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Features of the 1,3,5-Trioxane Stabilization Process

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Abstract

It has been shown that, at a temperature of 75°C, 1,3,5-trioxane obtained by the liquid-phase method in the presence of a homogeneous catalyst partially decomposes with the formation of free formaldehyde, paraformaldehyde, and formic acid. A number of stabilizers for the thermal-oxidative degradation of 1,3,5-trioxane have been proposed and their effectiveness has been compared. The most effective additives were selected and their concentrations were determined, which provide the minimum amount of by-product formation under the indicated conditions.

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REFERENCES

  1. I. A. Susorov and V. M. Lukina, RF Patent No. 2043999 (20 September 1995).

  2. K. E. Burkin and R. A. Akhmed’yanova, “One-step synthesis of isoprene from trioxane and trimethylcarbinol,” in Proceedings of Scientific Session of Kazanskii Gosudarstvennyi Tekhnicheskii Universitet (Kazan, 2011), pp. 52.

  3. I. A. Susorov, V. I. Samborskii, L. B. Sirotkin, V. V. Motora, and T. D. Shaidurova, RF Patent No. 20617259 (10 June 1996).

  4. N. S. Enikolopyan and S. A. Vol’fson, Chemistry and Technology of Polyformaldehyde (Khimiya, Moscow, 1968) [in Russian].

    Google Scholar 

  5. V. I. Lyubimov and E. L.Cherkasskaya, “Works in the Field of Synthesis and Study of the Properties of Trioxane and Dioxolane,” in Collection of Works of the Research Institute of Polymer Materials “Plastics” (Khimiya, Moscow, 1970) [in Russian].

  6. K. Weissermel, E. Fischer, K. Gutweiler, H. D. Hermann, and H. Cherdron, “Polymerization of trioxane,” Angew. Chem., Int. Ed. 6, 477–579 (1967).

    Article  Google Scholar 

  7. T. Mutsuhiko, K. Minoru, S. Masafumi, and Y. Kiyoshi, US Patent No. 5026875 (25 June 1991).

  8. S. Akitoshi, T. Mutsuhiko, M. Makoto, and S. Takeo, US Patent No. 4125540 (14 November 1978).

  9. Y. Zhao, F. Kin, and M. Kunitomi, CN Patent No. 1276372 (13 December 2000).

  10. W. Fleck and T. Lussling, US Patent No. 3519650 (7 July 1970).

  11. E. Masuda and K. Sugiyama, JPN Appl. No. 07242652 (19 September 1995).

  12. Y. Okui and D. Kobayashi, CN Patent No. 105392812 (9 March 2016).

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Authors and Affiliations

  1. Kargin Polymer Chemistry and Technology Research Institute with a Pilot-Production Plant, 606000, Dzerzhinsk, Russia

    M. N. Leshina, A. M. Mazlov, P. V. Kornienko & K. V. Shirshin

  2. Alekseev Nizhny Novgorod State Technical University, 603950, Nizhny Novgorod, Russia

    K. V. Shirshin

  3. Federal State Enterprise “Sverdlov Plant”, 606002, Dzerzhinsk, Nizhny Novgorod oblast, Russia

    T. I. Vidyaeva, A. A. Solodukhin & A. Ya. Ilyash

Authors
  1. M. N. Leshina
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  2. A. M. Mazlov
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  3. P. V. Kornienko
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  4. K. V. Shirshin
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  5. T. I. Vidyaeva
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  6. A. A. Solodukhin
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  7. A. Ya. Ilyash
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Corresponding author

Correspondence to M. N. Leshina.

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The authors declare that they have no conflicts of interest.

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Translated by V. Selikhanovich

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Leshina, M.N., Mazlov, A.M., Kornienko, P.V. et al. Features of the 1,3,5-Trioxane Stabilization Process. Polym. Sci. Ser. D 16, 322–326 (2023). https://doi.org/10.1134/S1995421223020181

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  • DOI: https://doi.org/10.1134/S1995421223020181

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