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Complexes of Cu(II), Co(II), and Zn(II) Terephthalates with Hydroxyalkylamines

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Abstract

The reactions of Cu(II), Co(II), and Zn(II) terephthalates with hydroxyalkylamines (tris(2-hydroxyethyl)amine, bis(2-hydroxyethyl)amine, tris(hydroxymethyl)aminomethane, and bis(2-hydroxyethyl)aminotris(hydroxymethyl)methane) are studied for the first time. The structures and properties of the synthesized complexes are studied by IR spectroscopy, electronic absorption spectroscopy, mass spectrometry, and elemental and thermal analyses. The structure of the binuclear heteroligand [Cu2(TEA)2(Tph)]n·H2O complex is studied by single-crystal X-ray diffraction (XRD) (CIF file CCDC no. 2224437).

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ACKNOWLEDGMENTS

The authors are grateful to the resource centers of the St. Petersburg State University “Optical and Laser Methods of Matter Investigation,” “X-ray Diffraction Investigation Methods,” and “Methods for Analysis of Matter Composition” for the use of the equipment for studying the compositions and structures of the synthesized compounds.

Funding

This work was carried out in terms of the state assignment of the Grebenshchikov Institute of Silicate Chemistry (Russian Academy of Sciences) and supported by the Ministry of Science and Higher Education of the Russian Federation (theme no. 0081-2022-0005).

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Authors and Affiliations

  1. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, St. Petersburg, Russia

    D. A. Zav’yalova, Yu. A. Kondratenko, V. L. Ugolkov & T. A. Kochina

  2. St. Petersburg State Technological Institute (Technical University), St. Petersburg, Russia

    D. A. Zav’yalova

  3. Institute of Earth Sciences, St. Petersburg State University, St. Petersburg, Russia

    A. A. Zolotarev

Authors
  1. D. A. Zav’yalova
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  2. Yu. A. Kondratenko
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  3. A. A. Zolotarev
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  4. V. L. Ugolkov
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  5. T. A. Kochina
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Corresponding author

Correspondence to Yu. A. Kondratenko.

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The authors of this work declare that they have no conflicts of interest.

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Translated by E. Yablonskaya

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Zav’yalova, D.A., Kondratenko, Y.A., Zolotarev, A.A. et al. Complexes of Cu(II), Co(II), and Zn(II) Terephthalates with Hydroxyalkylamines. Russ J Coord Chem 49, 486–495 (2023). https://doi.org/10.1134/S1070328423600389

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  • DOI: https://doi.org/10.1134/S1070328423600389

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