Polym. Sci. 126: E459–E469, https://doi.org/10.1002/app.36779.Search in Google Scholar

Received: 2023-01-15
Accepted: 2023-07-25
Published Online: 2023-08-03
Published in Print: 2023-09-26

© 2023 Walter de Gruyter GmbH, Berlin/Boston

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