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gem-Dichlorocyclopropanes and 1,3-Dioxacyclanes: Synthesis Based on Petroleum Products and Use in Low-Tonnage Chemistry

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Abstract

Methods for obtaining basic substituted gem-dichlorocyclopropanes and 1,3-dioxacyclanes based on petroleum products are considered. Separate reactions of O-, N-, C-alkylation of these compounds leading to the formation of heterocycles containing gem-dichlorocyclopropane and 1,3-dioxolane fragments are presented. Data are provided on radical polymerization, copolymerization, low-temperature ozonolysis, catalytic isomerization of vinyl-gem-dichlorocyclopropanes, as well as the study of reactions of 2,2-dimethyl-1,3-dioxolane with diazoacetoacetic ester. The possibilities of using the synthesized substances as biologically active compounds, as well as preparations capable of inhibiting the acid corrosion of metals, are shown.

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Funding

The work was supported by the state program of the RF Ministry of Science and Higher Education for scientific activities, project no. FEUR – 2022-0007 “Petrochemical Reagents, Oils and Materials for Thermal Power Engineering.”

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  1. Ufa State Petroleum Technological University, 450062, Ufa, Russia

    G. Z. Raskil’dina, R. M. Sultanova & S. S. Zlotskii

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  1. G. Z. Raskil’dina
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  2. R. M. Sultanova
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  3. S. S. Zlotskii
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Correspondence to G. Z. Raskil’dina or S. S. Zlotskii.

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Translated by S. Avodkova

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Raskil’dina, G.Z., Sultanova, R.M. & Zlotskii, S.S. gem-Dichlorocyclopropanes and 1,3-Dioxacyclanes: Synthesis Based on Petroleum Products and Use in Low-Tonnage Chemistry. rev. and adv. in chem. 13, 15–27 (2023). https://doi.org/10.1134/S2634827623700150

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