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Reactions of Triangular Molybdenum and Tungsten Clusters with Tetrabromocatechol

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Abstract

The reaction of cluster complex (nBu4N)2[Mo3Se7Br6] with tetrabromocatechol (H2Tbc) in the presence of Et3N and Ph4PBr results in the formation of (Ph4P)2[Mo3Se7(Tbc)3]∙2MeOH (Ia∙2MeOH). Under the same conditions, the tungsten analogue (nBu4N)2[W3S7Br6] is completely or partly destroyed to give the complex (Ph4P)(Et3NH)[WO2(Tbc)2] (II). The structures of Ia·2MeOH and II were established by X-ray diffraction analysis (CCDC nos. 2213900 and 2213901, respectively). The redox properties of complex Ia and related (Ph4P)2[Mo3S7(Tbc)3] (Ib) and (Ph4P)2[Mo3S7(Tcc)3] (Ic) (Tcc is tetrachlorocatecholate) were also studied by cyclic voltammetry.

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Funding

This study was supported by the Ministry of Science and Higher Education of the Russian Federation (project nos. 121031700313-8 and 121031700315-2).

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    P. A. Petrov, E. A. Filippova, T. S. Sukhikh, D. G. Sheven’, A. L. Gushchin & M. N. Sokolov

  2. Novosibirsk State University, Novosibirsk, Russia

    V. R. Giniyatullin

Authors
  1. P. A. Petrov
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  2. E. A. Filippova
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  3. V. R. Giniyatullin
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  4. T. S. Sukhikh
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  5. D. G. Sheven’
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  6. A. L. Gushchin
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  7. M. N. Sokolov
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Correspondence to P. A. Petrov.

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Translated by Z. Svitanko

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Petrov, P.A., Filippova, E.A., Giniyatullin, V.R. et al. Reactions of Triangular Molybdenum and Tungsten Clusters with Tetrabromocatechol. Russ J Coord Chem 49, 465–470 (2023). https://doi.org/10.1134/S1070328423600390

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  • DOI: https://doi.org/10.1134/S1070328423600390

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