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Water-Soluble Interpolyelectrolyte Complex Based on Poly(diallyldimethylammonium chloride) and Sodium Polyacrylate as a Component for Creating Stable Biocidal Coatings

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Abstract

Polycation-based coatings represent a promising class of protective antimicrobial coatings. Water-soluble complexes of poly(diallyldimethylammonium chloride) (PDADMAC) with sodium polyacrylate (PANa) have been studied by turbidimetry. It has been shown that the addition of the polyanion (12 mol %) to the polycation leads to the formation of an interpolyelectrolyte complex (IPEC) stable with respect to phase separation in water-salt media with salt concentrations as high as 0.1–0.2 M. In contrast to the traditional method of obtaining coatings from IPEC by layer-by-layer deposition, we have studied the preparation of the coatings directly from a solution of water-soluble IPEC on a hydrophilic glass surface and a surface of more hydrophobic polycarbonate. It has been found that the formation of IPEC makes it possible to increase the resistance of the coating to wash-off with water compared to the individual PDADMAC coating on both types of substrates.

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Funding

The work was supported by the Ministry of Higher Education and Science of the Russian Federation (project no. 075-15-2020-775).

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Authors and Affiliations

  1. Department of Chemistry, Moscow State University, 119991, Moscow, Russia

    V. A. Pigareva, A. V. Bol’shakova, V. I. Marina & A. V. Sybachin

  2. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 119071, Moscow, Russia

    A. V. Bol’shakova

Authors
  1. V. A. Pigareva
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  2. A. V. Bol’shakova
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  3. V. I. Marina
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  4. A. V. Sybachin
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Correspondence to V. A. Pigareva.

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Pigareva, V.A., Bol’shakova, A.V., Marina, V.I. et al. Water-Soluble Interpolyelectrolyte Complex Based on Poly(diallyldimethylammonium chloride) and Sodium Polyacrylate as a Component for Creating Stable Biocidal Coatings. Colloid J 85, 433–441 (2023). https://doi.org/10.1134/S1061933X23600100

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  • DOI: https://doi.org/10.1134/S1061933X23600100

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